• Journal of the Korean Chemical Society
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• v.48 no.3
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• pp.261-265
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• 2004

We investigated the order of local movement of functional groups (-C(=O)O) in a liquid crystalline (LC) oligomer (12-4) using 2D Raman correlation spectroscopy. The results suggest that the free carbonyl near the ethyl terminal group moved first, followed by the hydrogen-bonded group. The free carbonyl group between the biphenyl groups rarely moved. Interestingly, 2D sample-to-sample correlation spectroscopy (2D STSCS) revealed that some of the carbonyl modes started to move at far below (50$^{\circ}C$) the LC temperature (135$^{\circ}C$), countering conventional beliefs.

• Steel and Composite Structures
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• v.27 no.4
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• pp.525-536
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• 2018

This paper focuses on the application of the first-order shear deformation theory (FSDT) to thermo-elastic static problems of functionally graded carbon nanotubes reinforced composite (FG-CNTRC) cylindrical pressure vessels. A symmetric displacement field is considered as unknown function along the longitudinal direction, whereas a linear distribution is assumed along the thickness direction. The cylindrical pressure vessels are subjected to an inner and outer pressure under a temperature increase. Different patterns of reinforcement are applied as distribution of CNTs. The effective material properties of FG-CNTRC cylindrical pressure vessels are measured based on the rule of mixture, whereas the governing equations of the problem are here derived through the principle of virtual works. A large parametric investigation studies the effect of some significant parameters, such as the pattern and volume fraction of CNTs, on the longitudinal distribution of deformation, strain and stress components, as useful tool for practical engineering applications.

• Journal of the Semiconductor & Display Technology
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• v.18 no.3
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• pp.12-18
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• 2019

The protective double layer polymer coatings on silica optical fibers are realized by wet-on-wet liquid coating process and they play an important role in final quality of mass produced optical fibers. This numerical study aims to analyze the effects of secondary coating die design parameters by employing two dimensional axisymmetric model of coating cup and coating die geometry and computational fluid dynamics simulations which include temperature dependent viscosity of polymer coating liquids and viscous dissipation heating. Under high speed fiber drawing conditions and pressurized coating liquid supply, the effects of converging die angle are investigated in order to appreciate the change of coating liquid flow patterns such as flow recirculation zone near coating die as well as primary and secondary coating layer thicknesses. The auxiliary coating die to converging coating die is also tested and the results find that this concept is advantageous in achieving stable double layer coatings on silica glass fiber.

• Bulletin of the Korean Chemical Society
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• v.33 no.6
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• pp.1949-1954
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• 2012

We have developed a novel and eco-friendly synthetic route for the preparation of a two-dimensional layered zinc hydroxide with intercalated nitrate anions. The layered zinc hydroxide nitrate, called 'zinc basic salt', was, in general, successfully synthesized, using an electron beam irradiation technique. The 2-propanol solutions containing hydrated zinc nitrate were directly irradiated with an electron-beam at room temperature, under atmospheric conditions, without stabilizers or base molecules. Under electron beam irradiation, the reactive OH radicals were generated by radiolysis of water molecules in precursor metal salts. After further radiolytic processes, the hydroxyl anions might be formed by the reaction of solvated electrons and the OH radical. Finally, the $Zn_5(OH)_8(NO_3)_2{\cdot}2H_2O$ was precipitated by the reaction of zinc cation and hydroxyl anions. Structure and morphology of obtained compounds were characterized by powder X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and high resolution transmission electron microscopy (HR-TEM). The chemical components of the products were determined by Fourier transform infrared spectroscopy (FT-IR) and elemental analysis (EA). The thermal behavior of products was studied by thermogravimetric (TG) and differential thermal analysis (DTA).

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2004.03a
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• pp.34-40
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• 2004

Two different type scramjet models with side-wall compression and top-wall compression inlets have been tested in HPTF (Hypersonic Propulsion Test Facility) under the experimental conditions of Mach number 5.8, total temperature 1700K, total pressure 4.5㎫ and mass flow rate 3.5kg/s. The liquid kerosene was used as main fuel for the scramjets. In order to get fast ignition in the combustor, a small amount of hydrogen was used as a pilot. A strut with alternative tail was employed for increasing the compression ratio and for mixing enhancement in the side-wall compression case. Recessed cavities were used as a flameholder for combustion stability. The combustion efficiency was estimated by one dimensional theory. The uniformity of the facility nozzle flow was verified by a scanning pitot rake. The experimental results showed that the kerosene fuel was successfully ignited and stable combustion was achieved for both scramjet models. However the thrusts were still less than the model drags due to the low combustion efficiencies.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.112-115
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• 2017

We analyzed the rocket engine flow to check whether the possibility of the ground test and the equipment safety problems in the high altitude engine test facility. The test condition is that the vacuum chamber is open and the coolant water is injected into the supersonic diffuser. The analysis uses two-dimensional axisymmetry with a mixture of plume, air, and cooling water. As a result, the ground test was possible up to the cooling water flow rate of 200 kg/sec. However, due to the back flow of the initial plume, the vacuum chamber is exposed to high temperature, and at the same time, the inside of the vacuum chamber is contaminated due to the reverse flow of the cooling water. Therefore, sufficient insulation measures and work for pollution avoidance should be preceded.

• Transactions of the Korean hydrogen and new energy society
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• v.17 no.2
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• pp.158-165
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• 2006

In order to provide the database for designing microcombustors, the combustion characteristics of premixed methane and propane air microflames at normal and elevated temperatures and atmospheric pressure generated on a microtube were studied experimentally and computationally. The stability limits of premixed microflames and the propensity of the microflames near the stability limits were experimentally determined, while the structure of the microflame at the fuel-leanest limit was obtained using a two-dimensional CFD simulation with a reduced kinetic mechanism. For all the microflames, the stability limits were observed only in the fuel-rich region. Results also show substantial extension of stability limits with elevated temperature that is realistic condition for micro fuel processing and significant fuel dilution immediately near the tube exit due to a low Peclet number times Lewis number effect.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.12 no.1
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• pp.18-26
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• 1999

In this study, the undoped amorphous layers and phosphorus doped amorphous layers are fabricated using LPCVD at 531$^{\circ}C$ with SiH$_4$ gas or at same temperature with PH$_3$ gas during deposition, respectively. The thickness of deposited amorphous layer from this experiments was 5000 ${\AA}$. In this experiments, undoped amorphous layers are deposited with SiH$_4$and Si$_2$H$\_$6/ gas in a low pressure reactor using LPCVD. These amorphous layers can be doped for poly-silicon by phosphorus ion implantation. The experiments of this study are carried out by phosphorus ion implantation with energy 40 keV into P doped and undoped amorphous silicon layers. The distribution of phosphorus profiles are measured by SIMS(Cameca 6f). Recoiling effects and two dimensional profiles are also explained by comparisions of experimental and simulated data. Finally range moments of SIMS profiles are calculated and compared with simulation results.

• Journal of Ocean Engineering and Technology
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• v.26 no.5
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• pp.87-93
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• 2012

Many longitudinally-arranged pipes in ships are equipped with loops as a measure to reduce stresses caused by displacement loads conveyed from the hull girder bending and/or thermal loads of carried fluid of non-ambient temperature. But as the loops have some negative effects such as causing extra manufacturing cost and occupying extra space, the number and the dimensions of the loops need to be minimized. In the meanwhile, a design formula for pipe loops has been developed by modeling them as a spring element of which stresses and axial stiffness are calculated based on the beam theory. But as the beam theory turns out to be inappropriate to deal with the complex structural behavior in the curved corner portion of the loop, this paper aims at improving the previously developed design formula by adopting correction factors which can allow for the gap between the results of beam theory and a more accurate analysis. This paper adopts a finite element analysis with two-dimensional shell elements with some validation work for it. The paper ends with a sample application of the proposed formulas showing their accuracy and efficiency.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.8 no.1
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• pp.18-27
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• 1996

Efforts are concentrated onto effective simulation of surface discharged heat water in two-dimensional depth-averaged finite element model using Gaussian puff algorithm incorporating near-field characteristics as patches computed from CORMIX3 with ambient flow variations. Concise analyses of horizontal and vertical temperature distributions are made for real coastal power plant discharges through four field observations and the results from this proposed method are in good agreements with observations in far-field as well as near-field. Thus, this method can simulate the heat dispersion effectively for the whole region since the complex jet momentum characteristics and ambient flows are easily represented in 10 meters of finite element discretization around a discharging point.