• Journal of the Korean Society of Combustion
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• v.14 no.3
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• pp.16-23
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• 2009

It is strongly desired for coal-fired power plants to utilize not only low-rank coals with high moisture contents, but also lowering cost with diversifying fuel sources. In this study, combustion characteristics of low rank coal with high moisture, and standard pulverized coals are experimentally investigated using TGA (Thermogravimetric Analysis) and DTF (drop tube furnace). The coals tested are three kinds of coal with moisture content ranging from 8.32 to 26.82%. The results show that under the air combustion condition, the burn-out time at TGA rises as moisture content increases, and standard pulverized coal with 8.32% moisture content showed the lowest activation energy of 55.73 kJ/mol. In case of the high amount of moisture, the combustion efficiency decreases due to evaporation heat loss, and unburned carbon in ash produced at combustion process in DTF increased. Aslo, initial deformation temperature of slag attached in alumina tube of DTF decreased with lowering the crytallinity of anorthite and augite. To improve the combustion reactivity and efficiency, it is effective to upgrade through drying the high moisture coal to moisture level (less than 10%) of standard pulverized coal.

• Progress in Superconductivity
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• v.10 no.2
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• pp.103-107
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• 2009

$Bi_2Sr_2Ca_1Cu_2O_x$(BSCCO 2212) superconductors for current lead were fabricated by centrifugal melting process(CMP). BSCCO 2212 powder was melted at $1200^{\circ}\C$ in a resistance furnace using a Pt crucible and poured in a rotating cylindrical mold preheated at $550^{\circ}\C$ for 2 hour. The solidified BSCCO-2212 samples were heat-treated by partial melting process in oxygen atmosphere. The current-voltage curves at 77 K of the samples were obtained by transport measurement, and the microstructure was investigated by scanning electron microscope. The $J_c$ values at 77 K of the tubes partially melted at $840^{\circ}C,\;860^{\circ}C\;and\;880^{\circ}C$ were 492, 430 and 398 $A/cm^2$, respectively. It was observed that the plate-like grains in BSCCO 2212 tube was more developed in the sample heat-treated at $840^{\circ}C$. It was found that the critical current of the BSCCO 2212 samples was dependent on the partial melting schedule regarding the grain shape and size of the BSCCO 2212.

• Proceedings of the KSME Conference
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• 2000.11b
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• pp.174-179
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• 2000

Ultrafine particles have been used widely in many high technology industrial areas. The spherical nonagglomerated and uniform nanometer-size $SiO_2$ particles are synthesized by the direct injection of TEOS(Tetraethyorthosilicate) using electro-hydrodynamic spray ins method. Electro-hydrodynamic spray can generate in the range of submicron-size TEOS particles with high electric charge by applying a high electric field between the liquid injection nozzle and the reaction tube. This TEOS particles are thermally decomposed or oxidized to produce nanometresized $SiO_2$ particles in the reaction tube. Spherical, nonagglomerated and ultrafine particle generated and examined at furnaced temperature, $800^{\circ}C$ and TEOS flowrate of 0.49 or $1.00cm^3/hr$ using SEM and SMPS. As the total gas flowrate changes from 1.51pm to 5.01pm, the mean diameter of $SiO_2$ particle decreases from 120 nm to 68nm.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.415-415
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• 2012

ZnO nanostructures were synthesized by a vapor phase transport process in a single-zone furnace within a horizontal quartz tube with an inner diameter of 38 mm and a length of 485 mm. The ZnO nanostructures were grown on Au-catalyzed Si(100) substrates by using a mixture of zinc oxide and graphite powders. The growth of ZnO nanostructures was conducted at $800^{\circ}C$ for 30 min. High-purity Ar and $O_2$ gases were pushed through the quartz tube during the process at a flow rate of 100 and 10 sccm, respectively. The sequence of ON/OFF cycles of the Ar gas flow was repeated, while the $O_2$ flow is kept constant during the growth time. The Ar gas flow was ON for 1 min/cycle and that was OFF for 2 min/cycle. The structure and optical properties of the ZnO nanostructures were investigated by field-emission scanning electron microscope, X-ray diffraction, temperature-dependent photoluminescence. The preferred orientation of the ZnO nanostructures was along c-axis with hexagonal wurtzite structure.

• Journal of the Korean Society for Nondestructive Testing
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• v.22 no.2
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• pp.140-148
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• 2002

Anisotropic elastic constants of Zr-2.5Nb pressure tube materials were determined by a high temperature resonant ultrasound spectroscopy (RUS). The resonant frequencies were measured using alumina wave-guides and wide band ultrasonic transducers in a small furnace. The rectangular parallelepiped specimens were fabricated along with the axial, radial and circumferential direction of the pressure tube. A nine elastic stiffness tensor for orthotropic symmetry was determined in the range of room temperature ${\sim}500^{\circ}C$. As the temperature increases, the elastic constant tensor, cij gradually decreases. Higher elastic constants along the transverse direction compared to those along the axial or radial direction are similar to the case of Young's modulus or shear modulus. A crossing of shear elastic constants along axial direction and radial direction was observed near $150^{\circ}C$. This fact corresponds to the crossing of c44 and c66 of single crystal zirconium.

• 한국연소학회:학술대회논문집
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• 2006.10a
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• pp.168-174
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• 2006

A pilot scale (200kg/hr) pyrolysis melting incineration system is designed and constructed in Korea Institute of Industrial Technology. The incineration process is composed of pyrolysis, gas combustion, ash melting, gas stabilization, waste heating boiler, and bag filter. For each unit process, experimental approaches have been conducted to find optimal design and operating conditions. Especially, a pyrolysis is very important process in that it is a way of energy recirculation and minimizing the waste products. This paper presents major results of the most efficient operating conditions in a pilot scale pyrolysis melting incinerator.

• 한국연소학회:학술대회논문집
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• 2006.10a
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• pp.276-281
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• 2006

Although fireside corrosion of heat transfer surfaces in coal fired steam generators has been a problem to some extent for a number of tears, with the advent of low NOx firing systems these surfaces can be exposed to conditions that will exacerbate wastage rates. Numerous reports of waterwall wastage in coal fired boilers have appeared in the literature. It is believed that wastage results both from gaseous phase attack of metal surfaces and from deposition of ash and unburned fuel. Gaseous phase attack is known to occur in the presence of reducing sulfur species such as $H_2S$ and in the presence of fuel chlorine. The highest wastage rates are thought to be due to deposition of unoxidized material and the presence of fuel chlorine. Localized wall and near wall conditions that may exacerbate wastage include reducing conditions, high temperatures, high heat fluxes, and a high fraction of unoxidized material deposited. So, this study is directed at developing an advanced corrosion model in coal-fired utility boilers.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.11a
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• pp.243-243
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• 2009

Bi2O3 doped ZnO nanostructures structure were successfully synthesized by a thermal evaporatiion process and their structural characteristics were investigated. It is demonstrated that the growth condition such as the areal density, pretreatment of the substrates and growth temperature have great influence on the morphology and the alignment of the nanorods arrays. The density of Bi2O3 doped ZnO nanostructures is controlled by the gold (Au) nanoparticle density deposited on the silicon substrates. Relatively homogenous size and shape were observed by introducing gold(Au) seed-layer as nucleation centers on the substrates prior to the VLS reaction. The samples were characterized by X-ray diffraction, scanning electron microscopy.

• Journal of Industrial Technology
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• v.17
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• pp.233-239
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• 1997

The effects of preheating the gas stream on deposition characteristics of ultrafine $SiO_2$ particles were investigated theoretically. The model equations such as mass and energy balance equations and aerosol dynamic equations were solved to predict the particle growth and deposition. The gas temperatures, $SiCl_4$ concentrations, $SiO_2$ particle volumes, $SiO_2$ particle sizes and deposition efficiencies of $SiO_2$ particles were calculated for various preheating temperatures. As the preheater setting temperature increases, the $SiO_2$ particle size distribution becomes more uniform, because the effect of $SiCl_4$ diffusion decreases.

• Electrical & Electronic Materials
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• v.16 no.9
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• pp.62.1-62
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• 2003

Silicon oxide with thickness lee than 9 nm is fabricated by tube furnace oxidation. Nitrogen is added to dilute the oxidation rate. Aluminum dots with radius of 0.05 cm are deposited on the oixde. High frequency capacitance-voltage(HF C-V), conductance-voltage(G-V) and current-voltage(I-V) characteristics are measured. Annealing under nitrogen atmosphere is carried out with different time and at different temperature. Densities of the interface states before and after annealing are compared. After annealing, a decrease in density of the interface states is found. Experiments show that 45$0^{\circ}C$ annealing for 30 minutes has the lowest density of the interface states.