• Journal of Institute of Convergence Technology
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• v.4 no.2
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• pp.23-26
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• 2014

As an effective separation method for biomolecules, aqueous two-phase systems based on ionic liquids were suggested. Hydrophobic ionic liquids are more expensive and viscous in spite of their usage in the ionic liquid/water biphasic extraction compared with hydrophilic ionic liquids. In case of aqueous two-phase systems using hydrophilic ionic liquids, they can be diluted in aqueous phase. Experimental results show that aqueous two phase systems can be formed by adding appropriate amount of ionic liquids to aqueous salts solutions. The viscosity of ionic liquid aqueous phase is proportional to the cation chain length in ionic liquids. It is founded that the ionic liquid based aqueous two phase systems are effective for the separation of biomolecules such as acrylic acid.

• Korean Chemical Engineering Research
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• v.52 no.5
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• pp.627-631
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• 2014

As an effective method for extraction of acrylic acid, aqueous two-phase systems based on morpholinium ionic liquids were used in this study. Effects of the alkyl chain length of cation in morpholinium ionic liquids on phase diagram and extraction efficiencies were investigated. Experimental results show that aqueous two phase systems can be formed by adding appropriate amount of morpholinium ionic liquids to aqueous $K_2HPO_4$ solutions. It can be found that the ability of morpholinium ionic liquids for phase separation followed the order [HMMor][Br]>[OMMor][Br]>[BMMor][Br]>[EMMor][Br]. There was little difference between binodal curves of imidazolium ionic liquids and those of morpholinium ionic liquids. 50~90% of the extraction efficiency was observed for acrylic acid by aqueous two phase extraction of acrylic acid with morpholinium ionic liquids. It can be concluded that morpholinium ionic liquids/$K_2HPO_4$ were effective for aqueous two phases extraction of acrylic acid comparing to imidazolium ionic liquids/$K_2HPO_4$ systems because of their lower cost.

• Korean Chemical Engineering Research
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• v.54 no.1
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• pp.52-56
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• 2016

As an effective method for extraction of succinic acid, aqueous two-phase systems based on piperidinium ionic liquids were used in this study. Effects of the alkyl chain length of cation in piperinidium ionic liquids on phase diagram and extraction efficiencies were investigated. Experimental results show that aqueous two phase systems can be formed by adding appropriate amount of piperidinium ionic liquids to aqueous $K_2HPO_4$ solutions. It can be found that the ability of piperidinium ionic liquids for phase separation followed the order [OMPip][Br]>[HMPip][Br]>[BMPip][Br]>[EMPip][Br]. The biphase-forming ability of piperidinium ionic liquids was higher than that of imidazolium and pyrrolidinium ionic liquids in the presence of $K_2HPO_4$. 75~95% of the succinic acid could be extracted into the ionic liquid-rich phase in a single-step extraction. There was little difference in the extraction efficiency of succinic acid by piperidinium ionic liquids comparing to other ionic liquids such as imidazolium and pyrrolonidium ionic liquids. This aqueous two phase system by piperidinium ionic liquid is suggested to have effective application for the separation of succinic acid.

• Phonetics and Speech Sciences
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• v.9 no.3
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• pp.7-15
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• 2017

The purpose of this study was to investigate the different aspects of word-initial liquid sounds in Korean according to generations. Five women in their 50s and seven in their 20s participated in the experiment. We examined FL (formant of liquids) and voice sustained time by using Praat software. Three English native speakers were asked to judge the Korean speakers' recorded speech samples for marking [l] or [r] using evaluation sheet. The results of the two experiments revealed three important aspects. First, there was a statistically significant difference between the two groups in the FL of the words 'racket' and 'ruby.' Second, we found statistically significant differences in 'rhythm', 'ruby' and 'litter' from the measurement of the duration of the acoustic data. Third, there was no difference in pronunciation between the two groups according to the phonemes of the original language. The results of this study showed that it is difficult to say that the duration of word-initial liquids and the phoneme difference of the original language are indicators to distinguish the word-initial liquids between generations. Also, it was seen that the pronunciation of Korean word-initial liquid sounds varied across generations.

• Transactions of the Korean Society of Mechanical Engineers
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• v.13 no.3
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• pp.373-384
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• 1989

The motions of a spinning rotor and a fluid enclosed in its cavity are known to have mutual interactions, which change the frequencies of forced vibrations and cause instabilities. These phenomena are of technical importance for fluid-cooled turbines as well as spin-stabilized satellites or rockets containing liquid fuels. In this paper the characteristics of unstable whirling of a rotor containing a partitioned cavity filled with two kinds of liquids are investigated experimentally. It studies the influence of rotational speed and filling ratio of two kinds of liquids on unstable whiring. As a result, it is found that the whirl velocity is approximately equal to, or slightly lower for large masses of trapped fluid than rotor critical speed. In case of a spinning rotor partially filled with two kinds of liquids the boundary surface plays a similar role to the free surface, and cases unstable forward whirl.

• Journal of the Korean Chemical Society
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• v.15 no.4
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• pp.171-175
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• 1971

Significant structure theory has been applied to the viscosities of supercooled liquids with success. In the supercooled region, the effect of free volume decrease is so significant that the thermal effects on the solid-like volume must be considered properly. In addition, the two state theories proposed by Jhon and Eyring for water and Litovitz et al. for boron trioxide have been successfully applied to the structure change in the liquid state. Considered liquids are benzene, carbon tetrachloride, p-xylene, water and boron trioxide.

• Bulletin of the Korean Chemical Society
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• v.21 no.7
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• pp.697-700
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• 2000

A method of calculating the excess Helmholtz free energy from the average of the bent effective acceptance ratio for two-center-Lennard-Jones liquids has been presented. The bent effective acceptance ratio has been newly composed from the acceptan ce ratio for the potential energy difference between a configuration in the Metropolis Monte Carlo procedure and random virtual configuration generated by the separate parallel Monte Carlo procedure and the Boltzmann factor for half the potential energy difference. The excess Helmholtz free energy was calculated directly from the average of the bent effective acceptance ratio through a single Metropolis Monte Carlo run. Because the separate parallel Monte Carlo procedure was used, this method can be applied to molecular dynamics simulations. For two-center-Lennard-Jones liquids, the average of the bent effective acceptance ratio gave better results than use of the modified effective acceptance ratio in the previous work.

• Tribology and Lubricants
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• v.30 no.6
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• pp.323-329
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• 2014

The friction-reducing properties of lubricants containing ionic liquids based on ammonium dithiocarbamate are studied. The ionic liquids are produced through the following two steps: the synthesis of sodium alkyl dithiocarbamates via the substitution reaction of dialkylamine and carbon disulfide and their subsequent conversion into ammonium dithiocarbamate-based ionic liquids through an ion-exchange reaction with a quaternary alkyl ammonium halide salt. The structures of the ionic liquids are characterized by NMR spectroscopy and Fourier transform infrared spectroscopy. The isolated yields of the ionic liquids, which are viscous and pale yellow, are approximately 92%. The Brookfield viscosities and pour points of the ionic liquids are determined. Further, their wear resistances are measured through the four-ball wear test and the Schwingung Reibung Ver-schleiss (oscillation, friction, wear) test. The wear scar diameter of the lubricants containing 1 wt of the quaternary alkyl ammonium dithiocarbamate-based ionic liquids (0.475-0.631 mm) is significantly lower than that of the base oil (0.825 mm), proving that the ammonium dithiocarbamate-based ionic liquids have good friction-reducing characteristics. However, these friction-reducing characteristics fade significantly after long-term storage, owing to the degradation of the ionic liquids.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.45 no.2
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• pp.56-65
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• 2013

Electron beam treatment was applied for improving dissolution of cellulose with ionic liquids. Two ionic liquids, 1-allyl-3-methylimidazolium chloride ([Amim]Cl]: AC) and 1,3-dimethylimidazolium methylphosphite ([Dmim][$(MeO)(H)PO_2$]: Me) were used for this experiment. Treatment with electron beams up to dose of 400 kGy resulted in the increase of hot water extract and alkali extract of cotton pulp and the great reduction in the molecular weight of cellulose. For the dissolution of cotton pulp with two ionic liquids, the electron beam treated samples showed faster dissolution. The dissolved cellulose with Me ionic liquid were regenerated with acetonitrile and the structure of regenerated cellulose showed distinct difference depending on the electron beam treatment. Those results provide the electron beam pre-treatment could be applied as an energy efficient and environmentally benign method to increase the dissolution of cellulose with ionic liquids.

• Transactions of the Korean Society of Automotive Engineers
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• v.7 no.5
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• pp.31-39
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• 1999

A good atomization in uniform size brings the elevation of thermal efficiency in spray combustion, the beautiful painting on surfaces, and the economical sprinkling of chemicals. Ultrasonic atomization has been expected as a good uniform atomization mechanism due to its uniform size distribution. Influx, load, and physical properties of liquids are the effecting factors to atomize liquids. In this study, distilled water and city water are selected as reference liquids and gasoline, kerosene, and petroleum as fuel liquids. Characteristics and affinity to get the maximum effect for the ultrasonic atomization are observed by using the two ultrasonic transducers with 28kHz and 2MHz. Results show that the size distributions of liquid spray dorplet by the direct vibration method prevail over those by the aerosol method in uniform droplet size and as a whole, sizes of spray liquid droplets are increased slightly according to increasing influx in the direct vibration method and quantities of spray droplets in the aerosol method decreasing according to increasing liquid load h.