• 제목/요약/키워드: Transition Temperature Tc

검색결과 54건 처리시간 0.032초

Finite-Size Errect에 의한 강바성 Gd박막의 상전이온도 이동 (Phase Transition Temperature Shift of a Ferromagenetic Gadelonium Film due to the Finite-Size Effects)

  • 이일수;이의완;이상윤
    • 한국재료학회지
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    • 제3권1호
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    • pp.3-6
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    • 1993
  • Gd박막의 강자성-상자성 상전이 온도(Tc)이동을 조사했다. 강자성-상자성 상전이 온도에서 전기저항이 변화되는 변곡점을 관측하여 Tc를 결졍하였는데, 두께가 6600$\AA$인 Gd박막의 상전이 온도는 bulk상태의 Gd의 전이온도보다 4$\pm$0.$3^{\circ}C$정도 아래로 이동됨을 알았다. 이것은 강자성 Gd박막의 Tc이동에 대한 최초의 측정이며, 실험과 finite-sime scaling이론을 비교 분석했다.

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III-V 화합물 자성 반도체의 강자성체 천이온도에 관한 연구 (Ferromagnic Transitition Temperature of Diluted Magnetic III-V Based Semiconductor)

  • 이화용;김송강
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 춘계학술대회 논문집 유기절연재료 전자세라믹 방전플라즈마 연구회
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    • pp.143-147
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    • 2001
  • Ferromagnetism in manganese compound semiconductors open prospects for tailoring magnetic and spin-related phenomena in semiconductors with a precision specific to III-V compounds. Also it addresses a question about the origin of the magnetic interactions that lead to a Curie temperature(Tc) as high as 110 K for a manganese concentration of just 5%. Zener's model of ferromagnetism, originally suggested for transition metals in 1950, can explain Tc of $Ga_{1-x}Mn_x$ As and that of its IT-VI counterpart $Zn_{1-x}Mn_x$ Te and is used to predict materials with Tc exceeding room temperature, an important step toward semiconductor electronics that use both charge and spin. In this article, we present not only the experimental result but calculated Curie temperature by RKKY interaction. The problem in making III-V semiconductor has been the low solubility of magnetic elements, such as manganese, in the compound, since the magnetic effects are roughly proportional to the concentration of the magnetic ions. Low solubility of magnetic elements was overcome by low-temperature nonequilibrium MBE{molecular beam epitaxy) growth, and ferromagnetic (Ga,Mn)As was realized. Magnetotransport measurements revealed that the magnetic transition temperature can be as high as 110 K for a small manganese concentration.

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In vitro Anticancer Activity of Paclitaxel Incorporated in Low-melting Solid Lipid Nanoparticles

  • Lee, Mi-Kyung;Yang, Jae-Heon
    • Journal of Pharmaceutical Investigation
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    • 제39권3호
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    • pp.201-205
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    • 2009
  • Triglyceride solid lipid with medium chain fatty acid, tricaprin (TC), was used as a core matrix of lipid nanoparticles (LN) to solubilize water-insoluble paclitaxel and enhance the stability of nanoparticles by immobilization of incorporated drug in the solid core during storage at low temperature. In the present study, TC-LN containing paclitaxel was prepared by hot melt homogenization method using TC as a core lipid and phospholipids as stabilizers. The particle size of TC-LN containing paclitaxel was less than 200 nm and its zeta potential was around -40 mV. Calorimetric analysis showed TC core could be solidified by freezing and thawing in the manufacturing process in which the hot dispersion should be prepared at elevated temperature and subsequently cooled to obtain solid lipid nanoparticles. The melting transition of TC core was observed at $27.5^{\circ}C$, which was lower than melting point of TC bulk. The particle size of TC-LN remained unchanged when kept at $4^{\circ}C$. Paclitaxel containing TC-LN showed comparable anticancer activity to the Cremophore ELbased paclitaxel formulation against human ovarian (OVCAR-3) and breast (MCF-7) cancer cell lines. Thus, lipid nanoparticles with medium chain solid lipid may have a potential as alternative delivery system for parenteral administration of paclitaxel.

EXAFS study for the ordering of manganese in $La_{0.7}Ca_{0.3-x}Ba_xMnO_3$

  • 양동석
    • 한국결정학회:학술대회논문집
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    • 한국결정학회 2002년도 정기총회 및 추계학술연구발표회
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    • pp.12-12
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    • 2002
  • Lanthanum manganites have been extensively studied for the application to magnetic devices since the colossal magnetoresistance of these compounds has been observed [1]. The critical temperatures, Tc, of manganites La/sub 0.7/Ca/sub 0.3-x/Ba/sub x/MnO₃ increased as the content of Ba increased except the abrupt jump near the critical concentration. The step like behavior of the critical temperature for a similar compound has been known to be related to the structural phase transition [2]. To understand the step like behavior of Tc, the EXAFS technique is applied to the La/sub 0.7/Ca/sub 0.3-x/Ba/sub x/MnO₃ compound system. The ordering between the manganese and oxygen was examined by this method. The EXAFS analysis shows that the coordination numbers were not changed before and after the phase transition, the bonding distance between manganese and oxygen is about 1.94 ± 0.02 Å, which is consistent with other work [3] and the Debye waller parameters were about σ²= 0.0037 ± 0.0005 Ų for x=0.0 and x=3.0, respectively. The value of Debye-Waller parameter for x=0.09 is about σ² = 0.0050 ± 0.0005 Ų in about phase transition concentration. Based on the Debye-Waller parameters, it is shown that the ordering between manganese and oxygen is significantly reduced near the phase transition concentration.

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Metal-insulator Transition of VO2 Thin Films and Nanowires Induced Photo-excitation

  • Sohn, Ahrum;Kim, Haeri;Kim, Eunah;Kim, Dong-Wook
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.196.1-196.1
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    • 2014
  • VO2 exhibits metal-insulator transition (MIT), of which critical temperature (TC) is about 340 K. There have been many reports that MIT can be induced by UV light as well as heat. Clear mechanism regarding such photo-induced MIT has not been clarified. We have compared the MIT behaviors of VO2 thin film during heating-cooling cycles with and without light. We tried several light sources with different wavelengths (red, blue, and UV). Tc and hysteresis width of the resistance change were influenced by the illumination of the samples. We performed Kelvin probe force microscopy (KPFM) studies, which can reveal the evolution of the local sample work function. In this presentation, we will discuss possible physical origins for the photo-induced effects on the MIT behaviors of the VO2 samples.

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불소화된 $YBa_2Cu_3O_{7-y}$ 초전도체의 구조적, 전기적 성질에 관한 연구 (A study on the structural and electric properties of fluorinated $YBa_2Cu_3O_{7-y}$)

  • 김재욱;김채옥
    • E2M - 전기 전자와 첨단 소재
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    • 제9권4호
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    • pp.404-409
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    • 1996
  • The structural and electric properties of $Y_{1-x}$YbF$_{x}$Ba$_{2}$Cu$_{3}$O$_{7-y}$(x=0.0, 0.1, 0.2, 0.3, 0.4, 0.5 and 0.6) have been investigated by using XRD(X-ray diffraction), TMA(thennomechanical analysis), NMR(nuclear magnetic resonance) analysis and four probe method. $Y_{1-x}$YbF$_{x}$Ba$_{2}$Cu$_{3}$O$_{7-y}$ samples were prepared by conventional solid-state reaction method using $Y_{2}$O$_{3}$, BaCO$_{3}$, CuO and YbF$_{3}$ power. TMA and high temperature XRD results shows that orthorhombic to tetragonal phase transition occurs in the unfluorinated 1-2-3 sample while the phase change is not observed in the fluorinated 1-2-3 samples. Superconducting transition temperature(T$_{c}$) increases with increasing YbF$_{3}$ content ; T$_{c}$, of the sample reaching maximum of 102K for x=0.3, and then decreases with further increasing YbF$_{3}$ content. The structural analysis and T$_{c}$ results shows that the fluorine doping stabilize the orthorhombic phase, together with the increase in T$_{c}$.}$ c/.TEX> c/.

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Mechanism Study of Tropical Cyclone Impact on East Asian Subtropical Upper-Level Jet: a Numerical Case Investigation

  • Chen, Xian;Zhong, Zhong;Lu, Wei
    • Asia-Pacific Journal of Atmospheric Sciences
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    • 제54권4호
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    • pp.575-585
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    • 2018
  • In the case study of this paper, sensitivity experiments are carried out using the mesoscale non-hydrostatic Weather Research and Forecasting (WRF) model to investigate the impact of tropical cyclone (TC) Soudelor (2003) on the East Asian subtropical upper-level jet (EASJ) before TC Soudelor transformed into an extratropical cyclone. The physical mechanism for changes in the EASJ intensity and position caused by TC Soudelor is explored. Results indicate that TC Soudelor would warm the air in the middle and upper troposphere over the Japan Sea and the adjacent areas through stimulating northward propagating teleconnection pattern as well as releasing large amounts of latent heat, which led to increase (decrease) the meridional air temperature gradient to the south (north) below the EASJ axis. As a result, the geopotential height abnormally increased in the upper troposphere, resulting in an anomalous anticyclonic circulation belt along the EASJ axis. Correspondingly, the westerly winds to the north (south) of the EASJ axis intensified (weakened) and the EASJ axis shifted northward by one degree. The case study also suggests that before the extratropical cyclone transition of TC Soudelor, the TC activities had exerted significant impacts on the EASJ through thermodynamic processes.

반응성 동시 증착법에 의한 As-grown $YBa_2Cu_3O_{7-x}$ 박막의 결정 특성 및 표면형상에 관한 연구 (Crystalline Qualities and Surface Morphologies of As-Grown $YBa_2Cu_3O_{7-x}$ Thin Films on MgO(100) Substrate by Reactive Coevaporation Method)

  • 장호연;도부안광;토신전농;청수현사;추빈량삼;강본당일;송진태
    • 한국재료학회지
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    • 제1권2호
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    • pp.93-98
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    • 1991
  • The as-grown $YBa_2Cu_3O_{7-x}$ superconducting thin films on MgO(100) substrate have been prepared by a reactive coevaporation method. The superconducting transition temperature, surface morphology and crystalline quality were examined as a function of the substrate temperature ranging from $450^{\circ}C$ to $590^{\circ}C$. From the reflection high energy electron diffraction (RHEED) analysis, it was found the film consisted of almost amorphous phase with a halo pattern deposited at the substrate temperature of $450^{\circ}C$. The film deposited at the substrate temperature of $510^{\circ}C$ consisted of polycrystalline phase, showing a broad ring pattern. On the other hand, for the film deposited at $590^{\circ}C$, RHEED showed spotty pattern indicating that this film consisted of single crystal phase. It has rough film surface due to the surface outgrowth. The surface outgrowth increased as the substrate temperature increased from $510^{\circ}C$ to $590^{\circ}C$. the surface outgrowth may be due to the anisotropic growth rate. The highest transition temperature obtained in this study was $Tc_{zero}$ of 83K with $Tc_{onset}$ of 88K for the film deposited at $590^{\circ}C$ using activated RF oxygen plasma.

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