• Bulletin of the Korean Chemical Society
• /
• v.26 no.2
• /
• pp.297-302
• /
• 2005

The determination of total phenols was accomplished by capillary-high performance liquid chromatography (capillary-HPLC) after nitrosation of the U.S.E.P.A. classified 11 priority pollutant phenols, using the nitrosated parent phenol (POHNO) as a reference for calibration. The optimum mobile phase composition for this analysis was found by examining the effect of changing the percentage of acetonitrile (MeCN) in the mobile phase on retention factors (k values) and peak intensities. As MeCN percentage was increased, k values were reduced and peak intensities were generally increased. From the results obtained, it was found that the optimum mobile phase was 90%(v/v) MeCN solution at pH 8.0, the detection wavelength of 400 nm, and a detection limit (D.L., concentration at signal to noise ratio (S/N) of 3.0) of 4.5 ${\times}$ $10^{-7}$ M. In addition, 10 of the 11 phenols present in mineral or waste water were separated after the nitrosation by capillary-HPLC. The optimum mobile phase for separation was a 40%(v/v) MeCN solution at pH 5.0.

• Journal of IKEEE
• /
• v.28 no.2
• /
• pp.158-167
• /
• 2024

In this study, U-net model based on electrical capacitance is applied to monitor the condition inside the pipeline of semiconductor rear end process implemented in the numerical simulation. Capacitance values measured from electrodes attached to the pipeline is used as input data for the U-net network model and estimated permittivity distribution by the U-net model is used to reconstructed cross-sectional image at the pipeline. In the numerical simulation, images reconstructed by U-net model, Fully-connected neural network (FCNN) model and Newton-Raphson method are compared for evaluation. U-net model shows good results as compared to other models.

• Korean Journal of Optics and Photonics
• /
• v.34 no.5
• /
• pp.192-201
• /
• 2023

The band-limited angular spectrum method (BL-ASM) causes aliasing errors due to spatial frequency control problems. In this paper, a sampling interval adjustment technique for phase holograms and a technique for reducing speckle noise and improving image quality using a deep-learningbased U-net model are proposed. With the proposed technique, speckle noise is reduced by first calculating the sampling factor and controlling the spatial frequency by adjusting the sampling interval so that aliasing errors can be removed in a wide range of propagation. The next step is to improve the quality of the reconstructed image by learning the phase hologram to which the deep learning model is applied. In the S/W simulation of various sample images, it was confirmed that the peak signal-to-noise ratio (PSNR) and structural similarity index measure (SSIM) were improved by 5% and 0.14% on average, compared with the existing BL-ASM.

• Journal of Advanced Navigation Technology
• /
• v.28 no.1
• /
• pp.116-122
• /
• 2024

In this paper, course structure and course width were studied among the main performances of the system to derive the required performance of the modulation index, output power, and phase change specifications of the instrument landing system (ILS) localizer power amplifier. To satisfy the course structure's deviation standard (± 5 uA), the difference in depth of modulation (DDM) deviation standard of the carrier with sideband (CSB) amplifier was standardized to ± 1 uA(0.001 DDM). CSB 30 W power amplifier was designed, and through the modulation compensation circuit, sum in depth of modulation (SDM) is 40% ± 0.1% and DDM is ± 0.0005 DDM in the operating output range(45 dBm ~ 35 dBm). In addition, the course width and displacement sensitivity specifications were analyzed through simulation, and the ± 0.1° change applied during comissioning inspection, which is the most stringent standard, was applied. The output variation of the suppressed with sideband only ( SBO) amplifier was ± 2 mW or less, The phase was standardized to within ± 3 ° and the characteristics were satisfied. By applying a compensation circuit according to output power and temperature, stable modulation index, output, and phase characteristics were obtained.

• Korean Chemical Engineering Research
• /
• v.49 no.5
• /
• pp.582-587
• /
• 2011

Holdup characteristics of bubble, wake and continuous liquid phases were investigated in bubble columns with viscous liquid media. Effects of column diameter(0.051, 0.076, 0.102 and 0.152 m ID), gas velocity($U_G$=0.02~0.16 m/s) and liquid viscosity(${\mu}_L$=0.001~0.050 $Pa{\cdot}s$) of continuous liquid media on the holdups of bubble, wake and continuous liquid phases were discussed. The three phase such as bubble, wake and continuous liquid phases were classified successfully by adapting the dual electrical resistivity probe method. Compressed filtered air and water or aqueous solutions of CMC(Carboxy Methyl Cellulose) were used as a gas and a liquid phase, respectively. To detect the wake as well as bubble phases in the bubble column continuously, a data acquisition system(DT 2805 Lab Card) with personal computer was used. The analog signals obtained from the probe circuit were processed to produce the digital data, from which the wake phase was detected behind the multi-bubbles as well as single bubbles rising in the bubble columns. The holdup of bubble and wake phases decreased but that of continuous liquid media increased, with an increase in the column diameter or liquid viscosity. However, the holdup of bubble and wake phases increased but that of continuous media decreased with an increase in the gas velocity. The holdup ratio of wake to wake to bubble phase decreased with an increase in the column diameter or gas velocity, however, increased with an increase in the viscosity of con-tinuous liquid media. The holdups of bubble, wake and continuous liquid media could be correlated in terms of operating variables within this experimental conditions as: ${\varepsilon}_B=0.043D^{-0.18}U_G^{0.56}{\mu}_L^{-0.13}$, ${\varepsilon}_W=0.003D^{-0.85}U_G^{0.46}{\mu}_L^{-0.10}$, ${\varepsilon}_C=1.179D^{0.09}U_G^{-0.13}{\mu}_L^{0.04}$.

• Proceedings of the KIEE Conference
• /
• 1984.07a
• /
• pp.19-20
• /
• 1984

• Proceedings of the Optical Society of Korea Conference
• /
• 2005.07a
• /
• pp.246-247
• /
• 2005

• Proceedings of the Korean Nuclear Society Conference
• /
• 2005.10a
• /
• pp.885-886
• /
• 2005

• Journal of the Mineralogical Society of Korea
• /
• v.15 no.1
• /
• pp.78-84
• /
• 2002

New pyrochlore-type phases($A_2$$B_2$$O_{7}$) were synthesized in the systems: CaO-C$eO_2$-T$iO_2$, CaO-$UO_2$(T$hO_2$)-Z$rO_2$, CaO-$UO_2$(T$hO_2$)-$Gd_2$$O_3$-T$iO_2$-Z$rO_2$, 및 CaO-T$hO_2$-S$nO_2$. The starting materials were pressed with the pressure of 200~400 MPa and sintered at 1500~ 155$0^{\circ}C$ for 4~8 hours in air and at 1300~ 135$0^{\circ}C$ for 5 ~50 hours under oxygen atmosphere. The products were characterized using XRD, SEM/EDS and TEM. In the bulk compositions of CaCe$Ti_2$$O_{7}$, CaTh$Zr_2$$O_{7}$,($Ca_{0.5}$ Gd$Th_{0.5}$)(ZrTi)$O_{7}$) ($Ca_{0.5}$Gd$Th_{0.5}$)(ZrTi)$O_{7}$, ($Ca_{0.5}$G$dU_{0.5}$)(ZrTi)$O_{7}$ and CaTh$Sn_2$$O_{7}$ , pyrochlore was the major phase, together with other oxide phase $of_2$$O_{7}$ fluorite structure. In the samples with target compositions CaU$Zr_2$$O_2$및 $Ca_{0.5}$ G$dU_{0.5}$)$Zr_2$T$iO_{7}$ pyrochlore was not identified, but a fluorite-structured phase was detected. The formation factor as the stable phase depended on crystal chemical characteristics of the actinide and lanthanide elements of the system concerned.

• Journal of the Korean Chemical Society
• /
• v.38 no.7
• /
• pp.502-508
• /
• 1994

The measurement of trace amounts of uranium(VI) and thorium(VI) in the solutions containing high concentration of dissolved salts was carried out. The procedure using reversed phase liquid chromatography with trace enrichment techniques has been developed to cope with the high salt content of the samples. 2 ml of sample were passed through a small C_{18}$ reversed phase enrichment column with ${\alpha}$-HIBA eluent (0.11 M, pH 5.5) where the uranium and thorium were separated from other constituents and concentrated. The uranium and thorium were then backflushed from the column onto a deactivated C_{18}$ reversed phase analytical column where furthe separation was achieved with a mixed eluent (pH3.0, 0.17M ${\alpha}$-HIBA/0.0038 M 1-pentanesulfonate). The separated species were determined spectrophotometrically by postcolumn reaction with Arsenazo III, the chromogenic reagent. Detection limits were found within 1 ppb range for both species.