• Title/Summary/Keyword: UV Modification

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Modification of Dyeing Property of Polyester Fabrics by UV Irradiation (UV조사에 의한 Polyester직물의 염색성 개질)

  • 배중석;김인회
    • Textile Coloration and Finishing
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    • v.13 no.4
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    • pp.256-263
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    • 2001
  • Polyester fabrics were irradiated by UV produced by the low pressure mercury lamp. UV irradiation broke a C-H bond of PET fiber and caused the carbonyl groups on the fiber surfaces. Surface modification of PET fibers were accelerated by pretreatment with methanol, ethanol and acetone. The irradiated PET was dyed with basic dyes having cationic groups. The dye uptakes were proportional to irradiation times, and in inversely proportional to irradiation distances. The tensile strengths of PET fabrics decreased by UV irradiation. Washing fastness of PET dyeings were good, about 4-5 grade,andlightfastnesswerepoor, about l grade.

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Hydrophilic Modification of Polypropylene Hollow Fiber Membrane by Dip Coating, UV Irradiation and Plasma Treatment

  • Kim Hyun-Il;Kim Jin Ho;Kim Sung Soo
    • Korean Membrane Journal
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    • v.7 no.1
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    • pp.19-27
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    • 2005
  • PP hollow fiber membrane was hydrophilized by EVOH dip coating followed by low temperature plasma treatment and UV irradiation. EVOH coating attained high water flux without any prewetting but its stability did not guaranteed at high water permeation rate. At high water permeation rate, water flux declined gradually due to swelling and delamination of the EVOH coating layer causing pore blocking effect. However, plasma treatment reduces the swelling, which suppress delamination of the EVOH coating layer from PP support result in relieving the flux decline. Also, UV irradiation helped the crosslinking of the EVOH coating layer to enhance the performance at low water permeation rate. FT-IR and ESCA analyses reveal that EVOH dip coating performed homogeneously through not only membrane surface but also matrix. Thermogram of EVOH film modified plasma treatment and W irradiation show that crosslinking density of EVOH layer increased. Chemical modification by plasma treatment and UV irradiation stabilized the hydrophilic coating layer to increase the critical flux of the submerged membrane.

Surface Modification of PET Irradiated by Ultra-Violet (Part I) -Transformation of Chemical Structure and Surface Properties- (UV조사를 통한 PET의 표면개질 (제1보) -화학구조 변화 및 표면특성 변화-)

  • Choi Hae Young;Lee Jung Soon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.29 no.3_4 s.141
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    • pp.561-568
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    • 2005
  • The irradiation of Ultra-Violet (UV) is an efficient treatment for polymer to improve hydrophilic properties. 4-Channel PET knit fabrics were treated with UVA and UVC to develop functional and environment-friendly fabric. The fabric was treated with various treatment times and distances from UV lamps having different wavelength. FT-IR and XPS investigated the chemical changes. To confirm the change of surface properties, contact angle, surface energy and SEM were examined. The study of UV as a treatment for PET knit fabric shows significant changes in chemical and surface properties, which is proved by analyses. FT-IR and XPS analyses prove the augmentation of carboxylic, Hydrophilic groups on the surfaces treated by UV. The increase of water contact angle and surface energy means more water wettable and surface energy of PET film was substantially increased by UV irradiation time. The ageing after surface treatment had little influence on the surface energy of the irradiated PET film. SEM proves the surface modification of PET such as etching, bubble and crack. The negative effects are increased in accordance with increasing treatment time.

Surface Modification of PET Irradiated by Ultra-Violet (Part II) - Transformation of moisture properties and physical Properties - (UV조사를 통한 PET의 표면개질(제2보) -수분특성 및 물리적 특성 변화-)

  • Choi Hae Young;Lee Jung Soon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.29 no.5 s.142
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    • pp.617-625
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    • 2005
  • The purpose of this study was to develop functional and environment-friendly polyester fabric by irradiating Ultra-Violet, which was produced by the low-pressure mercury lamp. UV irradiation was conducted with various treatment times and distances. Also, pretreatments of solvents and photoinitiator were used to improve the surface modification effects. The effects of UV irradiation on the moisture regain were found to increase gradually with increase of UV treatment time and decrease of treatment distance. Compared the effects of UVC and UVA, UVC was more effective than UVA. Moisture regain and wicking of PET was increased after UV treatment in our experimental condition. And owing to increasing of moisture regain, static charge was decreased. Pretreatment of solvents such as methanol, ethyl ether and addition of photoinitiator such as Benzophenone accelerated surface modification. The moisture regain was increased but wicking was decreased with pretreatment and addition of photoinitiatior. Therefore it is considered as inappropriate f3r clothing because of wicking effects. Yellowness, tensile strength and elasticity slightly decreased after UV irradiation.

Thermoplastic Fusion Bonding of UV Modified PMMA Microfluidic Devices (UV 개질된 PMMA 미세유체 장치의 열가소성 폴리머 용융 접합)

  • Park, Taehyun
    • Journal of the Korean Society for Precision Engineering
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    • v.31 no.5
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    • pp.441-449
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    • 2014
  • Thermoplastic fusion bonding is widely used to seal polymer microfluidic devices and optimal bonding protocol is required to obtain a successful bonding, strong bonding force without channel deformation. Besides, UV modification of the PMMA (poly-methyl methacrylate) is commonly used for chemical or biological application before the bonding process. However, study of thermal bonding for the UV modified PMMA was not reported yet. Unlike pristine PMMA, the optimal bonding parameters of the UV modified PMMA were $103^{\circ}C$, 71 kPa, and 35 minutes. A very low aspect ratio micro channel (AR=1:100, $20{\mu}m$ depth and $2000{\mu}m$ width) was successfully bonded (over 95%, n>100). Moreover, thermal bonding of multi stack PMMA chips was successfully demonstrated in this study. The results may applicable to fabricate a complex 3 dimensional microchannel networks.

Preparation and Characterization of Muscovite Mica/UV Coating Materials for Steel

  • Cheong, In-Woo;Kim, Hyeon-Seok;Hwang, Dong-Seop;Yoo, Hye-Jin;Kim, Jin-Tae;Lee, Jae-Ryung
    • Corrosion Science and Technology
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    • v.9 no.6
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    • pp.265-269
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    • 2010
  • This paper describes the exfoliation and surface modification of muscovite mica for UV coating formulation. For the exfoliation of the mica, hydrothermal process was used in the presence of lithium nitrate ($LiNO_3$). After the cation exchange with $Li^+$ ions, the surface of the mica was modified with several amphiphilic substances to increase compatibility and storage stability in UV coating formulation. Such a hydrophobic surface modification affected colloidal stability as well as dispersibility of the exfoliated mica in UV coating solution. Anticorrosive property of mica/UV coated steel plates was tested by salt spray test (SST) and compared with sodium montmorillonite ($Na^+$-MMT)/UV coated steel plates.

Surface modification of polymeric membranes for low protein binding

  • Higuchi, Akon;Tamai, Miho;Tagawa, Yoh-Ichi;Chang, Yung;Ling, Qing-Dong
    • Membrane and Water Treatment
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    • v.1 no.2
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    • pp.103-120
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    • 2010
  • Surface modification of microfiltration and ultrafiltration membranes has been widely used to improve the protein adsorption resistance and permeation properties of hydrophobic membranes. Several surface modification methods for converting conventional membranes into low-protein-binding membranes are reviewed. They are categorized as either physical modification or chemical modification of the membrane surface. Physical modification of the membrane surface can be achieved by coating it with hydrophilic polymers, hydrophilic-hydrophobic copolymers, surfactants or proteins. Another method of physical modification is plasma treatment with gases. A hydrophilic membrane surface can be also generated during phase-inverted micro-separation during membrane formation, by blending hydrophilic or hydrophilic-hydrophobic polymers with a hydrophobic base membrane polymer. The most widely used method of chemical modification is surface grafting of a hydrophilic polymer by UV polymerization because it is the easiest method; the membranes are dipped into monomers with and without photo-initiators, then irradiated with UV. Plasma-induced polymerization of hydrophilic monomers on the surface is another popular method, and surface chemical reactions have also been developed by several researchers. Several important examples of physical and chemical modifications of membrane surfaces for low-protein-binding are summarized in this article.

Advanced LCD modes through surface modification using reactive mesogen mixed with alignment layers

  • Lee, You-Jin;Kim, Young-Ki;Jo, Soo-In;Yu, Chang-Jae;Kim, Jae-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.91-94
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    • 2009
  • We propose advanced liquid crystal display (LCD) modes through surface modification using UV curable reactive mesogen (RM) mixed with alignment layers. The LC directors on the modified alignment layer are controlled and memorized by the polymerized RMs under an applied voltage. Using the method proposed here, we can improve the response time and viewing angle characteristics through surface controlled patterned vertical alignment (SC-PVA) mode and 8-domains PVA mode, respectively. Also, we found that the method can be applicable to fabricate multi-domain structures using multiple UV exposure as same as conventional UV alignment method.

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