• Proceedings of the KSRS Conference
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• 2003.11a
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• pp.615-617
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• 2003

Carbon monoxide (CO) is one of the important trace gases because its concentration in the troposphere directly influences the concentrations of tropospheric hydroxyl (OH), which controls the lifetimes of tropospheric trace gases. CO traces the transport of global and regional pollutants from industrial activities and large scale biomass burning. The distributions of CO were analyzed using the MOPITT data for East Asia, which were compared with the ozone distributions. In general, seasonal CO variations are characterized by a peak in the spring, which decrease in the summer. The monthly average for CO shows a similar profile to that for O$_3$. This fact clearly indicates that the high concentration of CO in the spring is possibly due to one of two causes: the photochemical production of CO in the troposphere, or the transport of the CO into East Asia. The seasonal cycles for CO and O$_3$ in East Asia are extensively influenced by the seasonal exchanges of different air mass types due to the Asian monsoon. The continental air masses contain high concentrations of O$_3$ and CO, due to the higher continental background concentrations, and sometimes to the contribution from regional pollution. In summer this transport pattern is reversed, where the Pacific marine air masses that prevail over Korea bring low concentrations of CO and O$_3$, which tend to give the apparent summer minimums.

• Journal of the Korean earth science society
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• v.21 no.3
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• pp.287-301
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• 2000

In order to investigate the factors and processes affecting the vertical distributions of ozone, we analyzed the ozone profile data measured using ozonesonde from 1995 to 1997 at Pohang city, Korea. In the course of our study, we analyzed temporal and spatial distribution characteristics of ozone at four different heights: surface (100m), troposphere (10km), lower stratosphere (20km), and middle stratosphere (30km). Despite its proximity to a local, but major, industrial complex known as Pohang Iron and Steel Co. (POSCO), the concentrations of surface ozone in the study area were comparable to those typically observed from rural and/or unpolluted area. In addition, the findings of relative enhancement of ozone at this height, especially between spring and summer may be accounted for by the prevalence of photochemical reactions during that period of year. The temporal distribution patterns for both 10 and 20km heights were quite compatible despite large differences in their altitudes with such consistency as spring maxima and summer minima. Explanations for these phenomena may be sought by the mixed effects of various processes including: ozone transport across two heights, photochemical reaction, the formation of inversion layer, and so on. However, the temporal distribution pattern for the middle stratosphere (30km) was rather comparable to that of the surface. We also evaluated total ozone concentration of the study area using Brewer spectrophotometer. The total ozone concentration data were compared with those derived by combining the data representing stratospheric layers via Umkehr method. The results of correlation analysis showed that total ozone is negatively correlated with cloud cover but not with such parameter as UV-B. Based on our study, we conclude that areal characteristics of Pohang which represents a typical coastal area may be quite important in explaining the distribution patterns of ozone not only from surface but also from upper atmosphere.

• Proceedings of the KSRS Conference
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• 2004.10a
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• pp.182-183
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• 2004

Atmospheric carbon monoxide (CO) and ozone $(O_3)$ play the important trace gases in tropospheric chemistry, through its concentration in the troposphere directly influences the concentrations of tropospheric hydroxyl (OH). Understanding the impact of CO and $O_3$ on the global tropospheric chemistry requires measurements of the global atmospheric CO and $O_3$ distributions. This study focuses on the identification of CO and O3 released in the East Asia between March 2000 and February 2004. During the period, the MOPITT instrument onboard the Earth Observing System (EOS)-Terra platform collected extensive measurement of CO. So we have used MOPITT data at 700hPa to analyze seasonal distribution of CO concentration. And the O3 measurements for this study were Total Ozone Mapping Spectrometer (TOMS) and Dobson spectrometer provided NASA/GSFC and Yonsei University, Korea. During springtime, the CO and O3 concentrations were increased over East Asia for April, May, and June. CO and O3 transport and chemistry in the springtime in East Asia are studied by use of the HYbrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model.

• Analytical Science and Technology
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• v.35 no.5
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• pp.212-217
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• 2022

In this study, ozone (O₃) samples were prepared for investigating the heterogeneous reactions between O₃ and tropospheric aerosols and were characterized by spectroscopic methods. O₃ generated from an ozone generator was purified by selective adsorption on refrigerated silica gel, followed by transfer to a sample bulb. The amount of UV light (λ = 256 nm) absorbed by O₃ was measured as a function of time at two different temperatures (room temperature and 50 ℃) and under different irradiation conditions. A correlation plot of 1/[O₃] versus time showed that O₃ decomposition follows the 2^nd order reaction rate under a steady-state approximation. The initial concentration of O₃, observed rate constants (k_obs), and the half-life of O₃ in the sample stored at room temperature were determined to be 2.74 [±0.14] × 10¹⁶ molecules·cm^-3, 4.47 [±0.64] × 10^-23 molecules^-1·cm³·s^-1, and 9.5 [±1.4] days, respectively. The evaluation of O₃ stability under various conditions indicated that special care should be taken to prevent the exposure of the O₃ samples to hightemperature environment and/or UV radiation. This study established a protocol for the preparation of highly purified O₃ samples and confirmed that the O₃ samples can be stored for a day after preparation for further experiments.

• Proceedings of the Korean Institute of Industrial Safety Conference
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• 2003.05a
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• pp.17-20
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• 2003

In a recent paper (Hartwig, ms.) I have shown that it is possible to understand and discuss the changing Austausch (i.e., exchange of air parcels between different atmospheric layers) between the stratosphere and troposphere by means of long-term measurement on series of spallation products. It is well known (Friend 1961; Muet et al. 1966, Hartwig et al. 1969) that there is a seasonal pattern in the 7Be concentration of ground-level air with a maximum during May-June. This maximum is caused by enhanced exchange processes between the atmospheric compartments of the stratosphere and troposphere during this interval. Generally, those exchange processes are a consequence of stability and dynamics of the atmospheric compartments, which themselves result from, among other factors, the distribution of the heat sources in those compartments, namely the ground and the ozone layer. Because of the growing importance of anthropogenic infrared-active gases in the atmosphere, it is to be expected that the relative importance of those original, naturally occurring heat sources will be of lesser significance, thus altering the Austausch. And indeed, it has been shown (Hartwig, ms.) by considering the ratio of the annual maximum and minimum during a 28-yr period of 7Be ground-level concentration at Braunschweig, Germany (10$^{\circ}$33'E, 52$^{\circ}$17'N) (Kolb 1992; Wershofen 1993), that there is a steady decline in that ratio, thus indicating alteration of atmospheric Austausch within the last three decades.(omitted)

• Korean Journal of Remote Sensing
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• v.15 no.3
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• pp.253-266
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• 1999

ADEOS(Advanced Earth Observing Satellite)/IMG(Interferometric Monitor for Greenhouse Gases) measurements - temperature, water vapor($H_2O$), ozone($O_3$) have been compared with the radio sonde and ozone sonde observations at Osan and Pohang stations for the 4 cases on 10 Jan.(a), 28 Jan.(b), 2 Apr.(c), and 19 Jun.(d) 1997 to detect the error ranges of the IMG data. It showed that the IMG data of the cases (b), (d) when the ADEOS passed over the central part of Korea were quite stable with the good agreement with the sonde observations, however, that of (a),(c) when the ADEOS passed over south- east coastal area were unstable with the larger differences from the sonde-observations. The RMSE and bias analyses of temperature for the stable cases (b),(d) showed that the differences between the IMG data and the sonde observations were about 1~4 K at the 700~300 hPa level and about 4~5 K or more at the higher level, and the IMG measurements tended to be larger than the sonde observations at the higher level above 200 hPa, while no typical bias was seen at the lower level. The RMSE and bias analysis for the version of level 2 5_6_4_4 of ozone showed that the RMSE of ozone were quite small, in general, except at the higher level above 50~60 hPa in the all 4 cases, however the bias was generally big with the positive value in the troposphere and the negative in the stratosphere. An example of vertical profile of trace gases such as $CO_2, N_2O, CH_4, HNO_3$, CO measured by IMG was also presented and it showed that the IMG data had large differences between the 5 different observation points.

• Journal of Wellbeing Management and Applied Psychology
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• v.6 no.1
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• pp.17-22
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• 2023

Purpose: VOCs (volatile organic compounds) are all the organic compounds that react with solar rays and increase the concentration of ozone in the troposphere and are partially also known as carcinogens. The adsorption using activated carbon is usually applied to remove VOCs. Research design, data and methodology: The 20 places of surface coating facilities were selected to evaluate the emission amount of VOCs in Seoul. In addition, the removal efficiency of VOCs in 25 places of automobile coating facilities was evaluated. Results: The average emission amount of VOCs was 10.903 kg/hr from automobile coating facilities, while 3.520 kg/hr from other surface coating facilities. The removal efficiency in adsorption with the combustion catalytic process has the mean value of 87.9% and the regeneration efficiency of activated carbon has the mean value of 95.0%. Conclusions: The removal efficiency in adsorption with the biofiltration process has the mean value of 89.8% and the regeneration efficiency of activated carbon has the mean value of 94.8%. The removal efficiency in the plasma catalyst process has the mean value of 79.3%.

• Journal of the Korean earth science society
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• v.21 no.6
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• pp.703-718
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• 2000

In order to investigate interannual variation of total ozone and reflectivity over the globe, Nimbus-7/TOMS data were used on the monthly mean and its anomaly for the period of 1979-92. This study also examined MSU channel 4(Ch4; lower-stratosphere) brightness temperature data and two model reanalyses of NCEP and GEOS to compare the ozone variation with atmospheric thermal condition. In addition, the MSU channel 1(Ch1 ; lower-troposphere) brightness temperature was used to compare with the reflectivity. The ozone showed strong annual cycle with downward trend(-6.3${\pm}$0.6 DU/decade) over the globe, and more distinct response to volcanic eruption than El Ni${\tilde{n}$o. The relationship between total ozone and MSU Ch4 observation, and between the ozone and model reanalyses of lower stratosphere temperature showed positive correlation(0.2-0.7) during the period of 1980-92. Reflectivity increased interannually by 0.2${\pm}$0.06%/decade over the globe during the above period and reflected El Ni${\tilde{n}$o(1982-83, 1991-92) well. Its variability in annual cycle was remarkably smaller in tropics than in higher latitudes. This is inferred due to cloud suppression and tropical upwelling regions. Reflectivity correlated negatively(-0.9) to the Ch1 temperature over the globe, but positively(0.2) over tropical ocean. The positive value over the ocean results from the effect of microwave emissivity which increases the Ch1 temperature with enhanced hydrometeor activity. Significant correlations between total ozone and the Ch4 temperature, and between reflectivity and the Ch1 Suggest that the TOMS data may use valuably to better understand the feedback mechanism of climate change.

• Journal of the Korean earth science society
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• v.37 no.7
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• pp.465-475
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• 2016

The diurnal and semidiurnal tides in the global atmosphere are examined using 3-hourly geopotential height field of the state-of-the-art reanalysis data. Unlike the previous studies, the spatial structure and seasonality of those tides are analyzed from the surface of the earth to the stratosphere. It is found that, at most levels, diurnal tide is strong in the midlatitudes while semidiurnal tide is predominant in the tropics. The former shows strong seasonal cycle with a larger amplitude in summer than in winter in both hemispheres. This is different from the semidiurnal tide which has essentially no seasonal cycle. In term of the vertical structure, while semidiurnal tide has a barotropic structure, diurnal tide exhibits a distinct vertical structure with increased amplitude and height. Especially tropical diurnal tide exhibits a nearly opposite phase from the surface to the free troposphere, and to the upper stratosphere. Its amplitude also varies nonlinearly with height, possibly influenced by water vapor, ozone, gravity waves and solar radiation.

• Journal of the Korean earth science society
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• v.21 no.2
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• pp.137-158
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• 2000

The correlation and Empirical Orthogonal Function (EOF) analyses over the globe have been applied to intercompare lower-stratospheric (${\sim}$70hPa) temperature obtained from satellite data and two model reanalyses. The data is the19 years (1980-98) Microwave Sounding Unit (MSU) channel 4 (Ch4) brightness temperature, and the reanalyses are GCM (NCEP, 1980-97; GEOS, 1981-94) outputs. In MSU monthly climatological anomaly, the temperature substantially decreases by ${\sim}$21k in winter over southern polar regions, and its annual cycle over tropics is weak. In October the temperature and total ozone over the area south of Australia remarkably increase together. High correlations (r${\ge}$0.95) between MSU and reanalyses occur in most global areas, but they are lower (r${\sim}$O.75) over the 20-3ON latitudes, northern America and southern Andes mountains. The first mode of MSU and reanalyses for monthly-mean Ch4 temperature shows annual cycle, and the lower-stratospheric warming due to volcanic eruptions. The analyses near the Korean peninsula show that lower-stratospheric temperature, out of phase with that for troposphere, increases in winter and decreases in summer. In the first mode for anomaly over the tropical Pacific, MSU and reanalyses indicate lower-stratospheric warming due to volcanic eruptions. In the second mode MSU and GEOS present Quasi-Biennial Oscillation (QBO) while NCEP, El Ni${\tilde{n}}$o. Volcanic eruption and QBO have more impact on lower-stratospheric thermal state than El Ni${\tilde{n}}$o. The EOF over the tropical Atlantic is similar to that over the Pacific, except a negligible effect of El Ni${\tilde{n}}$o. This study suggests that intercomparison of satellite data with model reanalyses may estimate relative accuracy of both data.