• Title/Summary/Keyword: Transition curve

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계면활성제/1-Hoxanol/물 혼합물의 상태도와 전기 전도도에 관한 연구

  • 오성근;김종득
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.12 no.1
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    • pp.34-61
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    • 1986
  • The microstructural transitions of aqueous micellar solutions of cetyltrime-thylammonium bromide and sodiumdodecyl sulfate by adding 1-hexanol were investigated, measuring the concentrations of equilibrated phases and the electrical conductivities at the low concentrations of surfactants, where the solobilities of 1-hexanol varied significantly, at 3$0^{\circ}C$ and 45$^{\circ}C$. Ternary phase diagrams of multiphase regions, constructed by liquid chromatography analysis and by counting the number of phase of samples, consisted of one three-phase region and three two-phase regions. One of the two-phase regions was found to equilibrate an aqueous micellar solution and a liquid crystal, and had a critical point between them. Near this region, the solubility curve varied abruptly, and the isotropic solution turned birefrigent. The conductivities of the single phase regions above the critical point increased up to a certain point as 1-hexanol added, and then decreased, representing the microstructural transition at the supercritical region. Further, the solubility of 1-hexanol in aqueous micellar solution was found to increase as temperature and the number of hydrophilelipophile balance of surfactants increase.

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Circular Polarization Spectroscopy in ^{87}Rb D_2$ line and Laser Frequency Stabilization (^{87}Rb D_2$ 전이선에 대한 원편광 분광 연구 및 레이저 주파수 안정화)

  • 문한섭;김승일;김현아;김중복;이호성
    • Korean Journal of Optics and Photonics
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    • v.6 no.4
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    • pp.317-323
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    • 1995
  • Doppler-free circular polarization spectroscopy in 87Rb Dz line has been carried out by using a diode laser whose linewidth was narrowed by an external cavity, and experimental results were compared with an optical pumping polarization spectroscopy theory. A dispersive spectrum obtained in a weak pump beam was completely fitted to a single cycle optical pumping theory. The laser frequency was locked to a Rb atomic hyperfine transition line without any frequency modulation by using the dispersive curve as an error signal. ignal.

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Cure Characteristics of Metal Particle Filled DGEBA/MDA/SN/ zeolite Composite System for EMI Shielding

  • Cho, Young-Shin;Lee, Hong-Ki;Shim, Mi-Ja;Kim, Sang-Wook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.548-551
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    • 1999
  • The cure characteristics of metal particle filled DGEBA/MDA/SN/ zeolite epoxy resin composite system for EMI shielding were investigated by dynamic DSC run method and FT-lR spectroscopy. As the heating rate increased, the peak temperature on dynamic DSC curve increased because of the rapid cure reaction. From the straight line of the Kissinger plot, the curing reaction activation energy and pre-exponential factor could be obtained. As the post-curing time at 15$0^{\circ}C$ increased, the glass increased the glass transition temperature or the thermal stability increased. When the post curing time is too long, the system filled with metallic Al particle can be thermally oxidized by the catalytic reaction of metal filler and the thermal stability of the composite for the EMI shielding application may be decreased.

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Development of Korean Standard Horizontal Design Spectrum Based on the Domestic and Overseas Intra-plate Earthquake Records (국내외 판내부 지진기록을 이용한 한국 표준수평설계스펙트럼의 개발)

  • Kim, Jae Kwan;Kim, Jung Han;Lee, Jin Ho;Heo, Tae Min
    • Journal of the Earthquake Engineering Society of Korea
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    • v.20 no.6
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    • pp.369-378
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    • 2016
  • The design spectrum for Korea, which is known to belong to an intra-plate region, is developed from the ground motion records of the earthquakes occurred in Korea and overseas intra-plate regions. The horizontal spectrum is defined as geometric mean spectrum, GMRotI50. From the statistical analysis of the geometric mean spectra, a mean plus one standard deviation spectrum in lognormal distribution is obtained. Regression analysis is performed on this curve to determine the shape of spectrum including transition periods. The developed design spectrum is valid for the estimation both spectral acceleration and displacement.

Miscibility and Thermal Behavior of Biodegradable Synthetic Aliphatic Polyester (Bionolle) and Poly(epichlorohydrin) Blends (생분해성 지방족 폴리에스테르(Bionolle)와 폴리에피클로로하이드린 블렌드의 상용성 및 열적 거동에 관한 연구)

  • 김진호;최형진;이동주;윤진산;진인주
    • Polymer(Korea)
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    • v.24 no.3
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    • pp.358-365
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    • 2000
  • Miscibility itnd thermal behavior of blends of synthetic biodegradable aliphatic polyester (Bionolle) with poly(epichlorohydrin) (PECH) were investigated by a differential scanning calorimetry (DSC), a dynamic mechanical thermal analyzer (DMTA) and a rotational rheometer. Observed both single glass transition temperatures from the DSC in agreement with the Fox equation and single T$_{g}$ changes as a function of composition from the DMTA indicate that these blend mixtures are miscible. In addition, the miscibility of this blend system was also observed from the single curve of the Cole-Cole Plot of log G′($\omega$) vs. log C"($\omega$) from the dynamic test using a rotational rheometer. This was further verified from the cryogenically fractured surface of BDP/PECH blends by scanning electron microscopy.

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Effect of Slip System Transition on the Deformation Behavior of Mg-Al Alloy: Internal Variable Based Approach (비탄성 변형 이론을 바탕으로 한 Mg-Al 합금의 슬립기구 천이 현상 해석)

  • Lee H.S.;Chang Y. W.;Bang W.
    • Transactions of Materials Processing
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    • v.13 no.6 s.70
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    • pp.535-539
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    • 2004
  • Although magnesium has high potential for structural material due to the lightweight and high specific strength, the structural application has been limited by the low ductility at room temperature. The reason of the poor ductility is few activated slip systems of magnesium (HCP structure) during deformation. As temperature increases, however, additional non-basal slip systems are incorporated to exhibit higher ductility comparable to aluminum. In the present study, a series of tensile tests of Mg-Al alloy has been carried out to study deformation behavior with temperature variation. Analysis of load relaxation test results based on internal variable approach gave information about relationship between the micromechanical character and corresponding deformation behavior of magnesium. Especially, the material parameter, p representing dislocation permeability through barriers was altered from 0.1 to 0.15 as the non-basal slip systems were activated at high temperature.

Thermo-Acoustic Instability in the Horizontal Rijke Tube

  • Song Woo-Seog;Lee Seung-Bae;Shin Dong-Shin;Na Yang
    • Journal of Mechanical Science and Technology
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    • v.20 no.6
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    • pp.905-913
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    • 2006
  • The instability curve of a Rijke tube system was obtained accurately by following different paths of heat power and flow-rate for three regions and by defining its locus from the criterion based on the measured sound pressure levels. The unstable limits in the region of flow-rate lower than that at the minimal power are compared with previous data. To observe the effect of turbulence on the unstable limits, inflow turbulence was introduced by placing a bundle of circular cylinders upstream of the heating part ($50). The large-amplitude inflow fluctuation may delay the transition of the chamber acoustic mode to the unstable Bone even at a sufficient power.

MAGNETIC PROPERTIES OF $FePt_{3}$ ORDERED ALLOY

  • Yoshida, H.;Fujimori, H.;Kaneko, T.;Abe, S.;Watanabe, K.;Matsumoto, M.;Yoshida, T.;Kanomata, T.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.362-365
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    • 1995
  • The magnetic properties for $Fe_{24}Pt_{76}\;and\;Fe_{26}Pt_{74}$ have been investigated. The temperature vs. magnetic susceptibility curve for $Fe_{24}Pt_{76}$ had no peak near the Neel temperature. The magnetization proccess at 4.2 K showed only a linear variation up to the high magnetic field of 240 kOe. That for $Fe_{26}Pt_{74}$ at 77 K showed a metamagnetic transition at 100 kOe. These properties were discussed on the basis of a band picture.

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정전위법에 의한 Alloy 600 및 Alloy 690의 Caustic 분위기에서의 부식저항성 비교

  • 맹완영;강영환;남태운
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.11b
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    • pp.475-480
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    • 1996
  • Alloy 600 및 Alloy 690의 Caustic 분위기에서, 시편의 포텐셜을 재료의 anodic polarization curve의 active-passive transition 영역의 한 값으로 일정하게 유지함으로서 응력부식균열을 쉽게 유발시키는 정전위 시험방법을 사용하여, 두 합금의 부식저항성을 비교하였다. C-ring형태의 Alloy 600 및 690 시편에 응력을 부과하고 30$0^{\circ}C$의 10% NaOH용액에서 7일간 정전위 응력부식시험을 수행하였다. Alloy 600의 경우, 입계를 따르는 100$\mu$m정도 깊이의 균열이 발생하였으나 Alloy 690의 경우는 균열이 유발되지 않았다. Alloy 690의 경우 부식 시험시간이 경과함에 따라 표면부식전류밀도는 주기적인 Passivation 경향을 보이나 Alloy 600의 경우는 점진적으로 표면부식전류밀도가 증가한다. Alloy 690의 강한 응력부식저항성은 이와 같은 주기적인 Passivation에 의한 것으로 판단된다.

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Ionic Strength Dependent Binding Mode of 9-Aminoacridine to DNA

  • 김혜경;조태섭;Kim, Seog K.
    • Bulletin of the Korean Chemical Society
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    • v.17 no.4
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    • pp.358-362
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    • 1996
  • The ionic strength dependent binding mode of 9-aminoacridine (9AA), a well-known DNA intercalator, to DNA is studied by flow linear dichroism, circular dichroism, fluorescence techniques and equilibrium dialysis. The DNA-bound 9AA exhibits spectral properties corresponding to the intercalative binding mode disregarding the salt concentrations; the angle between the long-axis transition moment of the 9AA molecule and DNA helix axis is calculated to be about 65°, indicating a significant deviation from the classical intercalation. At low salt concentrations, however, upwards bending curve in Stern-Volmer plot is observed (where 9AA is a fluorophore and DNA a quencher), indicating the coexistence of both static and dynamic quenching mechanisms or the existence of an additional binding site.