• Title/Summary/Keyword: Transition Property

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The Study on Magnetic Properties of Transition Metal Doped Semiconductor (전이금속이 치환된 반도체 물질의 자기적 특성 연구)

  • Kim, Jae-Uk;Cha, Byung-Kwan;Ji, Myoung-Jin;Kwon, Tae-Phil;Park, Byoung-Cheon;Kyoung, Dong-Hyoun;Jin, Hoon-Yeol;Kim, Seung-Hoi;Kim, Jong-Gyu
    • Journal of the Korean Chemical Society
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    • v.54 no.6
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    • pp.766-770
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    • 2010
  • This is the study of magnetic properties of transition metal doped diluted magnetic semiconductors(DMSs). The wurtzite structure samples were synthesized by the sol-gel method. The thermodynamic characteristics and magnetic properties of $Zn_{1-x}Co_xO$ single phase was investigated for different doping concentration (x = 0%, 1%, 2%, 3%, 4%, 5%, 10%, 15%). The property of diluted magnetic semiconductors has been comfirmed by X-ray diffraction (XRD), Scanning Electronic Microscope (SEM) and Vibrating sample magnetometer (VSM). The magnetic properties of pure $Zn_{1-x}Co_xO$ is found to be dominated by the ferromagnetic interaction between doped transition metal ions, where by the ferromagnetic coupling strength is simply increased with the concentration(>5%) of the doped transition metal.

Estimation of Hydraulic Parameters of a Fractured Rock Aquifer Using Derivative Analysis (변동량 분석을 이용한 암반대수층의 수리학적 매개변수 산출)

  • Kim, Bum-Su;Yang, Dong-Chul;Yeo, In-Wook
    • Journal of Soil and Groundwater Environment
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    • v.15 no.6
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    • pp.46-52
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    • 2010
  • Derivative analysis, based on the derivative of the drawdown as a function of time (i.e., rate of drawdown change), was applied to the evaluation of hydraulic parameters of the aquifer as an aid of the aquifer test interpretation based on the Theis solutions. Pumping tests were conducted at a coastal fractured aquifer in Muan county, Korea, of which the drawdown data, measured at the two observation wells, were used for derivative analysis. Wellbore storage and transition period were hard to identify at conventional log-log and semi long plots, but was easily recognized by distinctive curves of positive unit slope, hump and negative unit slope in the derivative plot. For the observation well of OW-2 at which wellbore storage and transition lasted over an hour, conventional aquifer analysis would suffer from the uniqueness problems and in further result in erroneous hydraulic parameters. Derivative analysis was found to be effective for distinguishing the drawdown data directly reflecting the aquifer property from those reflecting non aquifer effects such as wellbore storage and transition, which offers a unified methodology to yield correct hydraulic parameters from aquifer test data.

Thermal Behavior of Langmuir-Blodgett Film of Poly(tert-butyl methacrylate) by Principal Component Analysis Based Two-Dimensional Correlation Spectroscopy

  • Jung, Young-Mee;Kim, Seung-Bin
    • Bulletin of the Korean Chemical Society
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    • v.26 no.12
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    • pp.2027-2032
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    • 2005
  • This paper demonstrates details of thermal behavior of Langmuir-Blodgett (LB) film of poly(tert-butyl methacrylate) (PtBMA) by using the principal component analysis based two-dimensional correlation spectroscopy (PCA2D) through eigenvalue manipulating transformation (EMT). By uniformly lowering the power of a set of eigenvalues associated with the original data, the smaller eigenvalues becomes more prominent and the subtle contribution from minor components is now highlighted much more strongly than the original data. Thus, the subtle difference of thermal behavior of LB film of PtBMA from minor components, which is not readily detectable in the conventional 2D correlation analysis, is much more noticeable than the original data. PCA2D correlation spectra with EMT operation for the temperature-dependent IR spectra of LB film of PtBMA reveal the hidden property of phase transition processes during heating.

Uniform bend transition and twist retention time improvement in a bistable chiral splay nematic liquid crystal cell

  • Kang, Sang-Ho;Jhun, Chul-Gyu;Lee, Seong-Ryong;Kim, Jae-Chang;Yoon, Tae-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1173-1176
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    • 2004
  • In a previous work we reported the bistable property by doping a chiral material in a splay cell. The bistable states are the splay state and the metastable 180$^{\circ}$twist state. The retention time of the metastable state can be changed by the variation of d/p (cell gap over pitch), cell gap, pretilt angle, azimuthal anchoring force, liquid crystal material, and so on. In this paper we will present uniform bend transition and twist retention time improvement in a multi-domain BCSN LC cell by using the multi cell gap method.

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Optical Properties of $Yb(HFA-D)_3$ Complex for Laser Material (레이저 매질로서의 $Yb(HFA-D)_3$ 착물의 광학적 특성)

  • 김정호;박용필
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2000.11a
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    • pp.129-132
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    • 2000
  • Perdeuterated hexaflouroacetyIacetonato-ytterbium $[Yb(HFA-D)_3]$ complexes were synthesized by the keto-en01 tautomerism reaction of $Yb(HFA-D)_3$ in methanol-$d_4$ in order to reduce the radiationless transition to the ligands. The luminescence properties of $Yb(HFA-D)_3$ complex were measured in the following anhydrous deuterated organic solvents ; Acetone-$d_6$, Methanol -$d_4$, THF-$d_6$, PO$(OHC_3)_3$ and DMSO-$d_6$. The intensity, lifetime and quantum efficiency of the luminescence in DMSO-$d_6$ were superior to those in other deuterated solvents. It was suggested that the anhydrous DMSO-$d_6$ might be the most appropriate solvent for the liquid laser material of $Yb(HFA-D)_3$ complex.

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Development of Laser Material for High Power and High Efficiency (고출력, 고효율 실현을 위한 새로운 레이저매질 개발)

  • 김정호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.15-18
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    • 2001
  • Perdeuterated hexaflouroacetylacetonato-ytterbium [Yb(SOL)-D)$_3$] complexes were synthesized by the keto-enol tautomerism reaction of Yb(SOL-H)$_3$ in methanol-d$_4$in methanol-d$_4$in order to reduce the radiationless transition to the ligands. The luminescence properties of Yb(SOL-D)$_3$complex were measured in the following anhydrous deuterated organic solvents ; Methanol-d$_4$, THF-d$\sub$8/, PO(OCH$_3$)$_3$ and DMSO-d$\sub$6/. The intensity, lifetime and quantum efficiency of the luminescence in DMSO-d$\sub$6/ were superior to those in other deuterated solvents. It was suggested that the anhydrous DMSO-d$\sub$6/ might be the most appropriate solvent for the liquid laser material of Yb(SOL-D)$_3$ complex.

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Optical Properties of Yb(SOL-D)$_3$ Complex for Laser Material (신 레이저매질 Yb(SOL-D)$_3$착물의 광학적 특성)

  • 김정호;서연호;박용필
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.640-643
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    • 2001
  • Perdeuterated hexaflouroacetylacetonato-ytterbium [Yb(SOL-D)$_3$] complexes were synthesized by the keto-enol tautomerism reaction of Yb(SOL-H)$_3$in methanol-d$_4$in order to reduce the radiationless transition to the ligands. The luminescence properties of Yb(SOL-D)$_3$complex were measured in the following anhydrous deuterated organic solvents ; Methanol-d$_4$, THF-d$_{8}$, PO(O$CH_3$)$_3$and DMSO-d$_{6}$. The intensity, lifetime and quantum efficiency of the luminescence in DMSO-d$_{6}$ were superior to those in other deuterated solvents. It was suggested that the anhydrous DMSO-d$_{6}$ might be the most appropriate solvent for the liquid laser material of Yb(SOL-D)$_3$complex.complex.

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Development of Yb(HFA-D)$_3$Complexes for Liquid Laser Material (액체 레이저 매질로서의 신물질 Yb(HFA-D)$_3$착물의 개발)

  • 김정호;박용필
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.12
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    • pp.1045-1050
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    • 2000
  • Perdeuterated hexaflouroacetylacetonato-ytterbium [Yb(HFA-D)$_3$]complexes were synthesized by the keto-enol tautomerism reaction of Yb(HFA-H$_3$) in methanol-d$_4$in rder to reduct the radiationless transition to the ligands. The luminescence properties of Yb(HFA-D)$_3$complex were measured in the following anhydrous deuterated organic solvents ; Methanol-d$_4$, THF-d$_{8}$, PO(O$CH_3$)$_3$and DMSO-d$_{6}$. The intensity, lifetime and quantum efficiency of the luminescnce in DMSO-d$_{6}$ were superior to those in other deuterated solvents. It was suggested that the anhydrous DMSO-d$_{6}$ might be the most appropriate solvent for the liquid laser material of Yb(HFA-D)$_3$complex.complex.

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A Study on the Organization of the village and the Property of Folk Houses on Seomi 2-dong village in An-Dong (안동 서미 2동의 마을구조 및 민가 특성에 관한 연구)

  • 정명섭;곽동엽
    • Journal of the Korean housing association
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    • v.14 no.1
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    • pp.67-76
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    • 2003
  • This study is to analyze the system of the architectural order on Seomi 2-dong village in An-Dong. The scope of this study concentrated on the 12 traditional houses situated on this area. The focus of this study is mainly to investigate the transition of this village, the arragement of houses related in geographical features of it, and the characteristics of the site and ground plans on these houses. As results of it, there are mostly Yeo-Kan houses(six spans sized) on Seomi 2-dong village in An-Dong and every house on this domain is in harmony with the systematic order of it.

Thermodynamic properties and structural geometry of KMgCl3·6H2O single crystals

  • Yoon, Hyo In;Lim, Ae Ran
    • Journal of the Korean Magnetic Resonance Society
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    • v.19 no.3
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    • pp.119-123
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    • 2015
  • The thermodynamic properties and structural geometry of $KMgCl_3{\cdot}6H_2O$ were investigated using thermogravimetric analysis, differential scanning calorimetry, and nuclear magnetic resonance. The initial mass loss occurs around 351 K ($=T_d$), which is interpreted as the onset of partial thermal decomposition. Phase transition temperatures were found at 435 K ($=T_{C1}$) and 481 K ($=T_{C2}$). The temperature dependences of the spin-lattice relaxation time $T_1$ for the $^1H$ nucleus changes abruptly near $T_{C1}$. These changes are associated with changes in the geometry of the arrangement of octahedral water molecules.