• Title/Summary/Keyword: UV peak

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On the UV and IR Spectra of Dioxane Lignin from Bamboo Culm (죽재(竹材) Dioxane Lignin의 UV, IR Spectrum에 대하여)

  • Moon, Chang-Kuck;Jo, Jong-Soo
    • Journal of the Korean Wood Science and Technology
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    • v.15 no.4
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    • pp.26-31
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    • 1987
  • The ultraviolet and infrared spectra of dioxane lignin from bamboo were investigated. 1. Spectrum curve type considerably resembled that of wood lignin. There were 3 absorption peak positions at 210nm(max. peak), at 260-270nm(shallow mini. peak), at 280nm(lower max. peak) as in the wood lignin spectra. 2. The lower minimum peak near at 280 nm is the typical peak of lignin. This peak does not exist exactly at 280 nm but from 282nm to 285nm in this bamboo UV spectra. The absorption intensities are equal in this region and the peak is not sharp. 3. The absorption band of aromatic nucleus is near at wave number $1550cm^{-1}$ in the IR spectra of bamboo lignin. The intensity at about 1040-$1130cm^{-1}$ and at about 1230-$1275cm^{-1}$ were similar in the hardwood lignin but reverse to that of softwood lignin spectrum.

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Dippy Time Dependence of Transmittance Edge and Half Point in the UV cut lens' manufacture (UV 차단렌즈의 제작에서 광 투과율 Edge 및 Half Point의 Dippy 시간의존성)

  • Kim, Yong-Geun
    • Journal of Korean Ophthalmic Optics Society
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    • v.6 no.1
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    • pp.101-105
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    • 2001
  • It was measured the transmittance and the reflectance by tie dip method using the UV cut lens' UV solution. The half point and the edge wavelength of the transmittance were wry well applied to the eqution of a dip time dependence. $$W=W_0+A_1{e}{x}{p}[-(x-x_1)/t_1]$$ The half point wavelength of the transmittance shifted from 358 nm to 408 nm and the edge wavelength moved from 340 nm to 398 nm. The more dip time had long the less intensity of main reflectance peak-380 nm was small and shifted to long wavelength regions. And the component peak of UV solution began to show in dip time-10 min.

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Intrinsic UV Reflection and Fluorescence Studies for Water Sorption in Polycarbonate, Polyurethane and Poly(Ethylene Terephthalate) Films

  • Kim Min Sun;Sung Chong Sook Paik
    • Fibers and Polymers
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    • v.6 no.2
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    • pp.127-130
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    • 2005
  • Intrinsic UV reflection and fluorescence behaviors of polycarbonate, polyurethane and poly(ethylene terephthalate) films were investigated in order to characterize the interaction of water in these films. During water sorption process, UV reflection spectra of polycarbonate and polyurethane films showed little peak position changes. Fluorescence emission spectra of polycarbonate films showed red spectral shifts from 332 nm with water immersion time. This red-shifted peak could be due to phenyl-2-phenoxybenzoate, which is one of the major thermal degradation products in polycarbonate. Fluorescence peaks of polyurethane films appeared at two different positions and the ratio of these peak intensities increased with increasing immersion time. In the case of PET films, the UV reflection spectrum showed the peak intensity around 340 nm to change in response to water sorption. The fluorescence near 388 nm probably due to ground state dimer exhibited sensitivity with water sorption, when excited at 340 nm.

The Optical Property of Plasma-treated ZnO Nanorods (플라즈마 처리한 ZnO 나노막대의 광학적 특성)

  • Cho, Hyun-Min;Yu, Se-Gi;Cho, Jae-Won
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.3
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    • pp.230-234
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    • 2009
  • Hydrogen and Oxygen plasma treatments have been done on sonochemical grow ZnO nanorods by varying treatment temperature and time, The changes(position and intensity) in ultraviolet(UV) peaks and green peaks of photoluminescence(PL) spectroscopy have been measured, Experimental results showed; i) in the case of hydrogen plasma treatment, the blue shift of UV peak and the increase of PL intensity of the UV peak were observed as the increase of the process time and temperature, ii) in the case of oxygen plasma treatment, the red shift of green peak was observed and the ratio of $I_{Green}/I_{UV}$ was also increased, as the increase of the process time and the temperature.

On the UV Spectra of AcBr Lignins from Softwoods grown in Mt. Jiri (지리산산(智異山産) 침엽수재(針葉樹材) AcBr Lignin의 UV Spectra에 대(對)하여)

  • Jo, Jong-Soo;Moon, Chang-Kuck
    • Journal of the Korean Wood Science and Technology
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    • v.12 no.3
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    • pp.35-40
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    • 1984
  • The ultraviolet absorption spectra of AcBr lignin (Acetyl Bromide lignin) from 10 species grown in Mt. Jiri were determined. There were 3 peak positions, at 249nm (max peak), at 267-268 nm (shallow min. peak) and at 280 nm (lower max. peak). The Bjorkman lignin and lignin sulfonic acid spectra had shoulders, but the AcBr lignin had not them. Average absorbances and absorptivities of the AcBr lignins at peak positions were $0.367{\pm}0.0015$, $24.56{\pm}0.0535$, at 249 nm, $0.278{\pm}0.0016$, $18.50{\pm}0.0569$, at 267-268 nm and $0.306{\pm}0.0016$, $20.42{\pm}0.0627$ at 280 nm, respectively.

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The Identification of Stilbene Compounds and the Change of Their Contents in UV-irradiated Grapevine Leaves (자외선 조사 포도 잎에서 Stilbene 화합물의 동정과 함량의 변화)

  • Choi, Seong-Jin
    • Horticultural Science & Technology
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    • v.29 no.4
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    • pp.374-381
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    • 2011
  • Stilbenes are polyphenolic natural products, which have antioxidative and antifungal activities. In some plants, including grapevine, the stilbene compounds, as resveratrol derivatives, exist in very diverse forms. Experiments to identify the individual stilbene compounds were carried out first to quantify them in UV-irradiated grapevine leaves. For this, stilbene glycosides were extracted from grapevine leaves which irradiated intensively with UV light. The glycoside samples were hydrolyzed by ${\beta}$-glucosidase, before analyzed by HPLC-mass spectrometer at each m/z corresponding to the mass of specific stilbenes. As results, in chromatograms, the enzymatic hydrolysis resulted in decrease and increase of the peaks expected for glycosides and aglycones, respectively. The samples were also exposed to sunlight in order to photo-isomerize the stilbene compounds. The light exposure resulted in disappearance and appearance of peaks expected for trans- and cis-isomers of stilbenes, respectively. Such a change of the peaks in chromatograms provided information needed for the inference to peak components. In this way, it was possible to identify 16 kinds of stilbene compounds from grapevine leaves. The identified stilbenes were quantified from grapevine leaves irradiated mildly by UV light. The UV-irradiation increased markedly in the content of stilbene compounds, especially trans-resveratrol by several hundredfold. In addition, piceatannol, which is a mere minor component of stilbenes in control leaves and a more active radical scavenger than resveratrol, was also increased by several tenfold by the treatment. The increase in stilbene contents as influenced by UV irradiation seems to be one of the stress coping responses of grapevine as a hormesis phenomenon.

Influence of UV-B Radiation on Photosynthesis, Growth and Pigmentation of Chondrus ocellatus (Rhodophyta) from Shallow Water

  • Taejun Han;Han, Young-Seok;Cho, Man-Gee;Park, Jin-Hee;Goo, Jae-Gun;Kang, Sung-Ho
    • Korean Journal of Environmental Biology
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    • v.21 no.4
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    • pp.368-376
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    • 2003
  • The UV-B sensitivity was tested for the intertidal species Chondrus ocellatus from Korea, by measuring photosynthesis estimated as effective quantum yield ($\Phi_{PSII}$) of photosystem II (PS II), growth and content and composition of photosynthetic pigments and UV-absorbing pigments (UVAPs). The $$\Phi_{PSII}$ of the alga decreased with increasing time of exposure to UV-B radiation, followed by fast and nearly full recovery indicating dynamic photoinhibiton. Fresh weight-based growth and pigment contents of C. ocellatus were not seriously affected by UV-B radiation. A single broad peak at 327 nm was obtained from methanol extracts of C. ocellatus, and the absorbance peak increased with increasing UV. The single peak was resolved into three peaks (311, 330 and 336 nm) by the fourth -derivative, and quantitative change in response to UV-B radiation occurred only at 330 nm. High performance liquid chromatography (HPLC) analysis of purified extracts indicated that three MAAs (mycosporine-like amino acids) are present, asterina 330, palythine and shinorine. Field observations during three growing months showed that C. ocellatus exhibit the highest amount of UVAPs in May followed by July and little trace in September, coinciding with the species' phenology. In an ecological context, dynamic photoinhibition as well as accumulation of UVAPs may enable the shallow water red alga C. ocellatus to be well adapted to high UV-B environments.

A Study on the Effect of O$_2$ annealing on Structural, Optical, and Electrical Characteristics of Undoped ZnO Thin Films Deposited by Magnetron Sputtering (산소 어닐링이 마그네 트론 스퍼터링으로 증착된 undoped ZnO박막의 구조적, 광학적, 전기적 특성에 미치는 영향에 대한 연구)

  • Yun, Eui-Jung;Park, Hyeong-Sik
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.46 no.7
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    • pp.7-14
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    • 2009
  • In this paper, the effects of annealing conditions on the structural ((002) intensity, FWHM, d-spacing, grain size, (002) peak position), optical (UV peak, UV peak position) and electrical properties (carrier concentrations, resistivity, mobility) of ZnO films were investigated. ZnO films were deposited onto SiO$_2$/si substrates by RF magnetron sputtering from a ZnO target. The substrate was not heated during deposition. ZnO films were annealed in temperature ranges of $500\sim650^{\circ}C$ in the O$_2$ flow for 5$\sim$20 min. The film average thicknesses were in the range of 291 nm. The surface morphologies and structures of the samples were characterize by SEM and XRD, respectively. The optical properties were evaluated by photoluminescence (PL) measurement at room temperature (RT) using a He-Cd 325 nm laser. As the annealing temperature and time vary, the following relations were also observed: (1) proportional relationships among UV intensity (002) intensity, and grain size exist, (2) UV intensity is inversely proportional to FWHM, (3) there is no special relationship between UV intensity and electron carrier concentrations, (4) d-spacing is inversely proportional to (002) peak position, (5) UV peak position in the range of 3.20$\sim$3.24 eV means that ZnO films have a n-type conductivity which was consistent with that obtained from the electrical property, (6) the optimal conditions for the best optical and structural characteristics were found to be oxygen fraction, (O$_2$/(O$_2$+Ar)) of 0.2, RF power of 240W, substrate temperature of RT, annealing condition of 600$^{\circ}C$ for 20 min, and sputtering pressure of 20 mTorr.

Apodization of Linearly Chirped Fiber Gratings for Dispersion Compensation (색분산 보상을 위한 선형 첩 광섬유 격자의 Apodization)

  • 박제형;최선민;한영근;김상혁;이상배
    • Korean Journal of Optics and Photonics
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    • v.15 no.3
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    • pp.214-221
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    • 2004
  • We theoretically and experimentally investigate the effect of apodization on the transmission characteristics of linearly chirped fiber Bragg gratings(CFBGs). Based on the UV beam scanning method along a phase mask, we fabricated several apodized CFBGs with different apodization profiles such as Gaussian, Raised-cosine, Blackman, and Hyperbolic tangent. During the UV beam scanning, the phase mask is dithered by a PZT(Piezoelectric transducer) which is precisely controlled by a computer program so that the apodization profiles can be flexibly applied to the grating. We measured the reflection spectra and group delay characteristics of CFBGs with the different apodization profiles, and compared them according to their properties such as reflectivity, sidelobes, and group delay ripple (GDR). The peak-to-peak of GDR could be suppressed to less than 20 ps.

A Novel Ultraviolet Sensor using Photoluminescent Porous Silicon (광 루미네슨스 다공질 실리콘을 이용한 새로운 자외선 센서)

  • Min, Nam-Gi;Go, Ju-Yeol;Gang, Cheol-Gu
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.50 no.9
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    • pp.444-449
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    • 2001
  • In this paper, a novel ultraviolet sensor is presented based on a photoluminescent porous silicon. Porous silicon layer was formed by chemical etching of surface of pn junction in a $HF(48%)-HNO_3(60%)-H_20$ solution. Incident ultraviolet(UV) light is converted to visible light by photoluminescent porous silicon layer, and then this visible light generates electron-hole pairs in the pn junction, which produces a photocurrent flow through the device. In order to maximize detection efficiency, the peak sensitivity wavelength of the pn junction diode was matched with the peak wavelength of Photoluminescence from porous silicon layer. The porous silicon ultraviolet sensor showed a large output current as UV intensity increases and but very low sensitivity to visible light. The detection sensitivity of porous silicon sensor was calculated as 2.91mA/mW. These results are expected to open up a possibility that the present porous silicon sensor can be used for detecting UV light in a visible background, compared to silicon UV detectors which have an undesirable response to visible light.

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