• Membrane and Water Treatment
• /
• v.1 no.4
• /
• pp.297-316
• /
• 2010

Membrane fouling is one of the major operational concerns of membrane processes which results in loss of productivity. This paper investigates the ultrafiltration (UF) results of synthetic oil-in-water (o/w) emulsion using flat sheets of polysulfone (PSf) membrane synthesized with four different compositions. The aim is to identify the mechanisms responsible for the observed permeate flux reduction with time for different PSf membranes. The experiments were carried out at four transmembrane pressures i.e., 68.9 kPa, 103.4 kPa, 137.9 kPa and 172.4 kPa. Three initial oil concentrations i.e., 75 $mgL^{-1}$, 100 $mgL^{-1}$ and 200 $mgL^{-1}$ were considered. The resistance-in-series (RIS) model was applied to interpret the data and on that basis, the individual resistances were evaluated. The significances of these resistances were studied in relation to parameters, namely, transmembrane pressure and initial oil concentration. The total resistance to permeate flow is found to increase with increase in both transmembrane pressure and initial oil concentration while for higher oil concentration, resistance due to concentration polarization is found to be the prevailing resistance. The applicability of the constant pressure filtration models to the experimental data was also tested to explain the blocking process. The study shows that intermediate pore blocking is the dominant mechanism at the initial period of UF while in the later period, the fouling process is found to approach cake filtration like mechanism. However, the duration of pore blocking mechanism is different for different membranes depending on their morphological and permeation properties.

• Journal of Korean Society of Environmental Engineers
• /
• v.22 no.7
• /
• pp.1183-1191
• /
• 2000

Operating conditions for reduction of membrane fouling in treatment of dissolved organic matter by UF membrane process were investigated by pilot-scale plant using various operating conditions. As inlet pressure increased, increament of transmembrane pressure and flux decline were faster. The reason was due to the increase in adsorption of dissolved organic matter and the development of cake layer compression on the membrane surface. When efficient pressure (the difference of pressure between backwash and transmembrane pressures) was high, small amount of pollutant was retained on the membrane surface. When backwash was frequently conducted, low concentration of pollutant was maintained in recycling water. Therefore, backwash could be efficiently conducted with high efficient pressure and high frequency. Fouling rate was correlated with backwash and inlet pressures, recovery rate and cumulative permeated volume. Among the operating parameters backwash pressure was most closely related to fouling rate and inlet pressure was next to backwash pressure. It seems that the fouling was strongly related to pressure which leads to the cake layer compression and adsorption of dissolved organic matter.

• KSBB Journal
• /
• v.11 no.3
• /
• pp.347-352
• /
• 1996

The enzyme deactivation in a membrane recycling system for the simultaneous saccharification and fermentation(SSF) was studied under various temperature and pressure. The optimum molecular weight cut off(MWCO) of the ultrafiltration membrane for recycling cellulase and ${\beta}$-glucosidase was 50,000. When the cellulase was recycled continuously through the membrane system, it was not deactivated. But the activity of ${\beta}$-glucosidase was decreased with an increase in operating temperature and transmembrane pressure. After 720 minutes at $42^{\circ}C$ and 24.8 psig , the activity of ${\beta}$-glucosidase was reduced by 35% of the initial activity. Such tendencies could be well explained by the results of highly induced shear at the fiber surface of membrane when temperature and transmembrane pressure became higher.

• KSBB Journal
• /
• v.5 no.1
• /
• pp.69-74
• /
• 1990

Dynamic characteristics of separation in membrane filtration system of tangential flow was investigated to find the functional relationship among the filtrate flux, transmembrane pressure, inulin concentration and recirculation rate. In case that NMWL is 1000, tracts-membrane pressure $0.4kgf/\;{\textrm{cm}^2}$ to $3.2kgf/\;{\textrm{cm}^2}$, inulin concentration lwt% to 5wt%, and recirculation rate 4ml / sec, mathematical model for the function among filtrate flux, transmembrane pressure, and inulin concentration was deduced and expressed as follows.Jv = (0.0022p + 0.0003) ln \frac{3p\;+\;2.1}{C_b}$ The values calculated by the above equation and those measured were compared to find to be nicely in accord with each other. Especially the agreement was enhanced in the region of higher concentration of inulin.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.11 no.4
• /
• pp.1391-1398
• /
• 2010

Reuse feasibility of MBR effluent of S Electronic Company's organic wastewater as a LCD process water was investigated by a $32m^3/d$ pilot-scale RO membrane process. The effects of operating pressure and permeate flux at constant 85% recovery of RO membrane process using MBR effluent were analyzed for transmembrane pressure and period for CIP by membrane fouling as well as rejection of TOC and conductivity. MBR effluent requires additional treatment to meet the LCD process water quality criteria of TOC<1 mg/L and conductivity<$100{\mu}S/cm$ which is stringent as compared with those of conventional reuse water quality criteria. The RO process operated at 85% recovery with stepwise increasing of permeate fluxes from 12.5 LMH to 22.0 LMH was able to meet LCD process water quality criteria. However, the transmembrane pressure increased and the period of CIP decreased as increasing permeability fluxes due to fouling of RO membrane. The optimum operational conditions of RO membrane process were permeate fluxes of 16.5~18.5 LMH with operating pressure of $6.7{\sim}12.4kgf/cm^2$ and CIP period of 20~25 days at constant 85% recovery.

• Clean Technology
• /
• v.5 no.2
• /
• pp.69-78
• /
• 1999

Separation characteristics of cutting oil-in-water emulsions were studied experimentally by using various kinds of flat-type microfiltration and ultrafiltration membranes. For ultrafiltration membranes the permeation behavior of cutting oil emulsions obeys the film model, whereas a significant deviation from the model was observed for ASYPOR microfiltration membranes. The experimental data obtained for all the membranes showed that the effect of operating pressure on the permeation flux of oil-in-water emulsions is not very significant. At low transmembrane pressures the permeation flux decreased gradually with increasing filtration time, whereas the permeation flux at high transmembrane pressures decreased steeply for early filtration time. However, every flux eventually reached a constant value that depends only on the applied transmembrane pressure. For the hydrophobic polycarbonate microfiltration membrane the permeation flux increased with the filtration time. The critical permeation pressures were also determined from the data obtained from unstirred cell experiments.

• Proceedings of the Membrane Society of Korea Conference
• /
• 2000.04a
• /
• pp.51-54
• /
• 2000

• Proceedings of the Membrane Society of Korea Conference
• /
• 2000.04a
• /
• pp.63-66
• /
• 2000

• The Korean Journal of Physiology
• /
• v.2 no.1
• /
• pp.47-52
• /
• 1968

Twenty white rabbits anesthetized with nembutal (30 mg/kg) were employed in this experiment. Five of them served as controls; the remaining rabbits as experimental group were subjected to irreversible hemorrhagic shock. Shock was induced by bleeding the animals until mean blood pressure decreased to a level of 50-40 mmHg. This level of pressure was maintained for 3-4 hours, after which the drawn blood was reinfused. The reinfusion of blood caused the elevation of arterial pressure almost the control level for some minutes, after which a gradual and progressive decline of blood pressure became evident. This decline was thought to be the result from irreversible hemorrhagic shock. When mean blood pressure declined to less than 50 mmHg, chest was opened and samples of arterial blood and left ventricular muscle were taken. Left ventricular muscle and blood plasma were analyzed for potassium, sodium, chloride and water content. Blood glucose concentration was determined by Somogyi-Nelson's method. Extracellular and intracellular myocardial water and electrolyte content were calculated on the basis that electrolytes are distributed between plasma water and interstitial water according to Gibbs-Donnan equilibrium. In this calculation extracellular water was substituted for Na space. The findings obtained were as follows: 1. The concentration of blood glucose was 87mg% in the controls and it rose to 222 mg% in shock (P<0.01). 2. Plasma potassium elevated significantly from 3.3 mEq/l in controls to 8.0 mEq/l in shock (P<0.01), while small decreases in sodium (151-146 mEq/l) and chloride (102-96 mEq/l) were observed (P<0.3, P<0.1), 3. The changes of blood water content (83.1-84.3%) and cardiac water content (77.5-78.3 gm/100gm WT) were observed. 4. In control animals myocardial potassium levels which averaged 30.2 mEq/100 gmDT rose significantly to 40.3 mEq/100 gmDT in shock (P<0.01), while moderate decreases in sodium(16.3-14.3 mEq/100 gmDT) were observed in shock. 5. The calculated transmembrane resting potential of left ventricular muscle of control animals averaged 95 mV, while rabbits in shock averaged 77 mV. (P <0.01). The findings of this experiment do not correspond with the conclusions that myocardial depression seems to be the cause of irreversible hemorrhagic shock, because the excitability of heart muscle is elevated. From the point of view that the lowered transmembrane resting potential, the cause of death in terminal stage of irreversible hemorrhagic shock may be ventricular fibrillation. It can't be said, however, that the lowered transmembrane resting potential is responsible for the transition from reversible to irreversible hemorrhagic shock. The marked increase in blood glucose suggested that glycogenolysis in the liver is favorably active in shock.

• Journal of Korean Society of Water and Wastewater
• /
• v.22 no.5
• /
• pp.517-522
• /
• 2008

This study aims at an assessment of the effectiveness of taste & odor removal and transmembrane pressure changes in a pilot membrane plant(500m3/day) by adding PAC to MF process, and at providing a basis for applying it to the advanced water treatment process. The transmembrane pressure showed, in low turbidity of raw water, a tendency to decrease when PAC was injected at the Flux of 1, $1.5m^3/m^2{\cdot}d$, while it increased in high Flux($1.5m^3/m^2{\cdot}d$) in high turbidity of raw water. in addtion, it is shown that the fouling could be reduced more when PAC is injected together with appropriate amount of coagulant, than when PAC is solely injected. Taste & Odor-causing 2-MIB may not be detected in membrane filtered water, if the amount of PAC injection is increased in accordance with the increasing concentration of 2-MIB. Hence, PAC injection, as a pre-treatment process in MF membrane filtering, is supposed to be a suitable process for reducing fouling as well as for improvement effectiveness of taste & odor treatment.