• 제목/요약/키워드: Two-reaction model

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강한 측력이 작용하는 피스톤 펌프의 왕복동 피스톤 기구 부에서의 윤활모형에 관한 연구 (Lubrication Modeling of Reciprocating Piston in Piston Pump with High Lateral Load)

  • 신정훈;정동수;김경웅
    • Tribology and Lubricants
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    • 제30권2호
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    • pp.116-123
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    • 2014
  • The objective of this study is to model and simulate the nonlinear lubrication performance of the sliding part between the piston and cylinder wall in a hydrostatic swash-plate-type axial piston pump. A numerical algorithm is developed that facilitates simultaneous calculation of the rotating body motion and fluid film pressure to observe the fluid film geometry and power loss. It is assumed that solid asperity contact, so-called mixed lubrication in this study, invariably occurs in the swash-plate-type axial piston pump, which produces a higher lateral moment on the pistons than other types of hydrostatic machines. Two comparative mixed lubrication models, rigid and elastic, are used to determine the reaction force and sliding friction. The rigid model does not allow any elastic deformation in the partial lubrication area. The patch shapes, reactive forces, and virtual local elastic deformation in the partial lubrication area are obtained in the elastic contact model using a simple Hertz contact theory. The calculation results show that a higher reaction force and friction loss are obtained in the rigid model, indicating that solid deformation is a significant factor on the lubrication characteristics of the reciprocating piston part.

A MODIFIED SOLUTION PROCEDURE FOR THE ELLIPTIC-TYPE CONDITIONAL MOMENT CLOSURE MODEL IN NONPREMIXED TURBULENT REACTING FLOW

  • Liu, Tao;Huh, Kang-Yul
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 1997년도 제15회 KOSCO SYMPOSIUM 논문집
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    • pp.113-122
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    • 1997
  • The conditional moment closure formulation considering the molecular and turbulent diffusion is derived. A simplified solution procedure is proposed to reduce the computational burden due to the increased dimensionality of the conditionally averaged variables. A conditionally averaged variable is expressed as a linear weighted average of the two extremes, 'no reaction' and 'equilibrium' states. The modified elliptic-type conditional moment closure formulation is implemented to simulate a two dimensional nonpremixed mixing layer reacting flow. Results show good agreement for the conditional averages of the species concentration in Bilger et al.

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열적활성화된 과황산에 의한 염화페놀의 산화분해특성 연구 (A Study on Oxidative Degradation of Chlorophenols by Heat Activated Persulfate)

  • 손지민;권희원;황인성;김정진;김영훈
    • 한국환경과학회지
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    • 제29권1호
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    • pp.69-77
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    • 2020
  • Oxidative degradation of phenol, three monochlorophenols (2-chlorophenol, 2-CP; 3-chlorophenol, 3-CP; 4-chlorophenol, 4-CP), four dichlorophenols (2,3-dichlorophenol, 2,3-DCP; 2,4-dichlorophenol, 2,4-DCP; 2,5-dichlorophenol, 2,5-DCP; 2,6-dichlorophenol, 2,6-DCP), and two trichlorophenols (2,4,5-trichlorophenol, 2,4,5-TCP; 2,4,6-trichlorophenol, 2,4,6-TCP) was conducted with heat activated persulfate. As the number of chlorinations increased, the reaction rate also increased. The reaction rate was relatively well fitted to the zero-order kinetic model, rather than the pseudo-first order kinetic model for the reactions at 60 ℃, which can be explained by insufficient activation of the persulfate at 60 ℃, and the oxidation reaction of 2,4,6-TCP at 70 ℃ was relatively well fitted to the pseudo-first order kinetic model. The oxidation reaction rate generally increased with increase of persulfate concentration in the solution. 2,6-dichloro-2,5-cyclohexadiene-1,4-dione was found as a degradation product in a GC/MS analysis. This compound is a non-aromatic compound, and one chlorine was removed. This result is similar to the result of previous studies. The current study proved that heat activated persulfate activation could be an alternative remediation technology for phenol and chlorophenols in soil and groundwater.

오염수 내의 유기인 화합물의 측정을 위한 광섬유 바이오센서 (제 2 부 : 신호분석 및 수치모사) (Fiber-optic biosensor for the detection of organophosphorus compounds in a contaminated water (Part II : The signal analysis and simulation))

  • 최정우;민준홍;이원홍
    • 센서학회지
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    • 제3권2호
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    • pp.16-23
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    • 1994
  • 오염수에서 유기인 화합물을 측정하기 위해 개발된 광섬유 바이오센서의 신호의 분석과 최적설계를 위하여 센서에 사용되어진 AChE효소(acetylcholinesterase)의 반응, 반응기 내의 유체거동 및 물질전달현상의 해석이 필요하다. 사용되어진 센서의 반응기 부분을 해석하고 재설계하기 위하여 효소 반응을 연구하고, 이동현상학적으로 유체 및 물질확산 현상을 해석하여 반응기 모델을 성립하였다. 사용되어진 유기인 화합물에 의해 저해되는 AChE효소의 측정범위인 0-2 ppm 사이에서 저해반응을 실험하였으며, 비가역 저해 효소 반응식을 제안하였다. 반응기를 두상 즉 벌크상과 효소층으로 나누어 유체거동을 해석하였으며, 고정화겔 내의 확산의 영향을 조사하였다. 반응식, 유체거동식 및 확산식을 연계하여 세워진 반응기 전체모델을 제시하였고, 이를 이용하여 신호를 해석하였다. 제시된 모델을 이용하여 효소량, 효소층의 두께의 증가에 따른 센서 신호량의 민감도를 전산모사하였다.

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개통 이후의 지하철역 거리에 기반한 주택가격의 시간적 반응 - 개통 후 10년의 대전 도시철도를 중심으로 - (Temporal Reaction of House Price Based on the Distance from Subway Station since Its Operation - Focused on 10-year Experience after Opening of the Daejeon Urban Transit Line -)

  • 강재원;성현곤
    • 국토계획
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    • 제54권2호
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    • pp.54-66
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    • 2019
  • This study analyzed whether a subway accessibility impact on house price is constant since its operation over time or not. The study was approached specifically to answer two research questions. One is "Are there significant temporal variations in the relationship between subway accessibility and housing price transacted after its opening?" The other one is "How the pattern of its temporal variation in housing price is formed as a function of the distance from the nearest station?" The study area is the subway station areas in the Daejeon metropolitan city, South Korea. Its first subway line has started to be opened in 2006 with 12 stations and then opened its additional 10 stations in 2007. It can be more appropriate to observe its impacts of subway accessibility on housing price because it has only one transit line with more than 10-year reaction term to its operation. The study employed alternative models to estimate yearly variation of subway accessibility on house price for the station areas with 500-meter and 1-kilometer radius respectively. While the study originally considered both a hedonic price model with interaction terms of its access distance to yearly transacted housing and a time-variant random coefficient model, the former model was finally selected because it is better fitted. Based on our analysis results, the reaction of house price to its transit line had significant temporal variation over time after opening. In addition, the pattern in its variation from our analysis results indicates that its capitalization impact on house price is over-estimated in its first several years after the opening. In addition, its positive capitalization impact is more effective in the 1000-meter station area than in the 500-meter one.

Design and Control of a Firefight Cannon Manipulator Applying Sliding Mode Control

  • Vu, Mai The;Choi, Hyeung-Sik;Kang, Hyeon-Seung;Bae, Jae-Hyeon;Joo, Moon-G.;Joo, Yeong-do
    • Journal of Advanced Marine Engineering and Technology
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    • 제39권5호
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    • pp.554-562
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    • 2015
  • This paper describes an analysis of an architecture and control system of a firefighting cannon manipulator (FCM) composed of two joint axes and one water-shooting actuator. Because the orienting FCM motion is disturbed by the reaction force from water shooting, the water shooting force has been modeled for robust control. The dynamics model of the manipulator has been set up including the external force of water-shooting reaction on the manipulator. A PD Controller and Sliding Mode Controller have been designed and their performance been tested through simulation to track a desired trajectory under the disturbance of a water-shooting reaction. The simulation shows that the performance of the Sliding Mode Controller is better than that of the PD controller.

콘크리트의 수화도 및 단열온도상승량 예측모델 개발 (Mathematical Modelling of Degree of Hydration and Adiabatic Temperature Rise)

  • 오병환;차수원;신경준;하재담;김기수
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1998년도 가을 학술발표대회 논문집(III)
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    • pp.883-887
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    • 1998
  • Hydration is the main reason for the growth of the material properties. A exact parameter to control the chemical and physical process is not the time, but the degree of hydration. Therefore, it is reasonable that development all material properties should be formulated in terms of degree of hydration. Mathematical formulation of degree of hydration is based on combination of reaction rate functions. The effect of moisture conditions as well as temperature on the rate of reaction is considered in the degree of hydration model. This effect is subdivided into two contributions: water shortage and water distribution. The former is associated with the effect of on the progress of hydration. The water needed for progress of hydration do not exist and there is not enough space for the reaction products to form. The latter is associated with the effect of free capillary water distribution in the pore system. Physically absorption layer does not contribute to progress of hydration and only free water is available for further hydration.

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An innovative method for determining the diffusion coefficient of product nuclide

  • Chen, Chih-Lung;Wang, Tsing-Hai
    • Nuclear Engineering and Technology
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    • 제49권5호
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    • pp.1019-1030
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    • 2017
  • Diffusion is a crucial mechanism that regulates the migration of radioactive nuclides. In this study, an innovative numerical method was developed to simultaneously calculate the diffusion coefficient of both parent and, afterward, series daughter nuclides in a sequentially reactive through-diffusion model. Two constructed scenarios, a serial reaction (RN_1 ${\rightarrow}$ RN_2 ${\rightarrow}$ RN_3) and a parallel reaction (RN_1 ${\rightarrow}$ RN_2A + RN_2B), were proposed and calculated for verification. First, the accuracy of the proposed three-member reaction equations was validated using several default numerical experiments. Second, by applying the validated numerical experimental concentration variation data, the as-determined diffusion coefficient of the product nuclide was observed to be identical to the default data. The results demonstrate the validity of the proposed method. The significance of the proposed numerical method will be particularly powerful in determining the diffusion coefficients of systems with extremely thin specimens, long periods of diffusion time, and parent nuclides with fast decay constants.

고압하에서 수소-산소 확산화염의 소염 특성에 관한 수치 해석 (A numerical analysis on the extinction of hydrogen-oxygen diffusion flames at high pressure)

  • 손채훈;김종수;정석호;이수룡
    • 대한기계학회논문집B
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    • 제21권9호
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    • pp.1174-1184
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    • 1997
  • Extinction characteristics of pure hydrogen-oxygen diffusion flames, at high pressures in the neighborhood of the critical pressure of oxygen, is numerically studied by employing counterflow diffusion flame as a model flame let in turbulent flames in rocket engines. The numerical results show that extinction strain rate increases almost linearly with pressure up to 100 atm, which can be explained by comparison of the chain-branching-reaction rate with the recombination-reaction rate. Since contributions of the chain-branching reactions, two-body reactions, are found to be much greater than those of the recombination reactions, three-body reactions, extinction is controlled by two-body reactions, thereby resulting in the linearity of extinction strain rate to pressure. Therefore, it is found that the chemical kinetic behaviors don't change up to 100 atm. Consideration of the pressure fall-off reactions shows a slight increase in extinction strain rate, but does not modify its linearity to pressure. The reduced kinetic mechanisms, which were verified at low pressures, are found to be still valid at high pressures and show good qualitative agreement in prediction of extinction strain rates. Effect of real gas is negligible on chemical kinetic behaviors of the flames.

습지의 수질관리를 위한 연속교반탱크반응기 모델의 적용 (Application of Continuous Stirred Tank Reactor Model for Water Quality Control and Management in Wetland Treatment)

  • 김경섭;안태진;김민수
    • 한국수자원학회논문집
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    • 제41권3호
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    • pp.243-249
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    • 2008
  • 본 연구에서는 지표흐름 습지의 수질관리를 위하여 습지 내 오염물질을 적절히 모의할 수 있는 연속교반탱크반응기(CSTR) 모델을 구축하였다. 이 모델은 4차 Runge-Kutta법을 사용하고, 실측치와 계산치의 차이를 최소화 하는 최적화 기법으로 해를 구하며, 미국 EPA 습지 데이터베이스에 수록된 자료중 수질 및 수리자료가 충분하며, 분석이 용이한 하나의 수생대를 갖는 습지를 선택하여, 수질항목중 관심도가 높은 BOD, TSS (Total Suspended Solid)의 모의에 적용하였다. 습지의 체적이 일정할 경우와 체적 및 유량이 일정할 경우 각각에 대해 반응속도상수만을 고려할 경우, 물질흐름양만을 고려할 경우 및 반응속도상수와 물질흐름양 모두를 고려할 경우로 나누어 모의를 실시하였다. 모의 결과 기존의 반응속도상수만을 고려한 경우보다 반응속도상수 및 물질흐름양 모두를 고려하는 것이 실제현상을 잘 나타냈으며, 습지의 TSS 침강속도는 $0.3{\sim}0.4\;m/d$의 값을 나타내는 것으로 파악되었다. 이 모델은 습지의 수질관리에 적절히 활용할 수 있을 것으로 판단된다.