• Title/Summary/Keyword: UV spectrophotometer

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PET에 증착된 Al:ZnO 투명발열체 박막

  • 한길진;김영철
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2005.09a
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    • pp.133-136
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    • 2005
  • 스퍼터링 공정으로 Al이 $2\%$ 함유된 ZnO 박막을 PET에 증착하여 김서림 제거용 투명발열체를 제작하였다. 증착된 투명발열체는 $5\;{\times}\;10^{-3}{\Omega}\;cm$ 의 비저항과 $80\%$ 이상의 가시광 투과도를 나타내었고, 조도는 12.5nm로 양호하였다. 투명발열체의 비저항, 가시광 투과도, 그리고 조도는 각각 Hall 계수 측정장비, IR-VIS-UV spectrophotometer, 그리고 AFM을 이용하여 측정하였다. 증착된 투명발열체에 12V의 전압을 인가하였을 때, 표면의 온도는 평균적으로 1분에 약 $10^{\circ}C$ 증가하였다.

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A Study on the Effect on UV Exposure in Coastal Buildings (연안건축물의 자외선 노출에 따른 안전성 연구)

  • Kim, Taehwan;Uh, Jesun
    • Journal of the Society of Disaster Information
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    • v.17 no.2
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    • pp.195-205
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    • 2021
  • Purpose: The ultraviolet reflectance and transmittance of coastal building materials are one of the important factors of ultraviolet radiation in and out of coastal building. In this research, the ultraviolet spectral reflectance of many kinds of building materials was measured. Also, the relationships with the lightness, roughness, and chromaticity, which are surface characteristics, were reviewed and suggested. Method: In this study, according to the CIE classification, the ultraviolet region was defined as short-wavelength region UV-C(10nm~280nm), medium-wavelength region UV-B (280-315 nm), and long-wavelength region UV-A (315-400nm), and the visible light region was defined as (400nm~780nm). Spectrophotometer was used to continuously measure the reflectance from the ultraviolet region to the visible light region. Results: From the measurement results, the ultraviolet reflectance on Wood was shown to be about Visible 55-68%, UV-A* 7-12%, and UV-B 4-5%. Wall tiles are about Visible18-40%, UV-A* 8-20%, and UV-B* 7-8%. That on concrete was shown to be about Visible 37%, UV-A* 28%, and UV-B*19%. Conclusion: The ultraviolet reflectance can be estimated by visible reflectance. Also, it is important to select a variety of materials according to the application when blocking UV.

Radiative Properties at King Sejong Station in West Antarctica with the Radiative Transfer Model : A Surface UV-A and Erythemal UV-B Radiation Changes (대기 복사 모형에 의한 남극 세종기지에서의 복사학적 특징 : 지표면에서 UV-A와 Erythemal UV-B 자외선 양 변화)

  • Lee, Kyu-Tae;Lee, Bang-Yong;Won, Young-In;Jee, Joon-Bum;Lee, Won-Hak;Kim, Youn-Joung
    • Ocean and Polar Research
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    • v.25 no.1
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    • pp.9-20
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    • 2003
  • A solar radiation model was used to investigate the UV radiation at the surface offing Sejong Station in West Antarctica. The results calculated by this model were compared with the values measured by UV-Biometer and UV-A meter during 1999-2000. In this study, the parameterization of solar radiative transfer process was based on Chou and Lee(1996). The total ozone amounts measured by Breve. Ozone Spectrophotometer and the aerosol amounts by Nakajima et al.(1996) was used as the input data of the solar radiative transfer model. And the surface albedo is assumed to be 0.20 in summer and 0.85 in winter. The sensitivity test of solar radiative transfer model was done with the variation of total ozone, aerosol amount, and surface albedo. When the cosine of solar zenith angle is 0.3, Erythemal UV-B radiation decreased 73% with the 200% increase of total ozone from 100 DU to 300 DU, but the decrease of UV-A radiation is about 1%. Also, for the same solar zenith angle, UV-A radiation was decreased 31.0% with the variation of aerosol optical thickness from 0.0 to 0.3 and Erythemal UV-B radiation was decreased only 6.1%. The increase of Erythemal W-B radiation with the variation of surface albedo was twice that of UV-A increase. The surface Erythemal UV-B and UV-A radiation calculated by solar raditive transfer model were compared with the measured values fer the relatively clear day at King Sejong Station in West Antarctica. The model calculated Erythemal UV-B radiation at the surface coincide well with the measured values except for cloudy days. But the difference between the model calculated UV-A radiation and the measured value at the surface was large because of cloud scattering effect. So, the cloud property data is needed to calculate the UV radiation more exactly at King Sejong Station in West Antarctica.

Synthesis and Characteristics of 2,6-disubstituted Pyrylium Fluoroborates (2,6-Disubstituted Pyrylium Fluoroborates 화합물의 합성과 특성)

  • Cho, Sung-Il
    • Applied Chemistry for Engineering
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    • v.20 no.3
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    • pp.351-353
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    • 2009
  • Pyrylium fluoroborates undergo a wide range of synthetically useful reactions because of the positive charge. And the electron accepting nature has resulted in their widespread use as sensitizers for photo-induced electron transfer (PET) reactions. In this experiment, 2,6-disubstituted pyrylium fluoroborates are synthesized from the reaction between $3^{\prime}$-chloroacetophenone and excess orthoformate in an acidic medium (acetic anhydride/acid). Synthesized products are confirmed by $^1H-NMR$, FT-IR and TOF Mass spectroscopies. Also, photo-properties are analyzed with an UV-Vis spectrophotometer.

Analysis of Chlorine Species in Chlorine Dioxide Bleaching Liquor and Generation Process by UV-VIS Spectroscopy

  • Wang, Li-Jun;Lee, Seon-Ho;Yoon, Byung-Ho
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.04a
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    • pp.78-83
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    • 1999
  • In this paper the extinction coefficients of molecule chlorine ($Cl_2$), chlorine dioxide (ClO$_2$), hypochlorous acid (HClO), chlorous acid ($HClO_2$$_2$) were determined using a PDA UV-VIS spectrophotometer. Based on these, the concentrations of $Cl_2$, $ClO_2$, and HClO in general chlorine dioxide bleaching liquor can be measured. The concentrations of $Cl_2$, $ClO_2$ and $HClO_2$ produced during the generation of methanol based chlorine dioxide generator can also be determined use the same method. The method was thought to be able to give more information in chlorine dioxide bleaching chemistry if combine its use with titration and ion chromatography.

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Layer-by-layer self-assembly colorant multi-layer preparation using natural colorant Berberine and anionic polyelectrolyte (베르베린 천연색소화합물과 음이온고분자전해질을 이용한 layer-by-layer self-assembly 색소다층박막 제조)

  • Son Young-A;Park Young-Min;Lee Seung-Goo;Ravikumar K.
    • Textile Coloration and Finishing
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    • v.18 no.1
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    • pp.28-32
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    • 2006
  • A multi-layer of the dye, natural colorant Berberine, was successfully developed by the self-assembly deposition from water-soluble cationic dye(Berberine chloride) and anionic polyelectrolyte PSS(Polysodium 4-styrenesulfonate) in aqueous solution via electrostatic attraction. The corresponding results on multi-layer were characterized by UV-Vis absorbance measurements. The growth of multi-layer formed by the sequential interaction was also determined. The findings measured by UV-Vis spectrophotometer showed that the bilayer deposition characteristic was linear and highly reproducible from layer to layer.

Synthesis of Hexyltriphenylphosphonium-TCNQ Complex and Stability in Spreading Solvent (Hexyltriphenylphonium-TCNQ 착물(錯物)의 합성(合成)과 분산용매 중에서의 안정성)

  • Han, Jong-Soo;Hwang, Kyo-Hyeon;Sohn, Byoung-Chung
    • Journal of the Korean Applied Science and Technology
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    • v.12 no.1
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    • pp.115-118
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    • 1995
  • Hexyltriphenylphosphonium-TCNQ(HTPP-TCNQ) complex for preparing organic thin film by Langmuir-Blodgett technique was synthesized from LiTCNQ and Hexyltriphenylphosphonium bromide. The structure of the new complex was confirmed by $^{1}H$ NMR, $^{31}P$ NMR, IR, UV spectroscopies, TGA and elemental analysis. A stability to spreading solvent, which is acetonitrile, ethylacetate, ethanol and acetonitrile-ethylacetate(1:1 v/v), of HTPP-TCNQ complex was investigated by UV-visible spectrophotometer. The complex was stabilized in acetonitrile, ethylacetate, aceton, acetonitrile-ethylacetate (1:1 v/v) for 6 h.

Measurement of Color Change of Opaque Resin Materials by Radiation Energy (불투명 수지재료의 복사에너지에 의한 변색 측정)

  • Han, Jong-Sung;Kim, Hong-Beom;Kim, Hoon
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 1998.11a
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    • pp.138-141
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    • 1998
  • To evaluate the color change of the opaque resin materials, a measuring system including PAS(photodegradation acceleration system) was constructed. Xenon lamp is used as a light source in the PAS, and the radiant energy from the lamp is irradiated to the samples through serveral high-pass filters with cut-off wavelength in UV and visible region. The color difference of the samples were measured by using the measuring system with a spectrophotometer(CM-2002) and a computer. The result showed that the opaque resin materials changed severely in their color in the wavelength of UV region and changed a little in the wavelength of visible region.

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Preparation of Nanosized Gold Particles by Microwave Irradiation and Kinetics Study for Reduction of 4-Nitroaniline under Various Conditions

  • Kim, Jae Jin;Ko, Weon Bae
    • Elastomers and Composites
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    • v.50 no.4
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    • pp.274-278
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    • 2015
  • Nanosized gold particles were synthesized by microwave irradiation in a mixture composed of potassium tetrachloroaurate(III) n-hydrate, sodium citrate dihydrate and Tween 20. The synthesized gold particles were characterized by UV-vis spectrophotometer, scanning electron microscopy, and X-ray diffraction techniques. Using UV-vis spectroscopy, it was confirmed that gold nanoparticles act as a catalyst in the reduction of 4-nitroaniline with sodium borohydride to form 1,4-diaminobenzene. Additionally, we studied the kinetics of this reductive reaction in the presence of these gold nanoparticles under various conditions.

Preparation of Au fine particle dispersed $TiO_2$ film by sol-gel and photoreduction process

  • Hyun, Buh-Sng;Kim, Byeong-Il;Kang, Won-Ho
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1998.09a
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    • pp.103-111
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    • 1998
  • Au fine particle dispersed TiO2 film was prepared on silica glass substrate by sol-gel dip and firing process. The films were fabricated from the system of titanium tetraisoproxie-EtOh-HCl_H2O-hydrogen tetrachloroaurate(III) tetrahydrate. The conditions for the formation of the clear solution and dissolving high concentration of Au compound were examined. And a photoreduction process was adopted to control the size of gold metal particles. Phase evolution of matrix TiO2 and variation of Au particle with UV irradiation were investigated by XRDA, SEM, TEM and UV-visible spectrophotometer. And the effect of CPCl(Cetylpyridinium chloride monohydrate) as a dispersion agent was evaluated.

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