• Title/Summary/Keyword: Two-reaction model

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Rotordynamic Analysis of a Labyrinth Seal Using the Moody's Friction-Factor Model (Moody 마찰계수식을 사용한 래버린스 실의 회전체 동역학적 해석)

  • Ha, Tae Woong
    • The KSFM Journal of Fluid Machinery
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    • v.2 no.3 s.4
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    • pp.52-58
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    • 1999
  • The leakage and rotordynamic coefficients of see-through type gas labyrinth seals are determined using a two-control-volume-model analysis with Moody's wall-friction-factor formula which is defined with a large range of Reynolds number and relative roughness. Jet flow theory are used for the calculation of the recirculation velocity in the cavity. For the reaction force from the labyrinth seal, linearized zeroth-order and the first-order perturbation equations are developed for small motion about a centered position. The leakage and rotordynamic coefficient results of the present analysis are compared with Scharrer's theoretical analysis using Blasius' wall-friction-factor formula and Pelletti's experimental results. The comparison shows that the present analysis using Moody's wall-friction-factor formula and Scharrer's theoretical analysis using Blasius' wall-friction-factor formula give the same results for a smooth seal surface and the range of Reynolds number less than $10^5$.

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The Uptake of Solvent in Polymeric Thin Membranes By a Relaxation-Sorption Coupled Mechanism

  • Song, Kyu-Min;Hong, Won-Hi
    • Proceedings of the Membrane Society of Korea Conference
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    • 1995.10a
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    • pp.43-44
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    • 1995
  • The diffusion behavior of liquid into polymer has been described by Fick's law, but the departure from Fickian diffusion is frequently found. In this study, 'noble' expressions for the rates of relaxation and sorption are introduced to eliminate these limitations. The ralaxation-sorption coupled mechanism model are based on the possibility of contacting liquid molecule and the active site which has the numerical concept of free volume. The concept has an analogy of reaction rate expressed by the possibility of collision with molecules and used in adsorption and reactive extraction etc. The new model simulated by Rungc-Kutta method for initial-value problem and Fickian diffusion is caompared with experimental data. The results show that the ralaxation-sorption coupled mechanism is able to account well for Fickian and non-Fickian sorption behavior including sigmoid and two-stage. In addition, this model has a chance of expansion to multi-component sorption with ease.

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A Numerical study on current density and temperature distributions of IT-SOFC (IT-SOFC의 전류밀도 및 온도분포에 관한 수치해석 연구)

  • Sohn, Sang-Ho;Lee, Kyu-Jin;Nam, Jin-Hyun;Kim, Charn-Jung
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.3067-3072
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    • 2008
  • A two-dimensional model for anode-supported IT-SOFCs is proposed in order to accurately consider the heat and mass transport processes with a fully-developed axial velocity profile in channel flow. A comprehensive micro model is employed to describe the electrochemical reaction in anode and cathode of SOFCs. This paper investigates the effects of operational parameters (inlet temperature, the amount of flow rate, and air flow rate) including flow configurations (co-flow and counter-flow) on the current density and temperature distributions in the IT-SOFCs.

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Rheological behavior during the phase separation of thermoset epoxy/thermoplastic polymer blends

  • Kim, Hongkyeong;Kookheon Char
    • Korea-Australia Rheology Journal
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    • v.12 no.1
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    • pp.77-81
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    • 2000
  • Rheological behavior of thermoset/thermoplastic blends of epoxy/polyethersulphone (PES) was monitored during curing of the epoxy resin. During the isothermal curing of the mixture, a fluctuation in viscosity just before the abrupt viscosity increase was observed. This fluctuation is found to be due to the phase separation of PES from the matrix epoxy resin during the curing. The experimentally observed viscosity fluctuation is simulated with a simple two phase suspension model in terms of the increase in domain size. The viscosity profiles obtained experimentally at different isothermal curing temperatures are in good agreement with the predictions from the simple model taking into account the viscosity change due to the growth of PES domain and the network formation of the epoxy matrix.

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Effect of Cutting Off Tension Bars in R/C Beams On the Full Scale and Model Specimens (철근콘트리트 보에서 체단된 철근의 효과에 관한 연구 실물 및 축소모형실험을 중심으로)

  • 이리형;최창식;임재형
    • Magazine of the Korea Concrete Institute
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    • v.2 no.1
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    • pp.79-90
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    • 1990
  • The purpose of this paper is to study on the effect of cutting off tension bars in reinforced concrete beams. that is, the ultimate strength, the failure mode and thl} tension stress distribution through the span. To achieve this purpose, a full-scale frame and seven small scale model beams (five rectangular and two T-section beams) were tested. The four main model specimens and two speciml}ns without cutting off tension bars 1,'{ere analyzed as plane stmss element with package program ADINA. As a result of test and analysis, the shorter' distance bet ween the reaction point and the cutting off point, the higher the ultimate strength of a bl}am will be when other physical properties are equal.

Direct strength evaluation of the structural strength of a 500 cbm LNG bunkering ship

  • Muttaqie, Teguh;Jung, DongHo;Cho, Sang-Rai;Sohn, Jung Min
    • Structural Engineering and Mechanics
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    • v.81 no.6
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    • pp.781-790
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    • 2022
  • The present paper describes a general procedure of the structural safety assessment for the independent type C tank of LNG bunkering ship. This strength assessment procedure consists of two main scheme, global Finite Element Analysis (FEA) model primarily for hull structure assessment and detailed LNG Tank structures FEA model including the cylindrical tank itself and saddle-support structures. Two kinds of mechanism are used, fixed and slides constraints in fore and rear of the saddle-support structures that result in a variation of the reaction forces. Finite Element (FE) analyses have been performed and verified by the strength acceptance criteria to evaluate the safety adequacy of yielding and buckling of the hull and supporting structures. The detail of FE model for an LNG type C tank and its saddle supports was made, which includes the structural members such as cylindrical tank shell, ring stiffeners, swash bulkhead, and saddle supports. Subsequently, the FE buckling analysis of the Type C tank has been performed under external pressure following International Gas Containment (IGC) code requirements. Meanwhile, the assessment is also performed for yielding and buckling strength evaluation of the cylindrical LNG tank according to the PD 5500 unfired fusion welded pressure vessels code. Finally, a complete procedure for assessing the structural strength of 500 CBM LNG cargo tank, saddle support and hull structures have been provided.

Femtosecond Photoelectron Imaging of N2 at 410 nm

  • Guo, Wei;Wei, Shanshan;Lu, Xingqiang;Wang, Li
    • Bulletin of the Korean Chemical Society
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    • v.31 no.12
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    • pp.3693-3696
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    • 2010
  • We experimentally measure the kinetic energy and angular distributions of photoelectrons of $N_2$ as a function of 410 nm femtosecond laser intensity by using velocity map imaging technique. The strong-field multiphoton ionization of molecules shares many of the characteristics with those of atoms. Electron kinetic energies are nearly independent of laser intensities. The independence suggests that the electron peaks in the photoelectron spectrum actually result from a two-step process, indicative of the occurrence of real population in the intermediate states. The relative amplitudes of electron peaks indicate that in the two-step process, nonresonant population transfer dominates for low intensities, while resonant population transfer dominates for higher intensities.

Numerical investigation on the performance of the aluminized HMX with varying aluminum concentration (알루미늄 함유량 변화에 따른 알루미늄 입자가 함유된 HMX 성능에 관한 수치 연구)

  • Kim, Wuhyun;Gwak, Min-cheol;Yoh, Jai-ick
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.617-621
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    • 2017
  • The performance characteristics of aluminized high explosive are considered by varying the aluminum(Al) concentration in a two-phase model. Since the time scales of the characteristic combustion process of high explosives and Al particles differ, the process of energy release behind the leading detonation wave front occurs over an extended period of time. Two cardinal observations are reported: a decrease in detonation velocity with an increase in Al concentration and a double front detonation (DFD) feature when anaerobic Al reaction occurs behind the front. In the current study, a series of confined rate sticks are considered for characterizing the performance of aluminized HMX with a maximum Al concentration of 50%. The simulated results are compared with the experimental data for 5%-25% concentrations.

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Analysis of α + 40Ca and α + 58Ni Elastic Scatterings at Elab = 240 MeV

  • Kim, Yong Joo
    • New Physics: Sae Mulli
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    • v.68 no.12
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    • pp.1324-1330
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    • 2018
  • The elastic scatterings for the ${\alpha}+^{40}Ca$ and the ${\alpha}+^{58}Ni$ systems at $E_{lab}=240MeV$ have been analyzed within the framework of the Coulomb-modified Glauber model using two kinds of Gaussian density parameters for the target nuclei. The first one is to use Gaussian density parameters obtained from the root-mean-square radius. The second one is to use parameters calculated by matching the Gaussian density to the two-parameter Fermi density. The results with surface-matched Gaussian densities provide reasonable agreement with the experimental data, but the results without matching do not. The oscillatory structures observed in the angular distributions of both system can be interpreted as being due to the strong interference between the near-side and the far-side scattering amplitudes. The differences between the phase shifts obtained from the two methods are examined. We also investigate the effect of these differences on the differential and reaction cross sections, the transmission functions and the strong absorption radii.

Limitations of the Transition State Variation Model. Part 8. Dual Reaction Channels for Solvolyses of 3,4-Dimethoxybenzenesulfonyl Chloride

  • Koo, In-Sun;Kwon, Eun-Ju;Choi, Ho-June;Yang, Ki-Yull;Park, Jong-Keun;Lee, Jong-Pal;Lee, Ikc-Hoon;Bentley, T. William
    • Bulletin of the Korean Chemical Society
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    • v.28 no.12
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    • pp.2377-2381
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    • 2007
  • Solvolyses of 3,4-dimethoxybenzenesulfonyl chloride (DSC) in water, D2O, CH3OD, and in aqueous binary mixtures of acetone, acetonitrile, 1,4-dioxane, ethanol, methanol, and 2,2,2-trifluoroethanol (TFE) have been investigated at 25.0 oC. Kinetic solvent isotope effects (KSIE) in water and in methanol and product selectivities in alcohol-water mixtures are also reported. The Grunwald-Winstein plot of first-order rate constants for the solvolyic reaction of DSC with YCl shows marked dispersions into separated lines for various aqueous mixtures. With use of the extended Grunwald-Winstein equation, the l and m values obtained are 1.12 and 0.58 respectively for the solvolyses of DSC. The relatively large magnitude of l is consistent with substantial nucleophilic solvent assistance. From Grunwald-Winstein plots the rate data are dissected approximately into contributions from two competing reaction channels. This interpretation is supported for alcohol-water mixtures by the trends of product selectivities, which show a maximum for ethanol-water mixtures. From the KSIE of 1.45 in methanol, it is proposed that the reaction channel favored in methanolwater mixtures and in all less polar media is general-base catalysed and/or is possibly (but less likely) an addition-elimination pathway. Also, the KISE value of 1.35 for DSC in water is expected for SN2-SN1 processes, with minimal general base catalysis, and this mechanism is proposed for solvolyses in the most polar media.