• Proceedings of the Computational Structural Engineering Institute Conference
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• 2001.04a
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• pp.391-397
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• 2001

This paper explores the free vibrations of double hinged curved beams with transition segment. In this study, the clothoid curve is chosen as the transition segment of beams. The differential equations governing free vibration of such beams are derived in which the effects of rotatory inertia and shear deformation are included. The Runge-Kutta method and Determinant Search method are used to perform the integration of differential equations and to compute natural frequencies, respectively. In numerical examples, the double hinged end constraint is considered. The lowest four natural frequencies are presented as functions of three non-dimensional system parameters: the slenderness ratio, shear parameter and stiffness parameter.

• Proceedings of the Korean Fiber Society Conference
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• 2002.04a
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• pp.466-469
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• 2002

Polyurethane(PU)은 segmented 블록공중합체로써 상온보다 높은 유리전이온도(glass transition temperature, Tg)를 갖는 hard segment(H.S)와 상온보다 낮은 Tg를 갖는 soft segment (S.S)로 구성되어 있다. 이들 두 segment간의 열역학적 불친화성으로 인해 미세 상분리 구조를 갖는다$^1$. 그 결과 hard segment-rich hard domain과 soft segment-rich soft matrix의 구조를 이룬다. 이중 hard domain(HD)은 상온에서 glassy한 성격을 띄므로 물리적 가교점과 충진제의 역할을 하며 soft domain(SD)은 rubbery한 성질을 가지므로 polurethane에 탄성을 부여하는 역할을 한다. (중략)

• The Journal of the Korea Contents Association
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• v.5 no.3
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• pp.167-173
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• 2005

In a speech coding system using excitation source of voiced and unvoiced, it would be involved a distortion of speech quality in case coexist with a voiced and unvoiced consonants in a frame. So, I propose TSIUVC(Transition Segment Including Unvoiced Consonant) extraction method by using pitch pulses and Zero Crossing Rate in order to unexistent with a voiced and unvoiced consonants in a frame. And this paper present a TSIUVC approximate-synthesis method by using frequency band division. As a result, this method obtains a high quality approximation-synthesis waveform within TSIUVC by using frequency information of 0.547kHz below and 2.813kHz above. And the TSIUVC extraction rate was $91\%$ for female voice and $96.2\%$ for male voice respectively This method has the capability of being applied to a new speech coding of Voiced/Silence/TSIUVC, speech analysis, and speech synthesis.

• Macromolecular Research
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• v.10 no.6
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• pp.365-368
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• 2002

Thermoplastic polyurethanes (TPUs) with different hard segment length has been prepared from a fixed molar ratio of poly(tetramethylene ether glycol), 4,4'-diphenylmethane diisocyanate, and 1,4-butanediol by different polymerization procedures. Results reveal that the on-set temperature of endotherms ( $T_{cc}$ ) due to the crystallization of hard segments by cooling the TPUs from melt and the peak temperature of endotherms due to the melting of hard segments ( $T_{mh}$ ) by heating the TPUs increased and levelled off with increasing the hard segment length of TPUs. It has also been observed that soft segment glass transition temperature ( $T_{gs}$ ) of TPU decreased slightly with increasing the hard segment length, which explains less mixing of soft segments and hard segments. In tensile measurement of TPUs, strain hardening is observed with increasing the hard segment length, which is attributed to the strain induced crystallization of soft segments.

• Journal of the Korean Institute of Gas
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• v.2 no.1
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• pp.59-65
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• 1998

Morphology and thermal properties of polyurethane synthesized from 4,4'-diphenylmethane diisocyanate (MDI), polyester polyol, and 1,4-butane diol are investigated using fourier transform infrared spectroscopy (FT-IR), differential scanning calorimeter (DSC), and dynamic mechanical thermal analysis (DMTA). From the FT-IR study, it is found that the stretching peaks of hydrogen bonded N-H and C=O are shifted to the low frequencies with the increase of hard segment content of the polyurethanes. The shift of the stretching peaks of hydrogen bonded N-H and C=O indicates that the degree of hydrogen bonding is increased. From the DSC study, it appears that the glass transition temperature ($T_g$) of the polyurethanes is increased with the increase of the hard segment content. Also, it is found that the polyurethanes investigated in this study have the homogeneous network structure due to the high functionality of the MDI. From the DMTA study, transition of the soft segment was not found. Therefore it is concluded that the polyurethanes investigated in this study have the one-phase morphology which is consistent with the DSC results.

• Macromolecular Research
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• v.10 no.4
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• pp.230-235
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• 2002

Alternating polyols of oxymethylene and oxyalkylene were synthesized and used as precursors for thermoplastic poly(ether-ester) elastomers (TPEs). The polyols were synthesized by reacting diols having different methylene units with dichloromethane in the presence of a phase transfer catalyst. The number of methylene units in the alkylene oxides was varied from 3 to 6. TPEs were prepared using the polyols as soft segments and poly(butylene terephthalate) units as hard segments. The polyols and TPEs synthesized were characterized using FTIR, NMR, GPC, DSC, and polarized optical microscopy. The polyols showed a profound odd-even effect on the melting (T$_{m}$) and glass transition temperatures (T$_{g}$). Polyols with odd numbers of methylene groups in the alkylene units have higher transition temperatures than polyols with odd number of methylene groups. The tendency is still kept in TPEs, even though the T$_{g}$ of soft segment in TPEs are slightly higher than those of corresponding neat polyols. The T$_{m}$ and T$_{g}$ of soft segments are almost constant in the range of 20 to 60 wt % contents of soft segments. On the other hand, the normalized heat of fusion of hard segment decreased with increasing the content of loft segment.ent.t.ent.

• Advances in pediatric surgery
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• v.10 no.1
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• pp.60-62
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• 2004

Leveling colostomy with a frozen-section biopsy in a Hirschsprung's disease is an important factor for a successful procedure. Two neonatal cases of Hirschsprung's disease in the descending colon are reported. In both cases, loop ileostomy was established because of the unavailability of frozen-section biopsy on an emergency basis. At the time of definitive procedure of the first case, transition zone at the splenic flexure was noted and was compatible with the frozen section biopsy. In the second case, an unexpected longer resection at a higher level than transition zone was required because of the poor vascularity after dissection. In conclusion, a leveling colostomy should be selected as a choice in long-segment Hirschsprung's disease. Confirming preservation of the marginal artery of Drummond is particularly important in case of Hirschsprung's disease in the descending colon.

• The Transactions of the Korea Information Processing Society
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• v.7 no.4
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• pp.1299-1304
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• 2000

In a speed coding system using excitation source of voiced and unvoiced, it would be involved a distortion of speech quality in case coexist with a voiced and an unvoiced consonants in a frame. So, I propose TSIUVC(Transition Segment Including UnVoiced Consonant) searching, extraction ad approximation-synthesis method in order to uncoexistent with a voiced and unvoiced consonants in a frame. This method based on a zerocrossing rate and pitch detector using FIR-STREAK Digital Filter. As a result, the extraction rates of TSIUVC are 84.8% (plosive), 94.9%(fricative), 92.3%(affricative) in female voice, and 88%(plosive), 94.9%(fricative), 92.3%(affricative) in male voice respectively, Also, I obain a high quality approximation-synthesis waveforms within TSIUVC by using frequency information of 0.547kHz below and 2.813kHz above. This method has the capability of being applied to speech coding of low bit rate, speech analysis and speech synthesis.

• Proceedings of the IEEK Conference
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• 1998.06a
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• pp.603-606
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• 1998

In a large number of words and the continued speech recognition system using a phoneme as teh recognition unit, it is necessary to segment processing. In this paper, a normalized AMDF new method. The suggested parameter represents a degree of sharpness at valley point. This method can detect the speech segment between the steady state and transient region to the continued speech without a prior information of speech signal.

• Journal of the Korean Magnetic Resonance Society
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• v.21 no.3
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• pp.90-95
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• 2017

The Z-DNA domain of human ADAR1 ($Z{\alpha}_{ADAR1}$) produces B-Z junction DNA through preferential binding to the CG-repeat segment and destabilizing the neighboring AT-rich region. However, this study could not answer the question of how many base-pairs in AT-rich region are destabilized by binding of $Z{\alpha}_{ADAR1}$. Thus, we have performed NMR experiments of $Z{\alpha}_{ADAR1}$ to the longer DNA duplex containing an 8-base-paired (8-bp) CG-repeat segment and a 12-bp AT-rich region. This study revealed that $Z{\alpha}_{ADAR1}$ preferentially binds to the CG-repeat segment rather than AT-rich region in a long DNA and then destabilizes at least 6 base-pairs in the neighboring AT-rich region for efficient B-Z transition of the CG-repeat segment.