• Title/Summary/Keyword: UV photometric method

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Analysis of Anions by Indirect Photometric Detection (I) (간접 분광 검출법에 의한 음이온의 분석(I))

  • Park, Man-Ki;Kim, Bak-Kwang;Park, Jeong-Hill;Kim, Kyoung-Ho;Lee, Mi-Yung;Jung, Jae-Eun
    • YAKHAK HOEJI
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    • v.34 no.3
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    • pp.215-218
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    • 1990
  • An ion chromatographic method based on indirect photometric detection of UV transparent anions was developed. Separation of anion was accomplished on strong anion exchange column (Waters SAX) using UV detector at 254 nm. Among examined UV-active additives (Dns-H, Dns-glu, Dnsser, Dns-val), Dns-glu showed the highest sensitivity. Studies on the effects of the pH and ionic strength of eluent revealed that the increase of pH and ionic strength of the eluent decreased capacity factor. The best eluent for the separation of acetate, fluoride, chloride, nitrate and bromide was $1\;{\times}\;10^{-4}M$ Dns-glu in 5 mM phosphate buffer (pH 6.30). The detection limit of chloride ion was 2.1 ng in this condition.

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A Study on the Analysis of Components in Foam Produced from a Stream (하천 발생 거품의 성분에 관한 분석 연구)

  • Bae, Jang-Soon;Park, Chan-Kyo;Sung, Ki-Chun;Lee, Seok-Woo;Hwang, Yong-Hyun
    • Journal of the Korean Applied Science and Technology
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    • v.21 no.2
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    • pp.117-123
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    • 2004
  • According to increase of using quantity, people interested in the environmental influence by synthetic detergent. The main visible form when synthetic detergent dissolved in water is generating foams. This foam makes coating over water surface and prevents oxygen penetrating in water and make water more polluted with that result. To analyze, components and origins of the foam, and to make clear its environmental influence in this study. The analyzing objects are introducing water of sewage treatment plant from the a tributary to the Han River. After analysis, reached the conclusion like below, Analyzing foams and introducing water by sublation method, average return rate of standard LAS (1.0ppm) is 90%. LAS contents of foams analyzed by UV photometric method and HPLC method are 35.0ppm and 44.5ppm each, and AOS contents of foams analyzed by the same method are 0.6ppm and 0.4ppm each. We can find out by this study's analyzing results that the main components of foams are anion surfactant, it's content and in case of capric acid linoleic acid, it's contents.

THE BVR CCD PHOTOMETRY OF GLOBULAR CLUSTER M13

  • PYO TAE SOO;LEE SEE-WOO
    • Journal of The Korean Astronomical Society
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    • v.27 no.2
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    • pp.119-132
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    • 1994
  • The BVR CCD photometry was performed for the globular cluster M13 down to $V=19^m$ over the region from the center to the west 13 arcmin and the CMD of M13 is investigated. The major photometric error in the crowded field which is due to the variation in the sky background was corrected by the median filtering method and the direct sky method. Some characteristics of the CMD of M13 obtained in the present study are as follows: Firstly, the distribution of stars on the CMD is well consistent with the mean lines of Sandage(1970) along the red giant branch(RGB), horizontal branch(HB) and asymtotic giant branch(AGB). Secondly, some gaps exists along the RGB and blue horizontal branch(BHB). Thirdly, the UV-bright stars are more concentrated at the inner region of the cluster.

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A study on the color management between scanner and monitor using multiple regression method (다중 회귀분석법을 이용한 스캐너-모니터간 색보정에 관한 연구)

  • 박진희;김홍석;박승옥
    • Korean Journal of Optics and Photonics
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    • v.14 no.4
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    • pp.473-479
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    • 2003
  • The purpose of this study is to recover the CIE XYZ tristimulus values of original colors from scanner output signals, and to reproduce true colors on the monitor. The process of this study is composed of three steps; scanner characterization, chromatic adaptation transformation, and color space transformation between and sRGB. Especially, in the process of recovery, scanner stimuli were obtained accurately by dividing the non-linear photometric response curve into two parts. As the result of test to EPSON Expression 1680 scanner, the average color difference between true and recovered XYZ for 228 target colors, 22 test neutrals, and 36 test colors were 1.49, 0.97, and 1.42 $\Delta$ $E_{UV}$ *, respectively. With the transformation from illuminant D50 to illuminant D65, the input signals to sRGB monitor were predicted. Finally, it could be found that displayed colors with predicted input signals were very consistent with true colors. with true colors.

Simultaneous Determination of Alkaline Earth Metal Ions by a Conventional High Performance Liquid Chromatographic System

  • Rho, Young-Soo;Choi, Seung-Gi
    • Archives of Pharmacal Research
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    • v.9 no.4
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    • pp.211-214
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    • 1986
  • A simultaneous determination method of alkaline earth metals was attempted with the conventional high performance liquid chromatographic system. Four cations, namely, magnesium, calcium, strontium and barium ion, were injected directly as aqueous solution into an eluent containing copper chloride solution and and were successfully separated and determined on a separating column (Zipax SCX, 4.6 mm i.d. ${\times}25$ cm length, Du Pont, USA) by using a variable wavelength UV detector. The linear calibration curves were obtianed in the range from $1.0{\times}10^{-4}M$ to $5.0{\times}10^{-4}M$ and the correlation coefficient of the calibration curve for each metal of magnesium and calcium in tap water. Alkaline earth metals were determined with the conventional high performance liquid chromatographic system.

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Ion Chromatography of Anions with Indirect UV-Photometric Detection by using Naphthalene Trisulfonic Acid and Naphthalene Disulfonic Acid as an Eluent (Naphthalene Trisulfonic Acid 및 Naphthalene Disulfonic Acid을 이용한 음이온 간접자외선흡광검출 이온크로마토그래피)

  • Lee, Kwang-Pill;Cheon, Hwi-Kyung;Seo, Hyun-Kyung;Kwon, Se-Mog;Park, Keung-Shik;Tanaka, Kazuhiko;Ohta, Kazutoku
    • Analytical Science and Technology
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    • v.12 no.2
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    • pp.111-115
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    • 1999
  • Single column anion chromatography by indirect UV detection was applied to the determination of 7 common anions($H_2PO_4^-$, $Cl^-$, $NO_2^-$, $NO_3^-$, $I^-$, $SO_4^{2-}$, $SCN^-$). A low capacity silica-based anion-exchange column(TSK guardgel QAE-SW; ca. 0.3 meq./g; 4.6 mm i.d${\times}$150 mm) was used. In separating common anions, we compared naphthalene trisulfonic acid(NTS) and naphthalene disulfonic acid(NDS) to find more sensitive, selective and rapid separation method. And cations and anions can be separated simultaneously in 0.20 mM NTS-5% acetonitrile-water.

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BRACKETT LINE-BASED MBH ESTIMATORS AND HOT DUST TEMPERATURES OF TYPE 1 AGNs FROM AKARI SPECTROSCOPIC DATA

  • KIM, DOHYEONG;IM, MYUNGSHIN
    • Publications of The Korean Astronomical Society
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    • v.30 no.2
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    • pp.443-445
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    • 2015
  • We provide results of near-infrared (NIR) spectroscopic observations of 83 nearby (0.002< z <0.48) and bright (K <14 mag) type 1 active galactic nuclei (AGNs). For the observations, we used the Infrared Camera (IRC) on AKARI allowing us to obtain the spectrum in the rarely studied spectral range of $2.5-5.0{\mu}m$. The $2.5-5.0{\mu}m$ spectral region suffers less dust extinction than ultra violet (UV) or optical wavelength ranges, and contains several important emission lines such as $Br{\beta}$ ($2.63{\mu}m$), $Br{\alpha}$ ($4.05{\mu}m$), and polycyclic aromatic hydrocarbon (PAH; $3.3{\mu}m$). The sample is selected from the bright quasar surveys of Palomar Green and SNUQSO, and AGNs with black hole (BH) masses estimated from reverberation mapping method. We measure the Brackett line properties for 11 AGNs, which enable us to derive BH mass estimators and investigate circum-nuclear environments. Moreover, we perform spectral modeling to fit the hot and warm dust components by adding photometric data from SDSS, 2MASS, WISE, and ISO to the AKARI spectra, and estimate hot and warm dust temperatures of ~1100K and ~220 K, respectively.

UBVI CCD Photometry of the Globular Cluster M30 (구상성단 M30의 UBVI CCD 측광연구)

  • Lee, Ho;Jeon, Young-Beom
    • Journal of the Korean earth science society
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    • v.27 no.5
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    • pp.557-568
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    • 2006
  • We present CCD UBVI photometry for more than 10,000 stars in $20'.5{\times}20'.5$ field of the halo globular cluster M30. From a color-magnitude diagram, main sequence turnoff was obtained when $V_{TO},\;(B-V)_{TO},\;and\;(V-I)_{TO}\;are\;8.63{\pm}0.05,\;0.44{\pm}0.05\;and\;0.63{\pm}0.05$, respectively. From a (U-B)-(B-V) diagram, reddening parameter, E(B-V) equals $0.05{\pm}0.01$ and a UV color excess ${\delta}(U-B)\;is\;0.27{\pm}0.01$. The abundance is derived, where [Fe/H] equals $-2.05{\pm}0.09$ according to the photometric method and spectroscopic data. The observed luminosity function of M30 shows an excess in the number of red giants relative to the number of turnoff stars, when comparing with the predictions of canonical models. Using the Hipparcos parallaxes for subdwarfs, we estimate distance modulus, $(m-M)_o\;as\;14.75{\pm}0.12$. Using the R and R' method, we find helium abundances, Y(R) as $0.23{\pm}0.02$, Y(R') as $0.29{\pm}0.02$, respectively. Finally, the cluster' sage dispersion was deduced from 10.71 Gyr to 17 Gyr.

A Study on Coagulation Process using Zirconium Silicate as a Coagulation-aid (지르코늄 실리케이트를 응집보조제로 이용한 응집공정에 관한 연구)

  • Cho, Jae-Seung;Yoon, Tai-Il;Jeon, Yu-Jae;Cho, Kyung-Chul
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.3
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    • pp.203-207
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    • 2009
  • The concern of seriousness and harmful effects of environmental pollution is rising by the various water pollutions, appearances of new micro-noxious substances and increase of sustainable pollutants. The method is suggested that can effectively increase the removal of organic substances and several pollutants using a coagulation process. The experiment for characteristics of $ZrSiO_4$ (zirconium silicate) as a coagulation-aid was carried out for application to coagulation process with domestic wastewater and lake water, and the removal rate of the organic substances depending on a dosage was evaluated by PDA (Photometric Dispersion Analyzer) in this study. Zeta-potential of zirconium silicate solution was -32.22 mv at pH 7 and the lower negative(-) charge was detected in the more acidic conditions. Absorbance on $UV_{254}$ presented higher when zirconium silicate was added than in a domestic wastewater itself. Besides, the results by PDA experiment represented that injection of zirconium silicate could promote growing of floc. Tests for coagulation process were conducted by three ways which are pre-injection, co-injection and post-injection of zirconium silicate with alum. Accordingly, removal efficiency of organic substances increased over 15% in co-injection than in using of alum as a sole reagent. When a 20 mg/L of alum was used with a 10 mg/L of zirconium silicate, the removal efficiency was high up to 90%. Removal efficiency of $COD_{Cr}$ was improved more than 15% in case of dosage of coagulant either PAC (Poly aluminium chloride) or PACS (Poly aluminium chloride Silicate) together with zirconium silicate. As a result, the removal efficiency of $COD_{Cr}$ were 5~10% higher in a co-injection of zirconium silicate with a coagulant than a pre-injection and a post-injection but it of soluble substances was lower in a co-injection.