• Korean Journal of Materials Research
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• v.29 no.8
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• pp.469-476
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• 2019

A lead-free bulk ceramic having a chemical formula $Ba_{0.8}Ca_{0.2}(Ti_{0.8}Zr_{0.1}Ce_{0.1})O_3$ (further termed as BCTZCO) is synthesized using mixed oxide route. The structural, dielectric, impedance, and conductivity properties, as well as the modulus of the synthesized sample are discussed in the present work. Analysis of X-ray diffraction data obtained at room temperature reveals the existence of some impurity phases. The natural surface morphology shows close packing of grains with few voids. Attempts have been made to study the (a) effect of microstructures containing grains, grain boundaries, and electrodes on impedance and capacitive characteristics, (b) relationship between properties and crystal structure, and (c) nature of the relaxation mechanism of the prepared samples. The relationship between the structure and physical properties is established. The frequency and temperature dependence of the dielectric properties reveal that this complex system has a high dielectric constant and low tangent loss. An analysis of impedance and related parameters illuminates the contributions of grains. The activation energy is determined for only the high temperature region in the temperature dependent AC conductivity graph. Deviation from the Debye behavior is seen in the Nyquist plot at different temperatures. The relaxation mechanism and the electrical transport properties in the sample are investigated with the help of various spectroscopic (i.e., dielectric, modulus, and impedance) techniques. This lead free sample will serve as a base for device engineering.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.4
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• pp.632-638
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• 2019

This paper presents the conceptual design and reaction force analysis of a bogie structure for an inter-modal automated transportation system, including road and rail transportation. The proposed system was based on a train with rotation-aligning bogie mechanism that can save significant time and cost. One of the critical issues in conceptual design is the lateral forces applied to the rail caused by the characteristic shapes and structure of the rails and bogie. In particular, the lateral forces are significant in the transition section between the driving and platform sections. This paper provides design guidance for the transition section through reaction force analysis. Based on the analysis result, it was confirmed that the proposed concept can be a valid design candidate of a practical system, and the radius of the rail and the distance between rails are major factors for reaction force generation.

• Preventive Nutrition and Food Science
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• v.7 no.3
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• pp.282-286
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• 2002

Anemia is prevalent among pregnant women in Korea, and Fe deficiency anemia is a major nutritional problem throughout the world. Because studies of Cu, Mn, and Cr levels excluding Fe are rare, we were interested in changes in the nutritional status of these trace minerals and their relationship to hematogenesis. Accordingly, we determined the changes in plasma Fe, Cu, Mn, and Cr concentrations of maternal and umbilical cord blood during pregnancy, and evaluated the relationships between them at different time points during pregnancy. A total of 81 women participated in the study: 26 subjects in the first trimester, 23 in the second, and 32 in the third trimester. Plasma Fe levels were lower significantly (p<0.05) in the third trimester. Plasma Cu level ($\mu\textrm{g}$/dL) in each trimester were 86.6$\pm$13.8, 111.6$\pm$27.9, and 114.0$\pm$29.7, respectively; with significant increases (p<0.()5) in the second and third trimester. Plasma Mn concentrations (pg/dL) in each trimester were 212.6$\pm$89.0, 234.0$\pm$140.0, and 240.3$\pm$166.0, respectively and tended to increase, though not significantly, as the pregnancies progressed. The plasma concentrations of Cr (pg/dL) in each trimester were 3.7$\pm$2.0, 3.1$\pm$1.0, and 2.4$\pm$1.2, respectively; and was significantly lower (p<0.05) in the third trimester. In umbilical cord blood, the plasma level of Fe was 194.8$\pm$74.6 $\mu\textrm{g}$/dL, Cu was 57.5$\pm$10.9 $\mu\textrm{g}$/dL, Mn was 482.4$\pm$111.1 pg/dL, and Cr was 9.3$\pm$2.8 pg/dL. Plasma concentrations of Fe, Cu, Mn, and Cr of cord blood were 300 %, 50 %, 200 %, and 370% as compared to those of maternal blood in the third trimester. These results suggest that an active transport mechanism for the transport of Fe, Mn, and Cr from mother to fetus may exist, whereas, for Cu, the placenta appears to have a blocking effect on the transport from mother to baby.

• Proceedings of the KSEEG Conference
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• 2002.06a
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• pp.81-100
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• 2002

While most of regulatory communities in abroad recognize ' 'natural attenuation " to include degradation, dispersion, dilution, sorption (including precipitation and transformation), and volatilization as governing Processes, regulators prefer "degradation" because this mechanism destroys the contaminant of concern. Unfortunately, true degradation only applies to organic contaminants and short- lived radionuclides, and leaves most metals and long-lived radionuclides. The natural attenuation Processes may reduce the potential risk Posed by site contaminants in three ways: (i)contaminants could be converted to a less toxic form througy destructive processes such as biodegradation or abiotic transformations; (ii) potential exposure levels may be reduced by lowering concentrations (dilution and dispersion); and (iii) contaminant mobility and bioavailability may be reduced by sorption to geomedia. In this review, authors will focus will focul on "sorption" among the natural attenuation processes of hazardous inorganic contaminants including radionuclides. Note though that sorption and transformation processes of inorganic contaminants in the natural setting could be influenced by biotic activities but our discussion would limit only to geochemical reactions involved in the natural attenuation. All of the geochemical reactions have been studied in-depth by numerous researchers for many years to understand "retardation" process of contaminants in the geomedia. The most common approach for estimating retardation is the determination of distrubution coefficiendts ($K_{d}$) of contaminants using parametric or mechanistic models. As typocally used in fate and contaminant transport calculations such as predictive models of the natural attenuation, the $K_{d}$ is defined as the ratio of the contaminant concentration in the surrounding aqueous solution when the system is at equilibrium. Unfortunately, generic or default $K_{d}$ values can result in significant error when used to predict contaminant migration rate and to select a site remediation alternative. Thus, to input the best $K_{d}$ value in the contaminant transport model, it is essential that important geochemical processes affecting the transport should be identified and understood. Precipitation/dissolution and adsorption/desorption are considered the most important geochemical processes affecting the interaction of inorganic and radionuclide contaminants with geomedia at the near and far field, respectively. Most of contaminants to be discussed in this presentation are relatively immobile, i.e., have very high $K_{d}$ values under natural geochemical environments. Unfortunately, the obvious containment in a source area may not be good enough to qualify as monitored natural attenuation site unless owner demonstrate the efficacy if institutional controls that were put in place to protect potential receptors. In this view, natural attenuation as a remedial alternative for some of sites contaminated by hazardous-inorganic components is regulatory and public acceptance issues rather than scientific issue.

• Journal of Soil and Groundwater Environment
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• v.12 no.6
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• pp.29-37
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• 2007

Shallow alluvial groundwaters in Korea of tell exceed the Korean Drinking Water Standard for dissolved iron (0.3 mg/L), which is one of the important water quality problems, especially in the use of bank infiltration technique. Using the reactive transport modeling, in this study we simulated the effectiveness of injection-and-pumping technique to remove dissolved iron in groundwater. The results of simulation showed that pumping of groundwater after injection of oxygenated water into aquifers is very effective to acquire the permissible water quality level. Groundwater withdrawal up to several times of irjected water in volume can be applicable to yield drinkable water. Potential problems such as clogging and permeability lowering due to in-situ precipitation of iron hydroxides may be insignificant. We also discuss on the mechanism and spatial extent of iron removal in aquifer.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.6
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• pp.2604-2611
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• 2013

The Personal Rapid Transit(PRT) system has been highly interested in future transportation developments due to its on-demand and optimized door-to-door transport capability. However, the major impediments to the commercialization of PRT are the high cost for construction of infrastructures as opposed to the small transport capacity and difficulty in defining the role of PRT in building a balanced transportation system. In this study, the vertical transfer device for the PRT vehicle is developed to provide more flexible and better compatible urban mobility services between means of transportation, which is expected to meet particular demands in a particular environment. This apparatus was initially designed based on the basis of vertical circulating conveyors with steel chains, which is frequently used in logistics. Its advantages are capable of the non-stop loading and reduced head-way time. Most importantly, it was intensified by the additional idea to ensure the stable and reliable transfer of the PRT vehicle fully loaded with passengers. The 1/10-scale prototype was successfully tested to demonstrate a fundamental mechanism of vertical transfer and identify unexpected user requirements prior to a real manufacturing process.

• Journal of the Korean Institute of Gas
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• v.8 no.3 s.24
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• pp.43-51
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• 2004

In this study, gas permeation and separation characteristics of $CO_2$ and $N_2$ on nano-porous TPABr(Tetrapropylammoniumbromide) templating silica/alumina composite membrane were studied by using GMS (Generalized Maxwell Stefan) model. Since the transport mechanisms of meso-porous alumina support are Knudsen diffusion and viscous diffusion(or poiseulle flow), they can be identified by DGM (dusty gas model). The transport mechanism of TPABr templating silica layer, which would contribute mainly to the separation of $N_2/CO_2$ mixture, showed surface diffusion rather than pore diffusion. Therefore, the oermeationjseparation mechanisms in multi-component suface diffusion were successfully analyzed by the GMS model. In the separation of $N_2/CO_2$ mixture using the composite membrane, $CO_2$, the strongadsorbate, was permeated through the membrane more than Na due to the pore-blocking phenomena of $CO_2$ by adsorption isotherm and solace diffusion.

• The Korean Journal of Physiology
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• v.30 no.1
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• pp.63-76
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• 1996

The aim of present study was to characterize phosphate uptake and to investigate the mechanism for the insulin and insulin-like growth factor(IGF) stimulation of phosphate uptake in primary cultured rabbit renal proximal tubule cells. Results were as follows : 1. The primary cultured proximal tubule cells had accumulated $6.68{\pm}0.70$ nmole phosphate/mg protein in the presence of 140 mM NaCl and $2.07{\pm}0.17$ nmole phosphate/mg protein in the presence of 140 mM KCl during a 60 minute uptake period. Raising the concentration of extracellular phosphate to 100 mM$(48.33{\pm}1.76\;pmole/mg\;protein/min)$ induced decrease in phosphate uptake compared with that in control cells maintained in 1 mM phosphate$(190.66{\pm}13.01\;pmole/mg\;protein/min)$. Optimal phosphate uptake was observed at pH 6.5 in the presence of 140 mM NaCl. Phosphate uptake at pH 7.2 and pH 7.9 decreased to $83.06{\pm}5.75%\;and\;74.61{\pm}3.29%$ of that of pH 6.5, respectively. 2. Phosphate uptake was inhibited by iodoacetic acid(IAA) or valinomycin treatment $(62.41{\pm}4.40%\;and\;12.80{\pm}1.64%\;of\;that\;of\;control,\;respectively)$. When IAA and valinomycin were added together, phosphate uptake was inhibited to $8.04{\pm}0.61%$ of that of control. Phosphate uptake by the primary proximal tubule cells was significantly reduced by ouabain treatment$(80.27{\pm}6.96%\;of\;that\;of\;control)$. Inhibition of protein and/or RNA synthesis by either cycloheximide or actinomycin D markedly attenuated phosphate uptake. 3. Extracellular CAMP and phorbol 12-myristate 13 acetate(PMA) decreased phosphate uptake in a dose-dependent manner in all experimental conditions. Treatment of cells with pertussis toxin or cholera toxin inhibited phosphate uptake. cAMP concentration between $10^{-6}\;M\;and\;10^{-4}\;M$ significantly inhibited phosphate uptake. Phosphate uptake was blocked to about 25% of that of control at 100 ng/ml PMA. 3-Isobutyl-1-methyl-xanthine(IBMX) inhibited phosphate uptake. However, in the presence of IBMX, the inhibitory effect of exogenous cAMP was not significantly potentiated. Forskolin decreased phosphate transport. Acetylsalicylic acid did not inhibit phosphate uptake. The 1,2-dioctanoyl-sn-glycorol(DAG) and 1-oleoyl-2-acetyl-sn- glycerol(OAG) showed a inhibitory effect. However, staurosporine had no effect on phosphate uptake. When PMA and staurosporine were treated together, inhibition of phosphate uptake was not observed. In conclusion, phosphate uptake is stimulated by high sodium and low phosphate and pH 6.5 in the culture medium. Membrane potential and intracellular energy levels are also an important factor fer phosphate transport. Insulin and IGF-I stimulate phosphate uptake through a mechanisms that involve do novo protein and/or RNA synthesis and decrease of intracellular cAMP level. Also protein kinase C(PKC) is may play a regulatory role in transducing the insulin and IGF-I signal for phosphate transport in primary cultured proximal tubule cells.

• Journal of Environmental Science International
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• v.2 no.2
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• pp.153-160
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• 1993

The problem of supply and transport of sediment from a mountainous catchment is very important in explaining dynamic geomorphology and the hydrological cycle. The discharge of suspended sediment is determined by a morphological system. Human interference to environment Is also an important, not negligible factor in sediment production. Moreover, growing concern in recent years for the problems of nonpoint pollution and for the transport of contaminants through terrestrial and aquatic ecosystems has highlighted the role of sediment-associated transport in fluvial systems. This study was conducted in forested and quarried catchments in order to clarify the different discharge process and the mechanism of suspended sediment dynamics for each catchment. As a forested catchment, the Yamaguchi River catchment which drains a $3.12km^2$ area was chosen. On the other hand, the Futagami River basin which is formed by three subbasins (1.07, 1.59 and $1.78km^2$), as a quarried catchment was selected. These catchments are situated to the north and east of Mt. Tsukuba, Ibaraki, Japan. The discharge pattern of suspended sediment from the Futagami River basin is more unstable and irregular than that from forested catchment, the Yamaguchi River catchment. Under the similar rainstorm conditions, suspended sediment concentration from quarried catchment during a rainstorm event increases from 43 to 27,340 mg/l. However, in the case of the forested catchment it changes only from nearly zero to 274 mg/l. Generally, the supply source of suspended sediment is classified into two areas, the in-channel and non-channel source areas. As a result of field measurements, in the case of the forested catchment the in-channel (channel bed, channel bank and channel margin) is the main source area of suspended sediment. On the other hand, remarkable sediment source area on the Quarried catchment is the non-channel that is unvegetated ground.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.2983-2988
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• 2007

In the present study, the numerical investigation on the effects of water-mist characteristics has been carried out for the fire suppression mechanism. The FDS are used to simulate the interaction of fire plume and water mists, and program describes the fire-driven flows using LES turbulence model, the mixture fraction combustion model, the finite volume method of radiation transport for a non-scattering gray gas, and conjugate heat transfer between wall and gas flow. The numerical model is consisted of a rectangular enclosure of $L{\times}W{\times}H=1.5{\times}1.5{\times}2.0m$ and a water mist nozzle that be installed 1.8m from fire pool. In the study, the parameters of nozzle for simulation are the droplet size and the spray velocity. Finally, the droplet size influences to fire flume on fire suppression than spray velocity because of the effect of terminal velocity, and the optimal condition for fire suppression is that the droplet size and the spray velocity are $100{\mu}m$ and 20m/s, respectively.