• Title/Summary/Keyword: Tube conductivity

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Effect of Conductive Additives on $FeS_2$ Cathode ($FeS_2$ 양극에 미치는 전도성 첨가제의 영향)

  • Choi, Yu-Song;Cheong, Hae-Won;Kim, Ki-Youl;Cho, Sung-Baek
    • Journal of the Korea Institute of Military Science and Technology
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    • v.15 no.2
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    • pp.224-230
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    • 2012
  • Thermal batteries have excellent mechanical robustness, reliability, and long shelf life. Due to these characteristics as well as their unique activation mechanism, thermal batteries are widely adopted as military power sources. Li(Si)/$FeS_2$ thermal batteries, which are used mostly in these days, use LiCl-KCl and LiBr-LiCl-LiF as molten salt electrolyte. However, it is known that Li(Si)/$FeS_2$ thermal batteries have high internal resistance. Especially, $FeS_2$ cathode accounts for the greater part of internal resistance in unit cell. Many efforts have been put into to decrease the internal resistance of thermal batteries, which result in the development of new electrode material and new electrode manufacturing processes. But the applications of these new materials and processes are in some cases very expensive and need complicated additional processes. In this study, internal resistance study was conducted by adding carbon black and carbon nano-tube, which has high electron conductivity, into the $FeS_2$ cathode. As a results, it was found that the decrease of internal resistance of $FeS_2$ cathode by the addition of carbon black and carbon nano-tube.

Research in Crystalization and Conductivity of Electricity of Ge-Se-Bi System Chalcogenide Glass (Ge-Se-Bi계 칼코게나이드 유리의 비정질 및 결정화에 따른 전기 전도도의 변화)

  • Lee, Myeong-Won;Gang, Won-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1992.11a
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    • pp.77-81
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    • 1992
  • The purpose of this research was th evaluate conductivity of electricity of Ge-Se-Bi system Chalcogenide glass as a amorphous semiconductor by observing its dissolution and crystallization. In this experiment. Ge-Se-Bi metal powder in the rage of $Ge_{12-25}$, $Se_{65-85}$, $Bi_{2.5-15}$ was used as the sample ore. The ore was. put into a vaccous quartz tube and then melted. The condition of heat treatment was to dispose it to $1000^{\circ}C$ heat for 10 hours and then rapidly quenched it at $3834^{\circ}C$/see. The crystallization of the fused sample ripened as the change of temperature and time, after the crystal core was formell. At that time it was possible to observe the state that $Bi_2Se_3$ and $GeSe_2$ were crystallized. In the experiment of making memberance, the memberance was produced by using the previously experimented bulk sample. And decrystalization was well progressed when Ge was over 15 at %, Se was over 70 at %, and Bi was under 10 at%. As for bulk. when Ge was fixed to 20 at %, the conducting of electricity was increased as Bi gained at %. In the case of memberance, the conductivity was much more increased than that of bulk sample as the increase of at the increase of at % of Bi. In the experiment on $Ge_{20}$, $Se_{77.5}$ and $Bi_{2.5}$, the crystallization sswas most vigorous when they were kept at $330^{\circ}C$ for 4 hours.

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Electrical Properties of PVdF/PVP Composite Filled with Carbon Nanotubes Prepared by Floating Catalyst Method

  • Kim, Woon-Soo;Song, Hee-Suk;Lee, Bang-One;Kwon, Kyung-Hee;Lim, Yun-Soo;Kim, Myung-Soo
    • Macromolecular Research
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    • v.10 no.5
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    • pp.253-258
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    • 2002
  • The multi-wall carbon nanotubes (MWNTs) with graphite crystal structure were synthesized by the catalytic decomposition of a ferrocene-xylene mixture in a quartz tube reactor to use as the conductive filler in the binary polymer matrix composed of poly(vinylidene fluoride) (PVdF) and poly(vinyl pyrrolidone) (PVP) for the EMI (electromagnetic interference) shielding applications. The yield of MWNTS was significantly dependent on the reaction temperature and the mole ratio of ferrocene to xylene, approaching to the maximum at 800 $^{\circ}C$ and 0.065 mole ratio. The electrical conductivity of the MWNTs-filled PVdF/PVP composite proportionally depended on the mass ratio of MWNTs to the binary polymer matrix, enhancing significantly from 0.56 to 26.7 S/cm with the raise of the mass ratio of MWNTs from 0.1 to 0.4. Based on the higher electrical conductivity and better EMI shielding effectiveness than the carbon nanofibers (CNFs)-filled coating materials, the MWNTs-filled binary polymer matrix showed a prospective possibility to apply to the EMI shielding materials. Moreover, the good adhesive strength confirmed that the binary polymer matrix could be used for improving the plastic properties of the EMI shielding materials.

Removal of Rhodamine B Dye Using a Water Plasma Process (수중 플라즈마 공정을 이용한 Rhodamine B 염료의 제거)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Health Sciences
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    • v.37 no.3
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    • pp.218-225
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    • 2011
  • Objectives: In this paper, a dielectric barrier discharge (DBD) plasma reactor was investigated for degrading the dye Rhodamine B (RhB) in aqueous solutions. Methods: The DBD plasma reactor system in this study consisted of a plasma component [titanium discharge (inner), ground (outer) electrode and quartz dielectric tube], power source, and gas supply. The effects of various parameters such as first voltage (input power), gas flow rate, second voltage (output power), conductivity and pH were investigated. Results: Experimental results showed that a 99% aqueous solution of 20 mg/l Rhodamine B is decolorized following an eleven minute plasma treatment. When comparing the performance of electrolysis and plasma treatment, the RhB degradation of the plasma process was higher that of the electrolysis. The optimum first voltage and air flow rate were 160 V (voltage of trans is 15 kV) and 3 l/min, respectively. With increased second voltage (4 kV to 15 kV), RhB degradation was increased. The higher the pH and the lower conductivity, the more Rhodamine B degradation was observed. Conclusions: OH radical generation of dielectric plasma process was identified by degradation of N, N-dimethyl-4-nitrosoaniline (RNO, indicator of OH radical generation). It was observed that the effect of UV light, which was generated as streamer discharge, on Rhodamine B degradation was not high. Rhodamine B removal was influenced by real second voltage regardless of initial first and second voltage. The effects of pH and conductivity were not high on the Rhodamine B degradation.

Research on the Heat Exchanger for Kimchi Refrigerator Using Thermal Conductive Plastic (열전도성 플라스틱을 이용한 김치냉장고용 열교환기에 관한 연구)

  • Kang Tae-Ho;Baek Jong-Yong;Kwon Yong-Ha;Kim In-Kwan;Kim Young-Soo;Sin Dae-Sik;Park Jae-Hong
    • Journal of Advanced Marine Engineering and Technology
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    • v.29 no.4
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    • pp.407-416
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    • 2005
  • The kimchi refrigerator is the electric home appliance which is used for the maturing and preserving of the kimchi in domestic and foreign market. The kimchi refrigerator is composed in 3 main parts as insulation. kimchi container, machinery room. The heat exchanger of kimchi refrigerator is made of aluminum and the other parts are made of steel and polymer. Also, kimchi refrigerator is expensive and heavy as compared with same class of refrigerator until now. In the present study, the possibility to replace heat exchanger from aluminum to thermal conductive plastic was analyzed and experimented. The thermal conductive plastic has $10{\sim}100$ times heat conductivity than that of normal plastic. It is known that heat transfer process is dependent not only conduction but convection or radiation. Thermal conductivity of the applied material in this research is over than 2 W/mK, thermal conductivity doesn't play a vital role on heat transfer. In this study, temperature is the most important parameter on the kimchi refrigerator and the temperature of kimchi refrigerator's heat exchanger was measured and compared with the temperature calibrated by CFD analysis on the inside wall of the kimchi refrigerator. It is important to keep constantly the inside temperature of the Kimchi refrigerator. Besides numerical analyses for the new thermal conductive plastic for heat exchanger were executed with the various height of evaporation tube. A series of experiments were conducted to compare the performance of the two heat exchanger made of aluminum and thermal conductive plastic at the same condition and certified the possibility of the thermal conductive plastic. According to these results, it was confirmed that the conventional aluminium heat exchanger can be replaced by thermal conductive plastic successfully.

The Study on Pressure Oscillation and Heat Transfer Characteristics of Oscillating Capillary Tube Heat Pipe Using Mixed Working Fluid (혼합 작동 유체를 이용한 진동 세관형 히트 파이프의 압력 진동과 열전달 특성에 관한 연구)

  • Jeong, Hyeon-Seok;Kim, Jeong-Hun;Kim, Ju-Won;Kim, Jong-Su
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.2
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    • pp.318-327
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    • 2002
  • In this paper, heat transfer and pressure oscillation characteristics on oscillating capillary tube heat pipe(OCHP) according to input heat flux, mixture ratio of working fluid and inclination angle were investigated and were compared single working fluid(R-142b) with binary mixture working fluid(R-142b-Ethano1). OCHP was made to serpentine structure of loop type with 10 turns by drilling the channels of length 220mm, width 1.5mm, and depth 1.5mm on the surface of brass plate. In this study, R-l42b and R-l42b-Ethanol were used as working fluids, the charging ratio of working fluids was 40(vol.%), the input heat flux to evaporating section was changed from 0.3W/㎠ to 1.8W/㎠, and mixture ratio of working fluid was R(100%), R(95%)-E(5%), R(90%)-E(10%), and R(85%)-E(15%). From the experimental results, it was found that the effective thermal conductivity of single working fluid was better than that of binary mixture working fluid. But, in case of binary mixture working fluid, critical heat flux was higher than that of single working fluid. And, the higher the mixture ratios of working fluid, the lower heat transfer performance. In case of pressure oscillation, as the inclination angle was lower, pressure wave was more irregular. These phenomena were more serious when the working fluid was binary mixture. Besides, when mixture ratio was higher, saturated pressure was increased, more irregular wave was observed and the mean amplitude was increased. For the same input heat flux, inclination angle and charging ratio, when pressure oscillation has sinusoidal wave, mean amplitude was small, and saturated pressure was low value, the heat transfer was excellent.

Shell and Tube Heat Exchanger Performance Estimation by Changing Shell-side Fluid Characteristics (쉘-튜브 열교환기에서의 쉘쪽 유체의 특성에 따른 열교환기 성능 변화 예측 사례)

  • Baek, Seungwhan;Jung, Youngsuk;Cho, Kiejoo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.2
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    • pp.27-37
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    • 2019
  • The shell and tube heat exchangers installed in the propulsion system test complex (PSTC) at the Naro Space Center heats cryogenic helium to 500 K with a heat transfer oil. As the experimental helium outlet temperature was lower than expected (less than 100 K), the boundary layer effect of the heat transfer oil is predicted to be the cause of the performance deterioration. A computational fluid dynamics (CFD) analysis was performed to verify where the boundary layer effect exists; however, the boundary layer effect has no significant impact on the performance of the heat exchanger. An alternative method to improve the performance of the heat exchanger by changing the heat transfer oil has been discussed in this paper. The low viscosity and high thermal conductivity at high temperature (~500 K) of heat transfer oil at the shell-side are required to improve the thermal performance of the heat exchanger. The experimental performance of the heat exchanger, used to exchange heat between the cryogenic helium and hot heat transfer oil at the PSTC are summarized in this paper.

The development of complex electrode for fuel cell using CNT (CNT를 이용한 PEMFC 연료전지용 복합전극 개발)

  • Ok, Jinhee;Altalsukh, Dorjgotov;Rhee, Junki;Park, Sangsun;Shul, Yonggun
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.135.2-135.2
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    • 2010
  • Carbon nanotube(CNT) has been spotlighted as a promising candidate for catalyst support material for PEMFC (proton exchange membrane fuel cell). The considerable properties of CNT include high surface area, outstanding thermal, electrical conductivity and mechanical stability. In this study, to fully utilize the properties of CNTs, we prepared directly oriented CNT on carbon paper as a catalyst support in the cathode electrode. The CNT layer was prepared by a chemical vapor deposition(CVD) process. And the Pt particles were deposited on the CNT oriented carbon paper by impregnation and eletro-deposition method. The potential advantages of directly oriented CNT on carbon paper can include improved thermal and charge transfer through direct contact between the electrolyte and the electrode and enhanced exposure of Pt catalyst sites during the reaction.

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Performance Test of Low Temperature Waste Heat Recovery Heat Exchanger Using Self-excited Oscillating Heat Pipe (자려 진동형 히트 파이프를 이용한 저온 폐열 회수 열교환기의 성능 실험)

  • 이욱현;이종현;김종수
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.12 no.9
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    • pp.853-859
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    • 2000
  • In this study, low temperature waste heat recovery heat exchanger was developed using a principle of self-excited oscillating heat pipe. The heat exchanger of serpentine type was composed of extruded flat aluminum tube with 6 channels (3 nm$\times$ 2.75nm) and louvered fin. The heat transfer area density of heat exchanger was $331.9 m^2/m^3$. Working fluid is R141b and charge ratio was 40% by volume. Heat transfer rate and the effectiveness of heat exchanger was primary concern of this study. As a result, the effectiveness of heat exchanger was about 0.4-0.67, and recovered waste heat rate was about 4.5 kW per one unit of heat exchanger.

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Forced Convection in a Circular Pipe with a Partially Filled Porous Medium

  • Kim, Woo-Tae;Hong, Ki-Hyuek;Myung S. Jhon;John G. VanOsdo;Duane H. Smith
    • Journal of Mechanical Science and Technology
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    • v.17 no.10
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    • pp.1583-1596
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    • 2003
  • A study of forced convection in a circular pipe with a partially filled porous medium was numerically investigated. The Brinkman-Forchheimer extension of the Darcy model was used to analyze the and temperature distribution in the porous medium. Our study includes two types of porous layer configurations: (1) a layer attached at the tube wall extending inward towards the centerline and (2) a layer at the centerline extending outward. The effect of several parameters, such as Darcy number, effective viscosity, effective thermal conductivity, and inertia parameter, as well as the effect of geometric parameters, were investigated.