• Title/Summary/Keyword: UMP

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Rheological Properties of Polyurethane Modified with Polyorganosiloxane (Polyorganosiloxane 변성 폴리우레탄의 유변 특성)

  • 한정우;한미선;이상문;박태석;강두환
    • Polymer(Korea)
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    • v.26 no.5
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    • pp.607-614
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    • 2002
  • Polyorganosiloxane(HBPS) modified polyurethane (UMPS) was synthesized to improve weatherability in the polyurethane (ITPU) sealant and its rheological propoerty was investigated. It was found that the viscosity increased with increasing HBPS content in polyurethane and maximum viscosity was observed in UMPS having 70/30 ITPU/HBPS ratio. This was understood that the segregation of HBPS segment in UMPS chain has been developed. Further increasing of the content of HBPS resulted in the lowering of viscosity because of the flexibility of HBPS block segment in UMPS chain. It was also found that UMPS has more sensitive environmental dependency of viscosity than ITPU such as shear rate, humidity and temperature. In additions, UMPS having Si(O$CH_3$)$_3$ end group (TUMPS) by adding coupling agent up to 0.3 wt% resulted in the increase of viscosity by the acceleration of curing. But introducing more than 0.5wt% curing agent to TUMPS caused the lowering of viscosity because of less NCO group in TUMPS for the curing.

Studies on the Food of Fresh Water Fish ( I ) - The Chemical Composition of Carp Muscle, Cyprinus Carpio - (담수어(淡水魚)의 식품학적(食品學的) 연구(硏究) (I) - 잉어 육(肉)의 화학성분(化學成分) -)

  • Sung, Nak-Ju;Shim, Ki-Hwan;Lee, Jong-Ho;Lee, Jong-Mi
    • Journal of Nutrition and Health
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    • v.13 no.1
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    • pp.59-64
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    • 1980
  • Carp, Cypinus carpio, has been esteemed as one of the most tasty fresh water fishes in Korea. But little study on its food has been reported. The composition of fatty acids, amino acids, nucleotides and their related compounds as chemical component of carp muscle were analyzed by gas-liauid chromatography, amino acid autoanalyzer and high speed liauid chromatography. The fatty acids of the carp muscle lipid consisted of the large amount of $C_{18}\;:\;2,$ $C_{18}\;:\;1,$ $C_{18}\;:\;3,$ $C_{16}\;:\;0,$ $C_{16}\;:\;1,$ acids, small amount of $C_{16}\;:\;2,$ $C_{18}\;:\;0,$ $C_{18}\;:\;4,$ $C_{14}\;:\;0,$ $C_{14}\;:\;1,$ $C_{12}\;:\;0,$ acids, and $C_{13}\;:\;1,$ $C_{13}\;:\;0,$ $C_{20}\;:\;1,$ $C_{17}\;:\;0,$ $C_{15}\;:\;1,$ $C_{17}\;:\;1,$ $C_{22}\;:\;1$ acids were smaller. In fresh carp, the results showed that inosine $17.25{\mu}mole/g$, hypoxanthine $10.06{\mu}mole/g$ were dominant and the content of GMP, IMP, AMP, UMP, CMP were 1.56, 1.36, 0.92, 0.49, $0.34\:{\mu}mole/g$ on dry base, respectively. Histidine and lysine were dominant amino acids in carp extract, having 49.4% (214.6mg%), 33.9% (147.1mg%) of total free amino acid contents, respectively, but the content of glycine, serine, alanine and glutamic acid were low, and arginine, aspartic acid, threonine, proline, valine, methionine, isoleucine, phenylalanine were detected in trace amount. The content of amino acid composition showed that glutamic acid, aspartic acid, lysine, leucine, alanine, valine and arginine were the most abundant amino acids, while such amino acids as glycine, isoleucine, phenylalanine, threonine, histidine, methionine, serine and tyrosine were low, and proline was detected in trace amount.

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Nonvolatile Flavor Components in Chinese Quince Fruits, Chaenomeles sinensis koehne (모과의 비휘발성 Flavor 성분에 관한 연구)

  • Chung, Tae-Yung;Cho, Dae-Sun;Song, Jae-Chul
    • Korean Journal of Food Science and Technology
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    • v.20 no.3
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    • pp.293-302
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    • 1988
  • This study was performed to identify detailed informations on the nonvolatile flavor of Chinese quince fruits, Chaenomeles sinensis koehne. About 72% of the free amino acids were shown to be valine, asparagine, ${\gamma}-aminobutyric\;acid$, aspartic acid and serine. Arginine, tyrosine, methionine and tryptophan were not present. Glutamic acid and glutamine as a amino acid for peptides were the major components, whereas cysteic acid, methionine sulfone and tryptophan were not detected. The nucleotides attained were composed of cytosine, uridine-5'-monophosphate and cytidine-5'-monophosphate, and these were proved to be a very small quantity. Guanosine-5'-monophosphate, inosine-5'-monophosphate and adenosine-5'-monophosphate were not present. The major sugars were shown to be glucose, sorbose, sucrose and fructose. Fructose was the most abundant one among them. A total of 11 organic acids were identified by capillary gas chromatography and capillary gas chromatography-mass spectrometry. The major components identified were tartaric acid and α-ketoglutaric acid. The total content of vitamin C determined was 386.6mg%, and those of ascorbic, dehydroascorbic, and 2, 3-diketo-L-gulonic acid were 28.8mg%, 154.5mg% and 197.3mg%, respectively. Calcium and phosphorus were the major components, while heavy metals such as cadmium, copper and lead were determined to be a small amount. In the result of organoleptic test on the natural and synthetic extract of Chinese quince fruits, the principal taste components consisted of free amino acids, sugars, organic acids, vitamin C and minerals. Five groups mentioned would have a favorable influence upon the taste of fresh Chinese quince fruits.

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Regulation of sfs1 gene expression by the cAMP-cAMP receptor protein (sfs1 유전자의 cAMP-cAMP receptor protein에 의한 발현 조절)

  • Yoo, Ju-Soon;Lee, Seung-Jin;Lee, Hee-Young;Chung, Soo-Yeol;Choi, Yong-Lark
    • Applied Biological Chemistry
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    • v.39 no.3
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    • pp.195-199
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    • 1996
  • We have cloned several E. coli sfs genes which stimulate mal gene expression with $crp^{{\ast}1}$). One the genes (pPVC2) was sequenced and potential CRP binding site is located in the upstream of the putative promoter in the regulatory region. In order to investigate the regulation of the sfs1 gene by the cAMP-CRP complex, we have constructed the sfs-lacZ fusion gene in this research. The overall transcriptional stimulations of sfs1 gene in the presence cAMP were confirmed by ${\beta}-galactosidase$ activity and Western blot analysis of sfs1-lacZ fusion gene. Transcriptional regulation by cAMP-CRP was also confirmed by Northern blot analysis. End-labelled DNA of the DNA fragment in sfs1 regulation region were used for gel retardation assay to examine the CRP-DNA complex in the presence of cAMP. Results here indicate that CRP binding site in the regulatory region of sfs1 gene is positive regulator for the expression of sfs1 gene.

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Studies on the Production of 5'-Nucleotides by Streptomyces spp. -Part 1. Isolation of 5'-phosphodiesterase Producing Microorganisms- (방사균(放射菌)에 의한 5'-Nucleotide류(類)의 생산(生産)에 관한 연구(硏究) -제 1 보(第 1 報) 5'-Phosphodiesterase생산균(生産菌)의 분리(分離)-)

  • Kim, Hong-Jip;Bae, Chong-Chan;Hwang, Kyu-Ln;Kong, Un-Young
    • Applied Biological Chemistry
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    • v.22 no.4
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    • pp.210-216
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    • 1979
  • RNA degrading bacteria were isolated from soil of Korea. One strain (no. JSC-114), having strong 5'-phosphodiesterase activity, was identified as belonging to the genus Streptomyces on the basis of taxonomic characteristics. The optimum conditions of 5'-phophosdiesterase production were found at $30^{\circ}C$ for 4 day in a medium containing 4.5% of soluble starch, 0.15% of peptone, 0.6% of yeast extract, 0.1% of $MgSO_4{\cdot}7H_2O$, 0.01% of $CaCl_2{\cdot}2H_2O$, 0.25% of $KNO_3$, and 0.5% of $KH_2PO_4$(pH 7.0). The maximum production rate of 5'-nucleotides from yeast RNA was 95% at $40-45^{\circ}C$ for 4hrs, and the products were identified as 5'-IMP, 5'-GMP, 5'-CMP and 5'-UMP(5.5 : 5.0 : 4.9 : 5.0).

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