• Title/Summary/Keyword: UV exposure

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Effects of UV Absorber and HALS(Hindered Amine Light Stabilizer) Addition in Water-soluble Acrylic Resin on Discoloration of Larix leptolepis (S. et Z.) Gordon (수용성(水溶性) 아크릴 수지(樹脂)의 자외선(紫外線) 흡수제(吸收劑)와 HALS 첨가(添加)가 일본잎갈나무의 변색(變色)에 미치는 영향(影響))

  • Kang, Kyoung-Taek;Lee, Phil-Woo
    • Journal of the Korean Wood Science and Technology
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    • v.24 no.4
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    • pp.47-55
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    • 1996
  • UV transmission spectra of water-soluble acrylic resin films containing hydroxybenzophenolic, hydroxyphenylbenzotriazolic UV absorber and HALS(hindered amine light stabilizer) were investigated by exposure time(before exposure weathered for 160 and 320hours) in QUV Weather-Ometer. Also the YID(yellowness index difference), LID(lightness index difference) and CD(color difference) of dried water-soluble acrylic resin films and the coated woods of Larix leptolepis were analyzed by addition level of UV absorber(0, 1, 2 and 3%) and HALS(0, 0.5, 1 and 1.5%) and by exposure time in QUV Weather-Ometer. They showed no significant effects on UV transmission spectra of dried water-soluble acrylic resin films in the range of 300 to 400nm irrespective of exposure time. However, UV transmission decreased as increase of exposure time. UV transmission spectra were lower in dried water-soluble acrylic resin films containing hydroxybenzophenolic UV absorber and HALS than in these containing hydroxyphenylbenzotriazolic UV absorber and HALS in the range of 350 to 400nm. The least YID, LID and CD in the coated woods of Larix leptolepis appeared at the addition level of 3%, based on non-volatile content, in hydroxybenzophenolic and hydroxyphenylbenzotriazolic UV absorber, and of 1.5% in HALS to water-soluble acrylic resin.

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A Study on Photofading of Cellulose Fabrics Dyed with Safflower Red Colorants (홍화의 홍색소로 염색한 셀룰로오스계 직물의 광변퇴색 고찰)

  • Shin, Youn-Sook;Choi, Seung-Youn
    • Journal of the Korean Home Economics Association
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    • v.46 no.10
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    • pp.1-9
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    • 2008
  • The purpose of this study was to increase uv-cut ability of cotton, ramie, and rayon fabrics dyed with safflower red colorants. For this purpose, samples treated with uv-cut agent and tannic acid were compared with the untreated samples after ultraviolet(uv)-light exposure in terms of K/S value, color changes(${\Delta}E$), SEM, and tensile strength retention. K/S value rapidly decreased with increasing exposure time, but K/S value of the samples treated with both uv-cut agent and tannic acid decreased less than that of untreated samples. As increasing exposure time, $L^*$ and $b^*$ increased, $a^*$ decreased, and so ${\Delta}E$ increased, indicating less red character and more yellow character in color. This leads to change hue, value and chroma value. But color change of samples treated with both uv-cut agent and tannic acid was less than that of untreated samples. SEM pictures showed a severe degradation by uv exposure in all samples. Tensile strength slowly decreased for 21 days. And after this point, the decreased proceeded more rapidly. Tensile strength retention of the samples treated with uv-cut agent and tannic acid was higher than that of untreated samples.

Control of Pretilt Angle by UV exposure during Imidization of Polyimide for Homeotropic Alignment (수직 배향용 폴리미이드의 소성시에 UV 조사를 이용한 프리틸트각 제어)

  • 황정연;서대식;한은주;갬재형
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.11
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    • pp.950-953
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    • 2000
  • Aligning capabilities of nematic liquid crystal(NLC) using an in-situ photo-alignment method with obliquely polarized UV exposure on a polyimide (PI) surface for homeotropic alignment were studied. The high angle for NLC can be measured by obliquely UV exposure of 30°on the PI surface for 10∼20 min. The pretilt angle of NLC generated using the in-situ photo-alignment was higher than that of a conventional photo-alignment method. Finally, we suggest that the control of pretilt angle in NLC with obliquely polarized UV exposure during imidization of the polymer for homeotropic alignment is promising method to generate high pretilt angle.

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Photodegradation stability study of PVDF- and PEI-based membranes for oily wastewater treatment process

  • Ong, C.S.;Lau, W.J.;Al-anzi, B.;Ismail, A.F.
    • Membrane and Water Treatment
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    • v.8 no.3
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    • pp.211-223
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    • 2017
  • In this work, an attempt was made to compare the effects of UV irradiation on the intrinsic and separation properties of membranes made of two different polymeric materials, i.e., polyvinylidene fluoride (PVDF) and polyetherimide (PEI). The changes on membrane structural morphologies and chemical characteristics upon UV-A exposure (up to 60 h) were studied by FESEM and FTIR, respectively. It was found that cracks and fractures were detected on the PVDF-based membrane surface when the membrane was exposed directly to UV light for up to 60 h. Furthermore, the mechanical strength and thermal stability of irradiated PVDF-based membrane was reported to decrease with increasing UV exposure time. The PEI membrane surface meanwhile remained almost intact throughout the entire UV irradiation process. Filtration experiments showed that the permeate flux of UV-irradiated PVDF membrane was significantly increased from approximately 11 to $16L/m^2.h$ with increasing UV exposure time from zero to 60 h. Oil rejection meanwhile was decreased from 98 to 85%. For the PEI-based membrane, oil rejection of >97% was recorded and its overall structural integrity was marginally affected throughout the entire UV irradiation process. The findings of this work showed that the PEI-based membrane should be considered as the host for photocatalyts incorporation if the membrane was to be used for UV-assisted wastewater treatment process.

Fabrication of Disposable Light Exposure Detector Kit using UV Curable Hydrogels (자외선 경화 하이드로겔을 사용한 일회용 빛 노출 검출 키트의 제조와 특성분석)

  • Kim, Young Ho;Kim, Gyu-Man;Dang, Trung Dung;Choi, Jin Ho;Kim, Hwan-Gon;Park, Sangju;Lee, Sang Hak
    • Applied Chemistry
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    • v.15 no.1
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    • pp.17-20
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    • 2011
  • A disposable light exposure detector kit has been developed by UV curing of a hydrogel material. The devised light exposure detector kit consisted of light sensitive structures, bottom plate, character sheet and sticky back plate. A light exposure detector kit has a serial light sensitive structures that contain various light sensitive dyes such as rhodamine and fluorescein. The light sensitive structure composed of UV curable hydrogel polymer material as a supporing material and photosensitive dye in a certain concentration. The fabrication procedure of the ligh exposure detector kit is very simple and fast due to UV curing procedure of a photopolymerizable hydrogel material such as poly(ethylene glycol) methyl ether acrylate (PEGMEA) and poly(ethylene glycol) diacrylate (PEGDA) with a photosensitive dye. By the proposed fabrication method, various size and shape of a light exposure detector kit could be fabricated using a flexible elastomer mold. Due to a fast and inexpensive fabrication method, the light exposure detector kit could be use a single use for various industrial applications. According to light irradation, the light sensitive structure on a light exposure detector kit could be lose its color by decomposition of a photosensitive dye chemical in the structure. Thus the amount of the exposed light on a substrate could easily be recognised by changing color or transparency of the structure.

Control of Pretilt Angles on Various Photo-Crosslinkable Polyimide based Polymers by Photodimerization

  • Hwang, Jeoung-Yeon;Seo, Dae-Shik;Suh, Dong-Hack
    • KIEE International Transactions on Electrophysics and Applications
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    • v.11C no.4
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    • pp.133-137
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    • 2001
  • In this research, we synthesized various photo-crosslinkable polyimide based polymers. The control of pretilt angles for a nematic liquid crystal (NLC) using the photodimerization method on the photopolymers was studied. A good thermal stability of the photopolymers was measured by thermogravimetric analysis (TGA) measurement until 450C. High pretilt angles of the NLC were otained by polarized UV exposure on the photopolymers containing biphenyl (BP), decyl (de), and cholesteryl (chal) groups, respectively. However, low pretilt angles of the NLC were measured by polarized UV exposure on the photopolymers containing fluorine and chalcone groups. The high NLC pretilt angles generated are attributable to the biphenyl and alkyl moieties, and the photodimerized chalocone group of the photopolymers. Additionally, good voltage-transmittance and response time characteristics were observed by UV exposure on the photopolymers.

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The Effect of Temperature and Exposure Time on UV-curing of Urethane Acrylate (UV 챔버 내부 온도 및 체류시간이 Urethane Acrylate의 경화속도에 미치는 영향)

  • Moon, Seung-Ho;Kim, Kwang-Hee;Kim, Jeong-Sik
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.9
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    • pp.3822-3826
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    • 2012
  • We have studied the effect of temperature and exposure time on the UV curing rate of Urethane Acrylate. UV dose has been modulated by changing the electric power, and temperature has been controled by coating rate and water temperature of the coating roll. Curing rate was evaluated by measuring gel fraction of the cured film. It has been found that effect of coating velocity on the gel fraction of the final film is predominant, but role of temperature of the UV chamber is negligible. These observations imply that exposure time of UV light is critical to have a fully cured film. To better understand the effect of design and operating condition of UV coater on the behavior of UV curing of Urethane Acrylate, we have also conducted heat-flux analysis of UV chamber.

Comparison of Biological Responses and Heat Shock Protein 70 Expression in Chironomidae by Exposure UV and O3 (UV와 O3 노출에 따른 깔따구류의 생물학적 반응 및 열충격 단백질 70 발현)

  • Ji-Hoon Kim;Won-Seok Kim;Jae-Won Park;Bong-Soon Ko;Kiyun Park;Ihn-Sil Kwak
    • Korean Journal of Ecology and Environment
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    • v.56 no.4
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    • pp.430-439
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    • 2023
  • UV and O3 are materials used in the water treatment process, and many studies have been reported to remove organic matters, contaminants, and microorganisms. In this study, we were investigated effects of Chirnomidae (Chironomus flaviplumus, Chironomus riparius), which are contamination indicator species to exposure UV and O3 for the survival rate, body color change and gene expression response. The survival rate of C. flaviplumus exposed to UV decreased to about 70% after 24 hours, and C. riparius about 50%. There was no change in the survival rate of C. flaviplumus exposed to O3, and C. riparius decreased to 95% after 10 minutes of exposure, but there was no change during the subsequent exposure time. In addition, UV and O3 exposure to the two species in body color faded in a time-dependent. In the HSP70 gene expression, C. riparius showed an increase in expression after UV exposure compared to the control group, and a significant difference was shown 12 hours after exposure (P<0.05). C. flaviplumus exposed to O3 showed a relatively low expression compared to the control group, and showed a significant difference at 10 minutes and 1 hour after exposure (P<0.05). These results reported the ecotoxicological effects on Chironomidae according to UV and O3 exposure. Therefore, the results of this study can be used as basic data to understand the effects of UV and O3, which are disinfectants used in water treatment plants, on Chirnomidae entering plants.

Alignment Effect of Liquid Crystal on new organics thin film using Ultraviolet Exposure method (UV 조사법을 이용한 새로운 무기박막 표면에 액정 배향 효과)

  • Hwang, Jeoung-Yeon;Kang, Hyung-Ku;Choi, Sung-Ho;Oh, Byeong-Yun;Ham, Moon-Ho;Myoung, Jae-Min;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.05a
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    • pp.62-65
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    • 2005
  • We studied the nematic liquid crystal (NLC) alignment capability by the Ultraviolet (UV) alignment method on a-C:H thin-films, and investigated electro-optical performances of the UV aligned twisted nematic (TN)-liquid crystal display (LCD) with the UV exposure on a-C:H thin film surface. A good LC alignment by UV irradiation on a-C:H thin-film surfaces was achieved. Monodomain alignment of the UV aligned TN-LCD can be observed. The good electro-optical (EO) characteristics of the UV aligned TN-LCD was observed with oblique UV exposure on the a-C:H thin film surface for 1min.

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Effect of Photopolymerization on the Rate of Photocrosslink in Chalcone-based Oligomeric Compounds

  • Choe, Dong Hun;O, Sang Jun;Ban, Si Yeong;O, Gwang Yong
    • Bulletin of the Korean Chemical Society
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    • v.22 no.11
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    • pp.1207-1212
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    • 2001
  • A new photochemically bifunctional epoxy and dimethacrylate compounds were synthesized for investigating the photosensitivity under UV irradiation. Photosensitivity of the synthesized chalcone-based compounds was investigated by using UV-visible absorption and Fourier transformed infrared (FT-IR) spectroscopies. The result of spectroscopic analysis substantiated that the two chalcone-based compounds have functions of both photocrosslinking and photopolymerization by UV exposure in the presence of photoinitiator. Two kinds of photochemical reactions proceeded competitively during UV exposure. Particularly, we studied the effect of photopolymerization on the rate of photocrosslink due to cycloaddition in the two oligomeric compounds.