• 한국수자원학회논문집
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• 제53권2호
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• pp.141-154
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• 2020

우리나라에서 일어나는 하천 내 유해화학물질 유입사고 발생건수는 매년 증가하는 추세를 보이고 있다. 이에 대응하기 위해 국가차원의 수질오염 사고대응체계를 구축하여 사고방재를 위한 체계적인 절차를 수립하였으나, 우리나라의 사고대응체계는 해외의 수질모형을 차용하고 있기 때문에 모형의 매개변수 입력 및 검보정에 어려움이 있다. 이에 따라 본 연구는 하천에 유출된 유해화학물질의 거동을 분석하기 위한 수심 평균 2차원 하천수질모형을 개발하고, 유해화학물질의 특성을 고려한 유의반응항 판별을 통해 효율적 모의수행을 위한 기법을 제시하였다. 수심 평균 2차원 하천수질모형인 CTM-2D에 흡·탈착, 휘발 반응을 재현할 수 있는 반응항을 추가하고, 이를 검증하기 위해 해석해와 수치해를 비교한 결과 0.1% 미만의 오차를 보여 모형의 타당성을 입증하였다. 또한 낙동강-금호강 합류부에 수질오염사고 가상시나리오를 구성하여 개발된 모형을 적용하였으며, 민감도 분석 기반 유의반응 판단을 통해 효율적 수질모의를 수행할 수 있었다.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2012년도 제45회 KOSCO SYMPOSIUM 초록집
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• pp.141-143
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• 2012

The present study is aiming at numerically analyze the soot formation processes coupled with gas reaction mechanism in turbulent non-premixed and partially premixed flames. In order to realistically represent turbulence-chemistry interactions with detailed chemical kinetics and soot formation behaviour related to the turbulent non-premixed and partially premixed flames, the transient flamelet[1] and flamelet based level-set approach[2] are coupled with soot formation based on the two equation model [3] and DQMOM (Direct Quadrature Method of Moment)[4].

• 한국진공학회:학술대회논문집
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• 한국진공학회 2010년도 제39회 하계학술대회 초록집
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• pp.74-74
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• 2010

The aqua-plasma is the non-thermal plasma in electrical conductive electrolyte by generates the vapor film layer on the immersed metal electrode surface. This plasma can generate the hydroxyl radical by dissociate the water molecule with the plasma electron. To develop the plasma discharge device for high efficiency in the hydroxyl radical generation, proper model for estimation of plasma power is necessary. In this work, the 1-D spherical model was developed, considering temperature dependence material constants. The relation between the plasma power and hydroxyl generation was also studied by the comparison between the optical emission intensity from the hydroxyl radical using monochromator and estimated plasma power. First, the thickness of vapor layer thickness was estimated using the Navier-Stokes fluid equation in order to calculate the discharge E-field inside vapor layer. Using the E-field magnitude and power balance on the plasma generation, it was possible to estimate the plasma power. The plasma power was assumed to uniformly fill the vapor layer and the temperature of vapor layer was fixed in the boiling temperature of electrolyte, 375K. In the experiment, the aqua-plasma was discharged in the saline by applied the voltage on the bipolar electrode. The range of applied voltage was 234 to 280V-rms in the frequency of 380 kHz. Two type electrodes were produced with two ${\Phi}0.2$ tungsten. The plasma power was estimated from the V-I signal from the two high voltage probes and current probe. The estimated plasma power agreed with the profile of emission intensity when the plasma discharged between the metal electrode and vapor layer surface. However, when the plasma discharged between the metal electrodes, the increasing rate of emission intensity was lower than the increase of plasma power. It implies that the surface reaction is more sufficient rather than the volume reaction in the radical generation, due to the high density of water molecule in the liquid.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 추계학술대회 초록집
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• pp.111.1-111.1
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• 2010

This paper focuses on a systematic configuration of steam reforming fuel processor, particularly designed for small and medium sized hydrogen production application. In a typical integration of the fuel processor, there exist significant temperature gradients over the entire system which has negative effect on both catalyst life-time and system performance. Also, the volumetric inefficiency should be avoided to obtain the possible compactness for the commercial purpose. In the present work, the computational analysis will be performed to gain the fundamental insight on the transport phenomena and chemical reactions in the reformer consisting of preheating, steam reforming (SR), and water gas shift (WGS) reaction beds in the flow direction. Also, the fuel processing system includes a top-fired burner providing necessary thermal energy for endothermic catalytic reactor. A fully two-dimensional numerical modeling for a integrated fuel processing system is introduced for in-depth analysis of the heat and mass transport phenomena based on surface kinetics and catalytic process. In the model, water gas shift reaction and decomposition reaction were assumed to be at equilibrium. A kinetic model was developed and then computational results were compared with the experimental data available in the literature. Finally, the case study was done by considering the key parameters, i.e. steam to carbon (S/C) ratio and temperature. The computer-aided models developed in this study can be greatly utilized for the design of advanced fast-paced compact fuel processors research.

• Nuclear Engineering and Technology
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• 제47권6호
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• pp.700-711
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• 2015

Sodium-cooled fast breeder reactors use liquid sodium as a moderator and coolant to transfer heat from the reactor core. The main hazard associated with sodium is its rapid reaction with water. Sodium-water reaction (SWR) takes place when water or vapor leak into the sodium side through a crack on a heat-transfer tube in a steam generator. If the SWR continues for some time, the SWR will damage the surface of the defective area, causing it to enlarge. This self-enlargement of the crack is called "self-wastage phenomena." A stepwise numerical evaluation model of the self-wastage phenomena was devised using a computational code of multicomponent multiphase flow involving a sodium-water chemical reaction: sodiumwater reaction analysis physics of interdisciplinary multiphase flow (SERAPHIM). The temperature of gas mixture and the concentration of NaOH at the surface of the tube wall are obtained by a numerical calculation using SERAPHIM. Averaged thermophysical properties are used to assess the local wastage depth at the tube surface. By reflecting the wastage depth to the computational grid, the self-wastage phenomena are evaluated. A two-dimensional benchmark analysis of an SWAT (Sodium-Water reAction Test rig) experiment is carried out to evaluate the feasibility of the numerical model. Numerical results show that the geometry and scale of enlarged cracks show good agreement with the experimental result. Enlarged cracks appear to taper inward to a significantly smaller opening on the inside of the tube wall. The enlarged outer diameter of the crack is 4.72 mm, which shows good agreement with the experimental data (4.96 mm).

• 천문학회보
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• 제35권2호
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• pp.73.2-73.2
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• 2010

In order to understand internal dynamics of starless cores, molecular line emissions are usually observed. From profiles of the molecular lines, internal motions of starless cores have been deduced using a simple radiative transfer model such as the two-layer model (Myers et al.1996). This brings complexities arising from the chemical evolution. The motivation of this study is to follow the chemical evolution of a starless core that goes through gravitational contraction. For this purpose, we have performed hydrodynamical simulations with a marginally unstable Bonnor-Ebert sphere as an initial condition. We follow the chemical evolution of this core with changing conditions such as the chemical reaction rate at the dust surface and the strength of radiation field that penetrate into the core. At the core center, the molecules suffer from a higher degree of molecular depletion on the dust covered by ice rather than on the bare silicate dust. The stronger radiation field dissociates more molecules at the core envelope. From analysis on the line profile using the two-layer model, we found that the speed of inward motion deduced from the HCN F = 2-1 line adequately traces the true infall speed, when the dust is covered by ice and the core is exposed to the diffuse interstellar radiation field. Under different conditions, the two-layer model significantly underestimate the infall speed.

• Macromolecular Research
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• 제17권10호
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• pp.734-738
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• 2009

Biodegradable, pH-sensitive, glycol chitosan (GC) hydrogels were prepared using divinyl adipate (DVA) as a crosslinker and acetic acid as a catalyst. DVA has highly reactive double vinyl ester groups and GC contains a high density of hydroxyl groups, with two in every glucosamine unit. The transesterification reaction between vinyl esters and hydroxyl groups produced crosslinked GC hydrogels. The initial crosslinking reaction was monitored by measuring the viscosity of the reaction mixture. When DVA was added to the GC solution and heated to $50^{\circ}C$, the viscosity of the GC solution gradually increased, implying a crosslinking reaction and hydrogel formation. A new peak from the ester group was observed in the FTIR spectra of the GC hydrogels, confirming the crosslinking reaction. The synthesized GC hydrogel showed pH-dependent water absorbency, mainly due to the presence of amine groups ($-NH_2$) at the C-2 position of the glucosamine unit of GC. The water absorbency greatly increased at acidic pH and slightly decreased at alkaline pH. The GC hydrogel gradually degraded in $37^{\circ}C$ water due to hydrolysis of the ester bonds, which were intermolecular crosslinking sites. A red dye, 5-carboxyltetramethyl-rhodamine (CTMR), was entrapped in the GC hydrogels as a model compound. CTMR was released from GC hydrogels in two steps: an initial burst release mainly due to desorption and diffusion, and a second sustained release possibly due to gradual degradation.

• Journal of Mechanical Science and Technology
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• 제19권9호
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• pp.1695-1705
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• 2005

Reaction wheels and thrusters are commonly used for the satellite attitude control. Since satellites frequently need fast maneuvers, the minimum time maneuvers have been extensively studied. When the speed of attitude maneuver is restricted due to the wheel torque capacity of low level, the combinational use of wheel and thruster is considered. In this paper, minimum time optimal control performances with reaction wheels and thrusters are studied. We first identify the features of the maneuvers of the satellite with reaction wheels only. It is shown that the time-optimal maneuver for the satellite with four reaction wheels in a pyramid configuration occurs on the fashion of single axis rotation. Pseudo control logic for reaction wheels is successfully adopted for smooth and chattering-free time-optimal maneuvers. Secondly, two different thrusting logics for satellite time-optimal attitude maneuver are compared with each other: constant time-sharing thrusting logic and varying time-sharing thrusting logic. The newly suggested varying time-sharing thrusting logic is found to reduce the maneuvering time dramatically. Finally, the hybrid control with reaction wheels and thrusters are considered. The simulation results show that the simultaneous actuation of reaction wheels and thrusters with varying time-sharing logic reduces the maneuvering time enormously. Spacecraft model is Korea Multi-Purpose Satellite (KOMPSAT)-2 which is being developed in Korea as an agile maneuvering satellite.

• 대한화학회지
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• 제33권2호
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• pp.168-176
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• 1989

화학 레이저 모델의 이론적 연구를 화학 반응속도론, gain 과정과 유도 방출과정을 고려하여 수행하였다. 우선 F+$H_2$비 연쇄반응 HF 화학 레이저를 진동준위가 v = 3 까지 pumping되는 것으로 생각하고 관련된 rate equation을 풀어서 출력을 산출하였다. 여기서 조화진동자를 가정한 계산과 비조화성 보정을 해준 계산결과의 비교로부터 그 차이가 거의 없음을 확인하였다. 또한 여러가지 온도와 초기농도를 택하여 산출되는 laser 축력의 변화를 검토하였다. 그리고 $H_2$+$F_2$ 연쇄반응 HF 화학 레이저에 관한 비교적 단순한 model simulation을 수행하였다. 이 계산 결과는 이미 보고된 상당히 복잡한 계산결과와 비교하여 만족할 정도이었다.

• 제어로봇시스템학회논문지
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• 제20권5호
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• pp.537-542
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• 2014

This paper proposes a control system to keep the balance of a unicycle robot. The robot consists of the disk and wheel, for balancing and driving respectively, and the tile angle is measured and used for balancing by the IMU sensor. A PID controller is designed based on a non-model based algorithm to prove that it is possible to control the unicycle robot without any approximated linear system model such as the sliding mode control algorithm. The PID controller has the advantage that it is simple to design the controller and it does not require an unnecessary complex formula. In this paper, assuming that the pitch and roll axis are dynamically decoupled, each of the two controllers are designed separately. A reaction wheel pendulum method is used for the control of the roll axis, that is, for balancing and an inverted pendulum concept is used for the control of the pitch axis. To confirm the performance of the proposed controllers using MATLAB Simulink, the dynamic equations of the robot are derived.