• 한국전산구조공학회:학술대회논문집
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• 한국전산구조공학회 2001년도 봄 학술발표회 논문집
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• pp.391-397
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• 2001

This paper explores the free vibrations of double hinged curved beams with transition segment. In this study, the clothoid curve is chosen as the transition segment of beams. The differential equations governing free vibration of such beams are derived in which the effects of rotatory inertia and shear deformation are included. The Runge-Kutta method and Determinant Search method are used to perform the integration of differential equations and to compute natural frequencies, respectively. In numerical examples, the double hinged end constraint is considered. The lowest four natural frequencies are presented as functions of three non-dimensional system parameters: the slenderness ratio, shear parameter and stiffness parameter.

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 2002년도 봄 학술발표회 논문집
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• pp.466-469
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• 2002

Polyurethane(PU)은 segmented 블록공중합체로써 상온보다 높은 유리전이온도(glass transition temperature, Tg)를 갖는 hard segment(H.S)와 상온보다 낮은 Tg를 갖는 soft segment (S.S)로 구성되어 있다. 이들 두 segment간의 열역학적 불친화성으로 인해 미세 상분리 구조를 갖는다$^1$. 그 결과 hard segment-rich hard domain과 soft segment-rich soft matrix의 구조를 이룬다. 이중 hard domain(HD)은 상온에서 glassy한 성격을 띄므로 물리적 가교점과 충진제의 역할을 하며 soft domain(SD)은 rubbery한 성질을 가지므로 polurethane에 탄성을 부여하는 역할을 한다. (중략)

• 한국콘텐츠학회논문지
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• 제5권3호
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• pp.167-173
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• 2005

유성음원과 무성음원을 사용하는 음성부호화 방식에 있어서, 같은 프레임 안에 모음과 무성자음이 있는 경우에 음질저하현상이 나타난다. 본 논문에서는 같은 프레임 안에 유성음과 무정자음이 같이 존재하지 않도록 Zero Crossing Rate과 개별피치 펄스를 사용하여 무성자음을 포함한 천이구간을 추출하는 방법과 주파수대역을 분할하여 TSIUVC를 근사합성하는 방법을 제안한다. 실험결과, 0.547kHz 이하 2.813kHz 이상의 주파수 정보를 사용하여 TSIUVC 음성파형을 양호하게 근사합성 할 수 있었으며, TSIUVC의 추출율은 여자와 남자음성에서 각각 $91\%$와 $96.2\%$를 얻었다. 이 방법은 음성합성, 음성분석, 새로운 Voiced/Silence/TSIUVC의 음성부호화 방식에 활용할 수 있을 것으로 기대된다.

• Macromolecular Research
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• 제10권6호
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• pp.365-368
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• 2002

Thermoplastic polyurethanes (TPUs) with different hard segment length has been prepared from a fixed molar ratio of poly(tetramethylene ether glycol), 4,4'-diphenylmethane diisocyanate, and 1,4-butanediol by different polymerization procedures. Results reveal that the on-set temperature of endotherms ( $T_{cc}$ ) due to the crystallization of hard segments by cooling the TPUs from melt and the peak temperature of endotherms due to the melting of hard segments ( $T_{mh}$ ) by heating the TPUs increased and levelled off with increasing the hard segment length of TPUs. It has also been observed that soft segment glass transition temperature ( $T_{gs}$ ) of TPU decreased slightly with increasing the hard segment length, which explains less mixing of soft segments and hard segments. In tensile measurement of TPUs, strain hardening is observed with increasing the hard segment length, which is attributed to the strain induced crystallization of soft segments.

• 한국가스학회지
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• 제2권1호
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• pp.59-65
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• 1998

4,4'-diphenylmethane diisocyanate (MDI)와 폴리에스테르 폴리올 그리고 1,4-butane diol로부터 폴리우레탄을 제조하고 모폴로지와 열적 특성에 대하여 연구하였다. Fourier transform infrared spectroscopy (FT-IR)를 이용한 폴리우레탄의 모폴로지 관찰에서 수소 결합된 N-H 피크와 C=O 피크는 폴리우레탄에서 하드 세그먼트(hard segment)의 함량이 증가할수록 낮은 주파수대로 전이되어 수소 결합이 증가함을 알 수 있었다. 시차 주사 열분석기(DSC)를 이용한 열적 특성에 대한 연구에서 폴리우레탄의 유리전이온도($T_g$)는 하드세그먼트의 함량이 증가함에 따라 증가하였다. 또한 소프트 세그먼트(soft segment)의 $T_g$는 관찰할 수 없었으며 이로부터 본 연구에서 제조된 폴리우레탄은 MDI의 높은 작용기로 인하여 화학 결합에 의한 경화 반응으로 균일한 망상구조를 가지고 있음을 알 수 있었다. 또한 DSC로부터 관측된 폴리우레탄의 $T_g$는 Fox 식으로부터 예측된 $T_g$와 큰 차이를 나타냈으며, 이는 경화 반응으로 인하여 폴리우레탄 사슬의 운동성이 제약되기 때문으로 생각된다. 동적 기계적 열분석(DMTA)에서도 소프트 세그먼트의 전이온도는 관찰되지 않았으며 이로부터 본 연구에서 제조된 폴리우레탄에서 하나의 상을 갖는 모폴로지를 확인할 수 있었다.

• Macromolecular Research
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• 제10권4호
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• pp.230-235
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• 2002

Alternating polyols of oxymethylene and oxyalkylene were synthesized and used as precursors for thermoplastic poly(ether-ester) elastomers (TPEs). The polyols were synthesized by reacting diols having different methylene units with dichloromethane in the presence of a phase transfer catalyst. The number of methylene units in the alkylene oxides was varied from 3 to 6. TPEs were prepared using the polyols as soft segments and poly(butylene terephthalate) units as hard segments. The polyols and TPEs synthesized were characterized using FTIR, NMR, GPC, DSC, and polarized optical microscopy. The polyols showed a profound odd-even effect on the melting (T$_{m}$) and glass transition temperatures (T$_{g}$). Polyols with odd numbers of methylene groups in the alkylene units have higher transition temperatures than polyols with odd number of methylene groups. The tendency is still kept in TPEs, even though the T$_{g}$ of soft segment in TPEs are slightly higher than those of corresponding neat polyols. The T$_{m}$ and T$_{g}$ of soft segments are almost constant in the range of 20 to 60 wt % contents of soft segments. On the other hand, the normalized heat of fusion of hard segment decreased with increasing the content of loft segment.ent.t.ent.

• Advances in pediatric surgery
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• 제10권1호
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• pp.60-62
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• 2004

Leveling colostomy with a frozen-section biopsy in a Hirschsprung's disease is an important factor for a successful procedure. Two neonatal cases of Hirschsprung's disease in the descending colon are reported. In both cases, loop ileostomy was established because of the unavailability of frozen-section biopsy on an emergency basis. At the time of definitive procedure of the first case, transition zone at the splenic flexure was noted and was compatible with the frozen section biopsy. In the second case, an unexpected longer resection at a higher level than transition zone was required because of the poor vascularity after dissection. In conclusion, a leveling colostomy should be selected as a choice in long-segment Hirschsprung's disease. Confirming preservation of the marginal artery of Drummond is particularly important in case of Hirschsprung's disease in the descending colon.

• 한국정보처리학회논문지
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• 제7권4호
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• pp.1299-1304
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• 2000

In a speed coding system using excitation source of voiced and unvoiced, it would be involved a distortion of speech quality in case coexist with a voiced and an unvoiced consonants in a frame. So, I propose TSIUVC(Transition Segment Including UnVoiced Consonant) searching, extraction ad approximation-synthesis method in order to uncoexistent with a voiced and unvoiced consonants in a frame. This method based on a zerocrossing rate and pitch detector using FIR-STREAK Digital Filter. As a result, the extraction rates of TSIUVC are 84.8% (plosive), 94.9%(fricative), 92.3%(affricative) in female voice, and 88%(plosive), 94.9%(fricative), 92.3%(affricative) in male voice respectively, Also, I obain a high quality approximation-synthesis waveforms within TSIUVC by using frequency information of 0.547kHz below and 2.813kHz above. This method has the capability of being applied to speech coding of low bit rate, speech analysis and speech synthesis.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 1998년도 하계종합학술대회논문집
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• pp.603-606
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• 1998

In a large number of words and the continued speech recognition system using a phoneme as teh recognition unit, it is necessary to segment processing. In this paper, a normalized AMDF new method. The suggested parameter represents a degree of sharpness at valley point. This method can detect the speech segment between the steady state and transient region to the continued speech without a prior information of speech signal.

• 한국자기공명학회논문지
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• 제21권3호
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• pp.90-95
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• 2017

The Z-DNA domain of human ADAR1 ($Z{\alpha}_{ADAR1}$) produces B-Z junction DNA through preferential binding to the CG-repeat segment and destabilizing the neighboring AT-rich region. However, this study could not answer the question of how many base-pairs in AT-rich region are destabilized by binding of $Z{\alpha}_{ADAR1}$. Thus, we have performed NMR experiments of $Z{\alpha}_{ADAR1}$ to the longer DNA duplex containing an 8-base-paired (8-bp) CG-repeat segment and a 12-bp AT-rich region. This study revealed that $Z{\alpha}_{ADAR1}$ preferentially binds to the CG-repeat segment rather than AT-rich region in a long DNA and then destabilizes at least 6 base-pairs in the neighboring AT-rich region for efficient B-Z transition of the CG-repeat segment.