• Title/Summary/Keyword: Trace elements

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Changes in Availability of Toxic Trace Elements (TTEs) and Its Effects on Soil Enzyme Activities with Amendment Addition

  • Lee, Sang-Hwan;Park, Misun;Kim, Min-Suk
    • Ecology and Resilient Infrastructure
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    • v.7 no.2
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    • pp.134-144
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    • 2020
  • In-situ stabilization is a remediation method using amendments to reduce contaminant availability in contaminated soil. We tested the effects of two amendments (furnace slag and red mud) on the availability of toxic trace elements (TTEs) and soil enzyme activities (dehydrogenase, phosphatase, and urease). The application of amendments significantly decreased the availability of TTEs in soil (p < 0.05). The decreased availability of TTE content in soils was accompanied by increased soil enzyme activities. We found significant negative relationships between the TTE content assessed using Ca(NO3)2-, TCLP, and PBET extraction methods and soil enzyme activities (p < 0.01). Soil enzyme activities responded sensitively to changes in the soil environment (pH, EC, and availability of TTEs). It could be concluded that soil enzyme activities could be used as bioindicators or ecological indicators for soil quality and health in environmental soil monitoring owing to their high sensitivity to changes in soil.

Studies on the Contents of the Trace Elements in Vegetables. (식품중 미량원소의 함량에 관한 연구)

  • Lee, S.K.;Youn, J.E.;Lee, S.H.;Hur, Y.H.;Lee, B.O.
    • Journal of Environmental Health Sciences
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    • v.3 no.1
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    • pp.13-16
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    • 1976
  • Authors investigated the analyse trace elements in vegetables and Ginseng which indicated as follows: 1. Garlic, ginger, and onion has considerably large amounts of magnesium, garlic has in proper sequence as copper, aluminum, magnesium, bromine and mercury. Ginseng has in proper sequence as aluminum, magnesium, copper, bromine and mercury, and onion has in proper sequence as copper, manganese, aluminum, bromine and mercury. 2. Carrot has considerably large amounts of magnesium and has in proper sequence as copper, magnesium, aluminum, bromine and mercury. 3. Ginseng also has large amounts of magnesium and has in proper sequence as magnesium, aluminum, copper, bromine, and mercury.

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Petrochemical Characteristics and Review on Petrogenesis on Cretaceous to Tertiary Volcanic Rocks in the Kyongsang Basin (경상분지 백악기~제3기 화산암류의 암석화학적 특징과 암석 성인 고찰)

  • Sung, Jong-Gyu;Kim, Jin-Seop
    • The Journal of the Petrological Society of Korea
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    • v.21 no.2
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    • pp.217-233
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    • 2012
  • Major elements abundances of Cretaceous to Tertiary volcanic rocks in Kyongsang basin are similar with Southern Volcanic Zone (SVZ) in Andes. Sr, K, Rb, $Ba{\pm}Th$ abundances, which have low ionic charge, are selectively fertile, on the other hand Ta, Nb, Ce, P, Zr, Hf, Sm, Ti, Y, Yb, Sc, Cr abundances are low. K, Sr, Th show characteristic spikes and Nb show remarkable trough on trace elements spider diagram. Trace elements abundances are higher than that of Andes which is supposed to mantle sources of Kyongsang basin volcanic rocks are produced lower degree of partial melting than SVZ in Andes.

A Study on Zinc, Copper, Iron Nutritional Status of Women Patients with Breast Cancer in Korea (여성 유방암 환자의 철, 구리, 아연 영양상태에 관한 연구)

  • Chun Noo-Ri;Kim Eun-Young;Bae Yun-Jung;Sung Chung-Ja
    • Journal of Nutrition and Health
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    • v.39 no.1
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    • pp.28-34
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    • 2006
  • This study was performed to compare nutrients intake and levels of three elements (iron, copper and zinc) in the plasma of breast cancer patients to those in healthy controls. Patients (n = 97) and their age-matched healthy control groups (n = 97) participated in the study. A semi-quantitative food frequency questionnaire specifically formulated to evaluate the consumption of nutrients was used to estimate dietary intake. Only plasma was taken from the 20 patients and their age-matched healthy control group. Plasma concentrations of iron, copper, zinc, ratio of Cu/Zn were measured in both groups. Results showed that patients consumed significantly lower protein, fat, iron. Plasma level of copper and ratio of Cu/Zn were significantly higher in patients compared to those of controls. In conclusion, change of trace elements in plasma might be useful and significant as biomakers involving the initial process. And these results imply that trace elements status is a factor related to breast cancer risk and suggest that proper intake of those nutrients is required for cancer prevention.

Size Distribution of Ambient Aerosol Measured at a Coastal Site in Jeju Island (제주도 해안가에서 측정된 에어로졸의 성분별 입경분포 특성)

  • 이기호;양희준;허철구
    • Journal of Environmental Science International
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    • v.12 no.10
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    • pp.1043-1054
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    • 2003
  • During the period from April to September 2002, the size distributions of ambient aerosol were measured at the coastal site at Hamduk in Jeju Island. Na$\^$+/, K$\^$+/, Mg$\^$2+/, Ca$\^$2+/and Cl$\^$-/ exhibited mostly a bimodal coarse mode size distribution, while ammonium and sulfate were mainly in the fine size range, with maximum at around 0.54$\mu\textrm{m}$. The average molar concentration ratio of ammonium to sulfate for fine particles was equal to 2.0${\pm}$0.9. Nitrate was evenly found in both the coarse and fine modes. Elements like Al, Fe, Cu, Mg, Na, Ti, Sr and Mn were dominant in coarse particles, with the maximum at around 5.25$\mu\textrm{m}$. S and Pb were mainly in the submicrometer size range. Other elements with a fine and coarse modes were V, Ni, Cu, Ba and Mo. The patterns of the size distributions of trace elements measured at the downtown in Jeju City were very similar to those at the coastal site in Hamduk. However, the amplitude of size fractional concentrations at Jeju City was narrower than that at Hamduk. While the mass median diameters for the chemical species originated from the natural origin such as marine and crust were relatively large, those for ammonium, sulfate, S and Pb were very small.

Intercomparison and Determination of Trace Elements in Urban Dust by Neutron Activation Analysis (중성자방사화분석법을 이용한 대기분진중의 미량원소 비교분석)

  • Chung, Yong-Sam;Moon, Jong-Hwa;Kim, Sun-Ha;Park, Kwang-Won;Kang, Sang-Hun
    • Analytical Science and Technology
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    • v.13 no.2
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    • pp.179-188
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    • 2000
  • Trace elements in air samples artificially loaded on filters with urban dust and the bulk material of urban dust as an environmental sample were determined non-destructively using instrumental neutron activation analysis. Standard reference material (Urban Dust, SRM 1648) of the National Institute of Standard and Technology was used for the analytical quality control. The relative error for 37 elements was less than 15% and the standard deviation was less than 10%. 29 elements in the urban dust and 21 elements in the loaded filter sample were determined respectively. To evaluate the proficiency and reliability of the measurement, data intercomparison was performed and 39 analytical laboratories participated in the analysis using different analytical methods; neutron activation analysis, particle induced X-ray emission analysis, X-ray fluorescence analysis and atomic absorption spectrometry. Z-scores were calculated using the standard deviation of the laboratorie's mean as target standard deviation, and a good result was obtained that the values fall between -1 and +1 except some elements.

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Studies on the Distribution of Heavy Metal Concentrations in Ambient Suspended Particulate Matters Using the X-ray Fluorescence Spectroscopy (X-선 형광분광법을 이용한 대기부유분진중 중금속의 농도분포에 관한 연구)

  • 이태정;김동술
    • Journal of Korean Society for Atmospheric Environment
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    • v.8 no.1
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    • pp.20-28
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    • 1992
  • The x-ray fluorescence(XRF) is one of the most convenient and widely used techniques for analyzing trace elements in ambient particulate matters. The objects of the study were to estimate the optimum exposure time using the XRF, to investigate the distributions of heavy metal levels in particulate matters, and finally to study seasonal variation for the concentrations of total suspended particulate matters(TSP) and size fractionated particulate matters. The suspended particulate matters had been collected by a cascade impactor having 9 size fragnated stages for 3 years(Dec. 1988 to Nov. 1991) in Kyung Hee University-Suwon Campus. The particulate matters were then collected on each stage by membrane filters. The weight concentrations were determined by the XRF system. Thus, seasonal variations and relationship between concentration and particle size could be investigated. Resulting distribution was bimodal with the coarse and the fine particle groups minimum occurring around 2.1 to 3.3 $\mu$m as an aerodynamic diameter. To determine optimum exposure time of the XRF for various trace inorganic elements, membrane filters and the NIST standard filters were extensively studied. Using a statistical technique, optimum exposure time was estimated for each trace element and overall elements. The time was then determined as 20 seconds for the XRF system. The concentration of TSP was 123.9$\mum/m^3$ on an arithmatic average. The levels of each inorganic metal were Si 2420.0ng/$m^3$, Fe 977.1ng/$m^3$, and so on. The Pb. Zn, and Cu abounded in the fine mode group, while Ca, Fe, Si, Al, and K in the coarse group. Marked seasonal variation of TSP and metal concentrations was observed. The concentration of heavy metals in the fine mode was highest in winter : on the other hand, that in the coarse mode was highest in spring.

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Studies on the Analysis of Constituents of Deer Horn(I) -Assay of Trace Elements and TLC Pattern Analysis of Gangliosides- (산지별 녹용(鹿茸)류의 성분분석 연구(I) -미량금속의 정량 및 Gangliosides의 TLC Pattern 분석-)

  • Hong, Nam-Doo;Won, Do-Hee;Kim, Nam-Jae;Chang, Seung-Youb;Youn, Whang-Geum;Kim, Hae-Soo
    • Korean Journal of Pharmacognosy
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    • v.22 no.3
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    • pp.171-182
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    • 1991
  • Several experiments were carried for the purpose of establishing the basis for the quality evaluation of deer horn. Deer horn originated from China, New Zealand, Soviet and Alaska were used as objectives and some constituents involved in deer horn were assayed and compared with one another. Five kinds of trace elements including Ca and Fe were determined by atomic absorbance spectroscopy. The more the region came down from the top of the deer horn, the more the ratio of Ca to Fe content (Ca/Fe) was increased. The same increasing tendancy was observed in the case of ash content. Gangliosides were isolated from deer horn by alumina column chromatography and identified by TLC using gangliosides Type II obtained from bovine brain as the standard material. The TLC chromatograms were scanned by dual wavelength TLC scanner, then those TLC profiles were compared. Deer horn from China and New Zealand were analogous but those from Soviet and Alaska were each distinguished in their TLC profiles.

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