• 제목/요약/키워드: UV absorbance

검색결과 411건 처리시간 0.033초

Encapsulation of 2,4-Dihydroxybenzophenone into Dodecylbenzenesulfonate Modified Layered Double Hydroxide for UV Absorption Properties

  • Li, Shifeng;Shen, Yanming;Liu, Dongbin;Fan, Lihui;Wu, Keke
    • Bulletin of the Korean Chemical Society
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    • 제35권2호
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    • pp.392-396
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    • 2014
  • New organic-inorganic composite of 2,4-dihydroxybenzophenone (BP-1) encapsulation into dodecylbenzenesulfonate (DBS) modified layered double hydroxide (LDH) was successfully prepared. The surface, structural, thermal and absorption properties of the BP-1/DBS-LDH nanohybrid was characterized by BET analysis, scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TG) and diffuse reflectance UV-Vis absorbance spectra (DRUV-vis). The interlayer configuration of composite and the adsorption mechanism of BP-1 on MgAl-DBS-LDH were discussed. It was suspected that DBS anions located in the form of monolayer arrangement with a $75^{\circ}$ anti parallel angle between dodecylbenzenesulfonate chain axis. The diffuse reflectance UV-Vis absorbance results revealed that the UV absorbing wavelength of BP-1/DBS-LDH evidently extends to about 400 nm, which shows that the BP-1/DBS-LDH has the potential application as a UV absorber.

광기능성 폴리머 도파로형 자외선 센서의 제작 및 특성 (Fabrication and characteristics of photofunctional polymer waveguide-type UV sensor)

  • 김규진;장수원;강병호;김도억;권대혁;김성훈;이용현;강신원
    • 센서학회지
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    • 제15권4호
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    • pp.231-236
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    • 2006
  • Single-mode planar waveguide type UV sensor was fabricated using SU-8 and photochromic dye. Polymer waveguide was fabricated $10{\mu}m$ width and $2{\mu}m$ thickness for single-mode operation. The UV sensor had an absorbance with $0.0396{\sim}0.114$ absorbance/mW respectively when the 5 mm sensing area was irradiated with UV for 3 sec. And sensor had a linear properties by sensing area variation. Proposed single-mode sensor had more excellent properties of UV sensitivity than other UV sensors.

가감서시옥용산의 미백효과에 관한 연구 (Depigmentation activity of Kakamseosiokyong-san)

  • 손동석;김윤범
    • 한방안이비인후피부과학회지
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    • 제15권2호
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    • pp.104-117
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    • 2002
  • Objective : The aim of this study was to investigate the skin-whitening effect of Kakamseosiokyong-san Method : We investigated that the extracts of Kakamseosiokyong-san inhibit activity of tyrosinase, the enzyme which converts 3-(3,4-dihydroxyphenyl)alanine to dopachrom in the biosynthetic process of melanin. the UV absorbance of the extracts in the UV - A region and UV - B region was measured by UV scanning. the effect of extracts on cell viability and melanin production in cultured B16 mouse melanoma cells was measured, and cytoprotective effects of extracts on PC12 cells injured by hydrogen peroxide was measured by MTT assay Results: The extracts of Kakamseosiokyong-san inhibited activity of tyrosinase. The extracts not only showed inhibitory effects on melanin production in cultured B16 mouse melanoma cells, but also exhibited cytoprotective effects on PC12 cells injured by hydrogen peroxide, but did not showed an absorbance in the UV - A region and UV - B region. Conclusion: These results suggest that Kakamseosiokyong-san inhibit melanin biosynthesis which is involved in hyperpigmentation and could be used as a whitening agent for the skin.

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Enhanced UV-Visible Absorbance Detection in Capillary Electrophoresis Using Modified T-Shaped Post-Column Flow Cell

  • Lim, Kwan-Seop;Kim, Su-Hyeon;Hahn, Jong-Hoon
    • Bulletin of the Korean Chemical Society
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    • 제23권2호
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    • pp.295-300
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    • 2002
  • The construction of the T-shaped post-column flow cell has been changed to enhance the practicability as a UV-visible absorbance detector for capillary electrophoresis. In this new design, a rectangular cube-shaped inner structure is employed, which completely fits the outer rectangular tubing. This arrangement has greatly facilitated the fabrication of the T-cells. In addition, the volume for the auxiliary flow has been dramatically reduced down to 300 ${\mu}L$, and its volume flow rate is optimized at 4.2 ${\mu}L$/min. The short optical path length in the sheath flows (500 ${\mu}m$ on each side) minimizes background absorption, and thus enhances its performance in low-UV wavelengths. We have optimized the auxiliary flow rate at 50 ${\mu}m$/s, so that migration times are insensitive to the flow rate. This optimization has improved repeatabilities in migration times and peak heights. A double-beam detection scheme using a pair of photodiodes is employed to increase the signal-to-noise ratio.

Rutile-$TiO_2$를 이용한 Mordant Yellow-12의 광촉매 분해반응 (Photocatalytic Destruction of a Mordant Yellow-12 Using Rutile-$TiO_2$)

  • 김창석;최인원
    • 분석과학
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    • 제13권5호
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    • pp.646-651
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    • 2000
  • $TiO_2$ 촉매 하에 염료 Mordant Yellow-12를 광촉매 분해하였다. 이때 사용한 광원은 각각 15-W, 21-W와 26-W 형광 램프를 이용하였다. 분해 정도는 자외선-가시광선 분광기와 pH 메타를 이용하였다. 실험 결과 반응 1시간 후에 각 광원에 따라 각각 17%, 24%, 34% 이상의 분해를 보였고 완전히 분해되는데는 각각 3, 4, 5시간 걸렸다. pH의 변화는 흡광도의 변화와 같이 급격한 결과를 나타내지 않았다. 분해 반응 속도는 15-W 보다 26-W에서 2배의 빠를 분해 반응속도를 보였다.

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흡광도법에 의한 주상변압기 절연유의 열화판정기준 설정에 관한 연구 (A Study on Suggestion of Insulating Oil Ageing Degree in Pole-Transformer by Absorbance)

  • 이동준;정종욱;김경화;곽희로;윤영자
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1996년도 하계학술대회 논문집 C
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    • pp.1851-1853
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    • 1996
  • In this paper the criteria for insulating oil condition of pole transformer were suggested by applying the UV-Visible spectrophotometric method. Ageing of insulating oil caused the change in absorbances of oil os well os the deterioration of electrical properties of oil. By comparing the electrical properties such as $tan{\delta}$ and breakdown voltage with the UV-Visible absorbances of oil, criteria for absorbance values determining oil condition were established. This UV-Visible spectrophotometric method might be applied in ageing analysis of oil and be expected to replace the current method.

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지방산과 인지질의 혼합비에 따른 단분자 LB막의 광이성질화 현상에 관한 연구 (Photoisomerization of Monolayer LB Films mixed with Fatty Acid and Phospholipid at mixture ratios)

  • 박근호;강동완;김성일;박태곤
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.479-482
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    • 2000
  • We investigated UV-vis absorbances to observe photoisimerization and effect of temperature using the mixture solution in chloroform and the LB monolayer mixed with DLPE and 8A5H containing azobenzene which shows reversible cis-trans isomerization irradiated by alternate lights. We could find that the absorption spectrum of the mixtures solution and LB monolayer was reversibly induced to photoisomerization irradiated by Uv of both and visible lights, in addition the absorbance by alternate temperatures.

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A Study of the Ionic Association of the Substituted N-Methyl Pyridinium Iodide (II), 4,N-Dimethyl Pyridinium Iodide in Ethanol-Water Mixture

  • Kwun, Oh-Cheun;Jee, Jong-Gi
    • Bulletin of the Korean Chemical Society
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    • 제6권1호
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    • pp.37-40
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    • 1985
  • The electrical conductance and UV absorbance of 4,N-dimethyl Pridinium Iodide (NDMPI) were measured in the ethanol volume percentage, 95, 90, 80 and 60 of an ethanol-water mixture at 15, 25, 35 and $45^{\circ}C$. Ionic association constants(K) of NDMPI were evaluated in accordance with a combined method of conductance UV absorbance. The ion size parameter (${\gamma}_{\pm}$) and dipole momemt (${\mu}_{A+D-}$) of NDMPI were obtained from the values of K and dielectric constant. The ${\mu}_{A+D-}$- values were in good agreement with the values of transition moment(${\mu}_{mn}$) which is calculated form the UV peak values. The large negative values of the electrical enthalpy (${\Delta}H_{el}^{\circ}$) and entropy (${\Delta}H_{el}^{\circ}$ ) have proved that NDMPI had a positive hydration. The positive values of entropy (${\Delta}S^{\circ}$) means the formation of NDMPI ion goes with dehydration.

졸-겔공정에 의해 실리카 구조체에 도입된 유기 NLO 물질의 특성 (Characteristics of Organic NLO Materials in Silica Matrix Prepared by Sol-gel Process)

  • 정미원;문정호;설용건
    • 공업화학
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    • 제4권3호
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    • pp.482-487
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    • 1993
  • 반응성과 성형성이 우수한 졸-겔법을 이용하여 비선형 광학물질인MNA(2-Methyl-4-nitro-aniline), Carbazole 1(5-Nitro-9-hydroxyethyl Carbazole), Carbazole 2(5-Nitro-9-ethyl Carbazole) 그리고 DR1(Disperse Red 1)을 Silica matrix에 조합시킨 유-무기계 복합박막을 제조하였다. 이들 유-무기계 복합박막의 열적 안정도와 분해정도를 비교한 결과 -OH기를 갖는 Carbazole 1과 DR 1이 열분해에 대한 안정성이 우수하다는 것을 알았다. Carbazole 1의 편극화 처리로 UV 흡광도의 현저한 감소가 일어났고 상온에서 전기장을 제거하자 UV 흡광도의 느린 회복이 발견되었다.

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Clay Coating for UV Resistant Nylon Fiber

  • Usami, Hisanao;Taniguchi, Akinori;Fujimatsu, Hitoshi;Suzuki, Eiji
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2003년도 The Korea-Japan Joint Symposium
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    • pp.57-58
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    • 2003
  • Thin coating layer of clay minerals was fabricated on nylon fiber and uv-light resistivity of the clay-coated nylons, schematically shown in Figure 1, were investigated. Clay minerals with higher absorbance protect the nylon fibers more effectively from uv light. The coating process is expected as safe and stable procedure because clay and aqueous dispersion of the clay used for the process is innocuous.

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