• Title/Summary/Keyword: Trap concentration

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Removal of OH Spectral Interferences from Aqueous Solvents in Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) with Ar Cryogenic Desolvation

  • Cho, Young-Min;Pak, Yong-Nam
    • Bulletin of the Korean Chemical Society
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    • v.26 no.9
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    • pp.1415-1420
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    • 2005
  • The spectral interferences of OH from aqueous solvents in ICP-AES have been studied and eliminated using a cryogenic argon trap. The prominent lines of Bi I 306.772 nm, Al I 309.271 nm, and V II 310.230 nm, which are very seriously overlapped with the OH band, were examined. With an extended torch and high tangential flow of 20 L/min, water vapor from air entrainment was prevented. The combination of a condenser and argon cryogenic trap was able to eliminated most of water vapor carried by the argon sample gas. Removal of OH spectral interference could extend the linearity of the calibration curve 5-10 times on the lower concentration for ICP-AES. Interference Equivalent Concentration (IEC) has been reduced to 5.6, 5.9, and 12.4 times for Bi, Al and V, respectively.

Analysis of Reduction of NPS Pollution loads using the small sediment trap at field (소규모 침사구를 이용한 밭의 비점오염원 저감 효과 분석)

  • Shin, Min-Hwan;Lim, Kyoung-Jae;Jang, Jeong-Ryeol;Choi, Yong-Hun;Park, Woon-Ji;Won, Chul-Hee;Choi, Joong-Dae
    • Journal of The Korean Society of Agricultural Engineers
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    • v.54 no.2
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    • pp.27-35
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    • 2012
  • Various Best Management Practices (BMPs) have been suggested to reduce Nonpoint source pollutant loads from agricultural fields. However, very little research regarding water quality improvement with sediment trap has been performed in Korea. Thus, effects of sediment trap were investigated in this study. Three sediment traps were installed at the edge of six plots and flow and water quality of inflow and outflow were monitored and analyzed. It was found that approximately 64.1 % of flow reduction was observed. In addition, pollutant concentration of outflow was reduced by 39.0 % for $BOD_5$. For SS, $COD_{Mn}$, DOC, T-N, T-P, approximately 62.1 %, 43.4 %, 43.5 %, 40.0 %, and 41.2 % reduction were observed, respectively. Over 80 % and 90 % of pollutant loads were reduced from sediment trap #2 and #3 because of less outflow from plots covered with rice straw/straw mat. In case of intensive rainfall events occurred from July 26~29, 2011, over 60 % of pollutant and 88.9 % of sediment reduction were observed from sediment trap #3. As shown in this study, small sediment traps could play important roles in reducing pollutant loads from agricultural fields. If proper management practices, such as rice straw/straw mat, are used to protect surface from rainfall impacts and rill formation, much pollutant reduction could be expected.

Effects of Regeneration Parameters on Oxidation of Particulate in a Diesel Particulate Trap System (디젤 입자상물질 후처리 장치에서 입자상물질의 연소에 미치는 재생 인자의 영향)

  • Kim, J. U.;Cho, H.;Kim, H. U.;Park, D. S.;You, C.;Kim, E. S.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.6 no.2
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    • pp.168-177
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    • 1998
  • The effects of the regeneration parameters such as inlet gas temperature, space velocity, oxygen concentration of the exhaust gas, and initial particulate loading on the oxidation of the particulate inside ceramic cordierite filter have been investigated through an engine experiment. As the inlet gas temperature increases, the remarkable filter temperature occurs owing to the rapid combustion rate. Though the higher space velocity affirms the safe regeneration, it also requires much fuel consumption of the burner. For that reason, the space velocity should be compromised considering the fuel economy. The excessive accumulation of the particulate may cause undesirable regeneration temperatures inside filer even under the optimized regeneration condition. The inlet gas temperature should be selected to overcome the variation of the oxygen concentration which is inherent feature of the diesel engine. It is the most important factor in the regeneration control techniques.

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Research on Odor Analysis Technology to Secure the Reliability of Air Quality Improvement in Air Conditioners (에어컨디셔너 공기질 개선의 신뢰도 확보를 위한 냄새 분석 기술 연구)

  • Kang, Seok-Hyun;Huh, Pil-Ho;Ahn, Young-Chull
    • Journal of Environmental Science International
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    • v.30 no.1
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    • pp.45-55
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    • 2021
  • In this study, the odor of the parts and the odor of the surrounding environment were classified and verified. In order to increase the reliability of odor quantitative/qualitative analysis, the selection criteria for 5 sensory evaluators were established, and the n-Butanol control solution for each odor intensity was periodically trained to recognize the odor intensity before sensory evaluation. In addition, although various odor thresholds have been used through several studies, verification of whether the odor intensity value obtained through GC/MSD analysis is similar to the degree to which a person directly smells and feels it. It is important to select the odor threshold that has the best correlation with the odor intensity calculated by the person smelling the odor. Finally, sampling and measuring flowing airflow and temporary odors such as odor component analysis was experimentally difficult due to limited collection space and differences in concentration of generated components. In this study, a quantitative analysis was made possible by using the low temperature concentration (cooling) trap method. Through this, it was confirmed that the correlation with the actual odor intensity was not caused by the product itself, but by the environmental factor discharged from the product after creating the odor environment.

Some Toxic Heavy Metals Transferring Rates to Decoction of Five Most Generally Adopting Herbal Medicinal Prescriptions (다섯 가지 다용한약처방의 전탕 전후 유해 중금속 이행률 조사)

  • Kim, Kee Dong
    • Journal of Society of Preventive Korean Medicine
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    • v.19 no.3
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    • pp.103-113
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    • 2015
  • Objective : Five most generally adopting basic oriental prescriptions (yookmijihwangtang, ojeoksan, sipjeondaebotang, samultang, bojoongikgitang) samples were collected from 10 oriental hospitals nationwide and the transferring ratio to aqueous phase (TRAP) were calculated. Method : The samples are grounded evenly and the decocted at $120^{\circ}C$ for 12 min on hot plate and then filtered. The concentrations of As, Cd, Co, Cr and Pb in before and after decoction were measure by ICP/MS and the TRAPs were calculated. Results : The concentrations of As, Cr and Pb in the ground samples before decoction were all below criteria level, and TRAP values were also very low (<10%). For Cd, although some ground samples before decoction showed relatively high concentration level compare to the criteria level, because of their low TRAP (~3%), the actual concentrations in the decoction were quite low compare the criteria level. The Co's concentrations in the ground samples before decoction were all relatively low level. However, the TRAP of Co was astonishingly high value of around 40% average. Conclusion : The toxic heavy metal concentrations in the decoction were very low compare to the criteria level. The TRAPs are less than <10% except Co. The toxic heavy metals in the prescriptions are mainly remained in the residue and the only very small fraction may transferred to the decoctions. Therefore the toxicity of the oriental herbal medicine about the toxic heavy metal may be overstressed. The Co's TRAP turned out to be quite high value (40% average). Since the criteria level wes not established yet, the safety of decoctions according to Co was not fully confirmed.

Memory Characteristics of Al2O3/La2O3/SiO2 Multi-Layer Structures for Charge Trap Flash Devices (전하 포획 플래시 소자를 위한 Al2O3/La2O3/SiO2 다층 박막 구조의 메모리 특성)

  • Cha, Seung-Yong;Kim, Hyo-June;Choi, Doo-Jin
    • Korean Journal of Materials Research
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    • v.19 no.9
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    • pp.462-467
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    • 2009
  • The Charge Trap Flash (CTF) memory device is a replacement candidate for the NAND Flash device. In this study, Pt/$Al_2O_3/La_2O_3/SiO_2$/Si multilayer structures with lanthanum oxide charge trap layers were fabricated for nonvolatile memory device applications. Aluminum oxide films were used as blocking oxides for low power consumption in program/erase operations and reduced charge transports through blocking oxide layers. The thicknesses of $SiO_2$ were from 30 $\AA$ to 50 $\AA$. From the C-V measurement, the largest memory window of 1.3V was obtained in the 40 $\AA$ tunnel oxide specimen, and the 50 $\AA$ tunnel oxide specimen showed the smallest memory window. In the cycling test for reliability, the 30 $\AA$ tunnel oxide sample showed an abrupt memory window reduction due to a high electric field of 9$\sim$10MV/cm through the tunnel oxide while the other samples showed less than a 10% loss of memory window for $10^4$ cycles of program/erase operation. The I-V measurement data of the capacitor structures indicated leakage current values in the order of $10^{-4}A/cm^2$ at 1V. These values are small enough to be used in nonvolatile memory devices, and the sample with tunnel oxide formed at $850^{\circ}C$ showed superior memory characteristics compared to the sample with $750^{\circ}C$ tunnel oxide due to higher concentration of trap sites at the interface region originating from the rough interface.

An Experimental Study on the Control of the Combustion Rate by Temperature Control of Gas Entrained into the Filter in Burner-Type Particulate Trap (버너방식 DPF 시스템에서 가스온도 제어를 통한 입자상물질 연소율제어의 실험적 검증)

  • Park, D. S.;Kim, J. U.;Cho, H.;Kim, E. S.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.5 no.4
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    • pp.130-141
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    • 1997
  • Work on the reduction of particulate matter(PM) from a diesel vehicl has led to a new trp system and a control method to control the combustion rate of the PM filtrated in the trap, which was named as 'Active Exhaust Feeding Regeneration(AEFR) System' by its operation mechanism. Ceramic cordierite filter is a major component of the trap and susceptible to thermal shock. Therefore the system should be designed to reduce the peak temperature and temperature gradients in the trap ; these have been considered to be the main factors causing thermal shock of the filter during the regeneration. It uses the engine's exhaust gas partially for the regeneration of the ceramic filter. It controlled bypass flow rate of the engine's exhaust gas precisely to control the temperature of the gas entrained into the filter. Gas temperatures were measured inside filter, and the oxygen concentration at the outlet of the filter was also monitored during the regeneration to analyze the combustion process of the PM. The temperature distributions and temperature gradients in the filter during the regeneration varied widely according to the regeneration control schemes. Finally, this system shows relatively low peak temperature and temperature gradients in the filter during its regeneration. It is considered that this system uses a mew method to control the combustion rate of the PM, which is different from the methods used in the previous studies.

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Inhibitory Effects of Ursolic Acid from Prunella Vulgaris on Osteoclast Differentiation (하고초(夏枯草)에서 추출한 Ursolic acid의 파골세포 분화 억제 효과)

  • Heo, Ja-Kyung;Hwang, Deok-Sang;Lee, Jin-Moo;Lee, Chang-Hoon;Jang, Jun-Bock;Lee, Kyung-Sub
    • The Journal of Korean Obstetrics and Gynecology
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    • v.27 no.2
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    • pp.59-70
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    • 2014
  • Purpose: This study was conducted to evaluate the inhibitory effect of ursolic acid from Prunella vulgaris on osteoclast differentiation. Methods: MTT-assay was performed to estimate cytotoxicity of ursolic acid from Prunella vulgaris in BMMs stimulated with M-CSF. TRAP staining, TRAP activity and Real-time PCR were performed to know the inhibitory effect on osteoclast differentiation. Actin ring formation were analysed to observe the effect of ursolic acid from Prunella vulgaris. Results: Ursolic acid from Prunella vulgaris has no cytotoxicity at the concentration of $1{\mu}g/ml$ or lower. Ursolic acid decreased the number of TRAP positive cells and the expression of NFATc1 gene, c-Fos gene, TRAP and OSCAR in BMMs stimulated with RANKL. Ursolic acid restrained the formation of actin ring. Ursolic acid inhibited NF-${\kappa}B$ activity by inducing degradation of p-$IkB{\alpha}$. Conclusions: Ursolic acid from Prunella vulgaris has the inhibitory effect of osteoclast differentiation and bone resorption. Futher studies are needed to treat osteoporosis by usolic acid from Prunella vulgaris.

A Study on Inhibitory Mechanism of Melia Fructus Extract on Osteoclast Differentiation (천연자(川楝子)의 파골세포 분화 억제기전 연구)

  • Yun, Young-Jin;Lee, Jin-Moo;Lee, Chang-Hoon;Jang, Jun-Bock;Lee, Kyung-Sub
    • The Journal of Korean Obstetrics and Gynecology
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    • v.25 no.2
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    • pp.1-11
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    • 2012
  • Objectives: This study was conducted to evaluate the inhibitory effect of Melia Fructus extract on osteoclast differentiation. Methods: MTT-assay was performed to estimate cytotoxicity of Melia Fructus extract in BMMs stimulated with M-CSF. TRAP staining, TRAP activity and Real-time PCR were performed to know the inhibitory effect on osteoclast differentiation. Actin ring formation were analysed to observe the effect of Melia Fructus extract. Results: Melia Fructus extract decreased the number of TRAP positive cells and the expression of NFATc1 gene, c-Fos gene, TRAP and OSCAR in BMMs stimulated with RANKL. Melia Fructus extract has no cytotoxicity at the concentration used in this study. Melia Fructus extract restrained the formation of actin ring. Melia Fructus inhibited NF-${\kappa}B$ activity by inducing degradation of p-$IkB{\alpha}$. Conclusions: Melia Fructus has the inhibitory effect of osteocalst differentiation and bone resorption. Further studies are needed to treat osteoporosis by herbal medicine containing Melia Fructus.

The Preclinical Study of Hyeolbuchugeo-tang (Xuefuzhuyu-tang) on Bone Healing in Rats with Rib Fracture (골절 유발 Rat에 대한 혈부축어탕(血府逐瘀湯)의 전임상 연구)

  • Huh, Gun;Oh, Min-Seok
    • Journal of Korean Medicine Rehabilitation
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    • v.30 no.3
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    • pp.23-44
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    • 2020
  • Objectives The purpose of this study is to evaluate the healing effect of Hyeolbuchugeo-tang (HC) in rats with rib fracture. Methods Rats were randomly divided into 5 groups (naive, control, positive control, HC-L and HC-H). All groups except naive group were subjected to bone fracture of rib. Naive group received no treatment at all. Control group was fed with phosphate buffered saline. Positive control group was orally medicated with tramadol. Experimental group was orally medicated with HC extract (50 mg/kg for low concentration [HC-L], 100 mg/kg for high concentration [HC-H]). X-ray and micro-computed tomography (micro-CT) were conducted to assess the effect of HC. We analysed the level of 2) transforming growth factor-β1 (TGF-β1), Ki67, alkaline phosphatase (ALP), receptor activator of nuclear factor kappa-β, runt-related transcription factor 2 (Runx2) and tartrate resistant acid phosphatase (TRAP) on 7 and 14 days after fracture. ALP, alanine aminotransferase, aspartate aminotransferase, blood urea nitrogen, creatinine was measured for safety assessment. Results X-ray and micro-CT, showed HC enhance bone repair process. Callus formation was increased in experimental group at 7 days after fracture, but decreased at 14 days after fracture. 7 days after fracture, the level of TGF-β1 in experimental group was decreased. The level of Ki67, Runx2 in HC-H, TRAP in HC-L was increased. 14 days after fracture, the level of Ki67 in HC-L and HC-H was decreased. The level of ALP, Runx2, BUN in HC-L, TRAP in HC-L and HC-H was increased. Conclusions Taken together the results, HC promoted healing of bone fracture. In conclusion, HC has a potential to promote healing of bone fracture.