• Journal of Korean Society of Environmental Engineers
• /
• v.35 no.12
• /
• pp.877-882
• /
• 2013

The application of ultrafiltration (UF) and microfiltration (MF) membranes has been increased for drinking water purification. The advantages of UF/MF membrane process compared to conventional treatment processes are stable operation under varying feed water quality, smaller construction area, and automatic operation. Most membrane treatment plants are designed with polymeric membranes. Recently, some studies suggested that the process of treating surface water with ceramic membranes is competitive to the application of polymeric membranes. Higher water flux, less frequent cleaning, and much longer lifetime are the advantages of ceramic membrane comparing to polymeric membrane. Therefore, this research focused on the application of ceramic MF membrane pilot plant at the slow sand filtration plant. The ceramic membrane pilot plant has three trains that used raw water and sand filtered water as a feed water, respectively. For optimizing the pilot plant process, the coagulation with PACl coagulant was used as a pretreatment of ceramic membrane process. In addition, CEB (Chemical Enhanced Backwash) process using $H_2SO_4$ and NaOCl was used for 1.5 days, respectively. The experimental results showed that applying the optimum coagulant dose before membrane filtration showed enhancing membrane fluxes for both raw water and sand filtered water. Also, when using raw water as a feed of membrane, minimum fouling rate was 2.173 kPa/cycle with 25 mg/L of PACl and when using sand filtered water, the minimum fouling rate was 0.301 kPa/cycle with 5 mg/L of PACl.

• Proceedings of the Membrane Society of Korea Conference
• /
• 1998.06a
• /
• pp.171-221
• /
• 1998

막분리기술은 이제 분리, 정제만의 단순한 개념이 아니며 고도분리정제와 자원재활용등이 복합적으로 해결되는 효율적 공정으로서 "Zero discharge" 및 "Closed-loop System" 으로서의 개념을 가지고 있다. 이것은 Clean Technology의 개념으로서 Membrane기술의 향후 Vision이라고 할 수 있다. 국내에 적용되고 있는 UF/MF막의 용도는 다음과 같다. -수처리분야, 가정용정수기, 폐수처리분야, 식품/생물공정 분야, 전착도장, 흡수식 냉동기의 LiBr 용액정제, 흡수식 냉동기의 LiBr 용액정제

• Journal of Korean Society of Environmental Engineers
• /
• v.28 no.6
• /
• pp.613-619
• /
• 2006

The objectives of this research are to evaluate the effect of membrane materials, particulate matter and membrane pore size on permeate flux. It was shown that the removal efficiency of high MW organic matter more than 10 kDa was lower than that of low MW organic matter for $MIEX^{(R)}$ process. For the change of permeate flux by the pretreatment process, $MIEX^{(R)}+UF$ process showed high removal efficiency of organic matter as compared with coagulation+UF processes, but high reduction rate of permeate flux was presented through the reduction of removal efficiency of high MW organic matter. The pretreatment of the raw water significantly reduced the fouling of the hydrophilic membrane, but did not decrease the flux reduction of the hydrophobic membrane. Flux decline on MF process increased due to the pore clogging, while the permeate flux decline of UF process decreased due to the formation of cake layer. It was shown that particle matter was not effect on MIEX+membrane process. But, for coagulation+membrane process, particle matter was important factor on permeate flux.

• Membrane Journal
• /
• v.22 no.5
• /
• pp.332-341
• /
• 2012

We studied the effects of induction of natural convection instability flow (NCIF) according to the gravitational orientation (inclined angle) of the membrane cell on the reduction of membrane fouling in the constant-flow ultrafiltration (UF) of colloidal silica solutions. Five colloidal silica solutions with different silica size (average size = 7, 12, 22, 50 nm and 78 nm) were used as UF test solutions. The silica particles in colloidal solutions form cakes on the membrane surface thereby causing severe membrane fouling. The constant-flow UF performance according to the gravitational orientation of the membrane cell (from $0^{\circ}$ to $180^{\circ}$ inclined angle), was examined in an unstirred dead-end cell. We evaluate the effects of NCIF on the suppression of fouling formation by measuring the variation of transmembrane pressure (TMP) and the increase of critical flux by using the flux-stepping method. In the constant-flow dead-end UF for the smaller size (7, 12 nm and 22 nm) silica colloidal solutions, changing the gravitational orientation (inclined angle) of the membrane cell above the $30^{\circ}$ angle induces NCIF in the membrane module. This induced NCIF enhances back transport of the deposited silica solutes away from the membrane surface, therefore gives for the reduction of TMP. But in the constant-flow UF for the more larger size (50 nm and 78 nm) silica colloidal solutions, NCIF effects are not appearing. The critical flux is increased as increasing the module angle and decreasing the silica size. Those results show that the intesity of NCIF occurrence in membrane module is more higher as increasing the module angle and decreasing the silica size.

• Membrane Journal
• /
• v.21 no.1
• /
• pp.84-90
• /
• 2011

We studied the effects of induction of natural convection instability flow (NCIF) according to the gravitational orientation (inclined angle) of the membrane cell on the reduction of membrane fouling in ultrafiltration (UF) of colloidal silica solutions. Five colloidal silica solutions with different silica size (average size = 7, 12, 22, 50 and 78 nm) were used as UF test solutions. The silica particles in colloidal solutions form cakes on the membrane surface thereby causing severe reduction in the flux. The UF performance according to the gravitational orientation of the membrane cell (from 0 to $180^{\circ}$ inclined angle), was examined in an unstirred dead-end cell. We evaluate the effects of NCIF on membrane performance as the flux enhancement ($E_i$). In the dead-end UF of smaller size (7, 12 and 22 nm) silica colloidal solutions, changing the gravitational orientation (inclined angle) of the membrane cell induces NCIF in the membrane module and higher inclined angle and smaller size silica colloidal solution offer more stronger NCIF. This induced NCIF enhances back transport of the deposited silica solutes away from the membrane surface, therefore gives for the improvement of permeate flux. But in UF of more larger size (50 and 78 nm) silica colloidal solutions, NCIF effects are not appearing. These results suggest that the size of colloidal particle affects the extent of NCIF occurrence.

• Journal of Advanced Marine Engineering and Technology
• /
• v.37 no.5
• /
• pp.541-547
• /
• 2013

It is important to establish water treatment technologies for drinking water because Korea belongs to water-stressed country. Leachate from recent incident of foot-and-mouth disease has become an opportunity to be aware of the need to manage water quality. Water purifiers are adopted to four or five steps of filtration process. Each steps are composed of a sediment filter, a pre-carbon filter, an UF or a RO membrane filter and a post-carbon filter. And additionally a ceramic filter can be used as a final stage. In this study, operational conditions in each steps are examined and characteristics of each filters are investigated. SEM analysis is used for filter surface and shape investigation using 6 commercial samples. Pore sizes of the sediment filter, the UF membrane filter, and the RO membrane filter are 30~47 ${\mu}m$, 0.005~0.5 ${\mu}m$, and 0.025~0.25 ${\mu}m$, respectively. Specific surface areas of activated carbons are ranged from 622 to 1,308 $m^2/g$.

• Journal of Korean Society of Water and Wastewater
• /
• v.26 no.1
• /
• pp.21-27
• /
• 2012

This study evaluated the performance of a thermophilic two-phase anaerobic digestion (TTPAD) coupled with membrane process treating garbage leachate. The pilot-scale treatment system is consisted of thermophilic acidogenic reactor (TAR) and thermophilic methanogenic reactor (TMR) coupled with an ultrafiltration (UF) membrane unit. The hydraulic retention time of TAR and TMR were 4 and 20 days, respectively. Effluent TCOD and SCOD of the TTPAD were $25\;{\pm}\;6\;and\;12\;{\pm}\;3$ g/L, respectively, and the corresponding TCOD and SCOD removal efficiencies were 77% and 81%, respectively. Propionate was major acids as 75% in the effluent. Scum formation was not observed in TTPAD, which might be resulted from complete lipid degradation. However, TTPAD was appeared to be sensitive to free ammonia toxicity. The UF membrane was operated with constant pressure filtration at average TMP 1.3 atm. Permeate flux had a range of 15-30 $L/m^2/hr$. With UF membrane, TCOD removal increased from 77% to 93%, and this SS free effluent would be beneficial to subsequent processes such as ammonia stripping.

• Proceedings of the Membrane Society of Korea Conference
• /
• 1999.04a
• /
• pp.115-118
• /
• 1999

• Food Science and Biotechnology
• /
• v.14 no.3
• /
• pp.380-386
• /
• 2005

Optimal conditions of ultrafiltration (UF) and nanofiltration (NF) were investigated for separation and concentration of isoflavones and oligosaccharides from Sunmul. Levels of COD, BOD, and suspended solids (SS) in UF and NF permeates were also determined to evaluate effectiveness of these processes for reducing water pollution. Optimal UF operation conditions to achieve minimal fouling and maximal flux were $33-34^{\circ}C$ operating temperature and 2.3-2.4 bar trans-membrane pressure. Recovery yields of isoflavones and oligosaccharides in UF retentate were 11.49-28.16% and 12.77-27.57%, respectively. Increase in volumetric concentration factor (VCF) resulted in more functional compounds of isoflavones and oligosaccharides passing through UF membrane. Total isoflavone and oligosaccharide yields decreased by 3% as VCF increased from 6.0 to 8.0 and from 8.0 to 10.0, while decreased significantly by 10% as VCF decreased from 4.0 to 6.0. Optimal NF operating conditions were 192-195 psig operating pressure at $30-33^{\circ}C$. Total yields of isoflavones and oligosaccharides significantly decreased at VCF 8.0, whereas did not decrease up to VCF 6.0 during NF operation. Therefore, VCF 6.0 was recommended for economical process. COD and BOD decreased by more than 98% after NF process, and SS were not detected after UF process. These results indicated sequential filtration process was useful for separation of isoflavones and oligosaccharides from Sunmul and for reducing water contaminants.

• Proceedings of the Membrane Society of Korea Conference
• /
• 1993.10a
• /
• pp.77-78
• /
• 1993

쥬스제조시 청징공정에 있어서 UF의 응용은 현재까지 그리 주목받아 오지 못했다. 그러나 UF는 기존의 여과방법보다 더 간단하고 저렴한 기술이며 더 좋은 품질의 제품을 생산할 수 있다. 일반적인 사과쥬스 제조에 있어서 기존의 청징방법은 보통 2단계를 필요로 하는데 먼저 Pectinase와 같은 효소처리된 원료쥬스를 Decanter라는 회전진콩 여과기로 여과한 다음 가압여과기로 여과를 하게 된다. 이 두단계에 있어서 많은 양의 규조토가 필요한데 UF를 사용하여 청징여과를 하게 되면 규조토의 사용을 안하므로 생산비 절감 뿐만아니라 폐기물처리 문제까지도 해결해 준다. 도한 제품의 질, 특히 덫징도가 증가하며 수율도 높일 수 있고 노동비를 절감할 수 있으며, 효소는 막을 통과하지 않기 때문에 농축액에 축적되어 효소의 재사용에 따른 효소사용량 절감을 가져올 수 있다.