• 제목/요약/키워드: Trace analysis

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폐암조직에서 중성자 방사화 분석법을 이용한 미량 원소 분석 (Trace Element Analysis by Neutron Activastion Analysis in the Human Cancer Tissue)

  • 임상무;조재일;심영목;정영주;조승연;정용삼
    • 대한핵의학회지
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    • 제27권1호
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    • pp.104-111
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    • 1993
  • Trace elements are important components in the biological system, as a structural material and metabolic controller. Neutron activation analysis (NAA) with high neutron flux and high energy resolution Ge (Li) detector coupled to multichannel analyzer (MCA) has been one of the most accurate method for the determination of ultra-trace level components, and is applicable to biological material. In human body, the NAA can be used for quantitation of trace elements in various organs and tissue with endocrinological and metabolic disease and industrial metal poisoning. In this study, Triga Mark III nuclear reactor in Korea Atomic Research Institute was used for quantitation of trace eleement in human lung cancer tissues by neutron activation analysis. In the squamous cell carcinoma tissues, Br, Hg, La, Sb, Sc, Cl, Fe and I content were lower than normal lung tissues, and K, Rb and Se content were higher. In the adenocarcinoma tissues, Fe, Au, La, Sc and Zn content were lower than normal lung tissues, and Rb, Co and Se content were higher. Rb content was higher in the adenocarcinoma tissues than in the squamous cell carcinoma tissues. Fe and Na content were higher in the squamous cell carcinoma tissues than in the adenocarcinoma tissues.

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ON DIFFERENTIABILITY OF THE MATRIX TRACE OPERATOR AND ITS APPLICATIONS

  • Dulov, E.V.;Andrianova, N.A.
    • Journal of applied mathematics & informatics
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    • 제8권1호
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    • pp.97-109
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    • 2001
  • This article is devoted to “forgotten” and rarely used technique of matrix analysis, introduced in 60-70th and enhanced by authors. We will study the matrix trace operator and it’s differentiability. This idea generalizes the notion of scalar derivative for matrix computations. The list of the most common derivatives is given at the end of the article. Additionally we point out a close connection of this technique with a least square problem in it’s classical and generalized case.

GC/AED를 이용한 HFC-134a의 미량 불순물 분석 (Determination of trace impurities of HFC-134a by gas chromatograph with atomic emission detector (GC/AED))

  • 김명자;임정식;이진복;이정순
    • 분석과학
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    • 제30권5호
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    • pp.240-251
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    • 2017
  • 1,1,1,2-수소불화탄소(HFC-134a)는 에어컨에 주로 사용되는 냉매로, 최근 온실가스로 규제되어 정제를 통한 재사용 방법이 권장되고 있다. 폐냉매의 재사용 기준 평가를 위해서는 폐냉매에 존재하는 미량 성분의 정량분석이 매우 중요하다. 본 연구에서는 표준 물질이 없어서 정량화하기 어려웠던 C, H, Cl, F가 포함된 미량 성분들을 GC/AED (gas chromatograph-atomic emission detector)를 이용하여 정량분석하였다. 이를 위하여 GC/MSD (mass selective detector)를 통한 정성분석을 선행하였다. 또한 성분의 원자 수와 비례하여 반응하는 AED의 특성을 조사하기 위하여, 탄화수소 혼합 표준물질을 이용하여 선형성을 확인하였다. 시료 중 C, H, Cl, F가 포함된 미량 성분의 정성 분석 결과, 주성분인 HFC-134a와 유사 냉매류들을 포함한 총 15 개의 성분이 검출되었다. MSD 결과를 토대로 AED를 이용한 미량 성분들을 정량 분석한 결과, 한 시료는 $CHClF_2$ 성분($45438.38{\mu}mol/mol$), 또 다른 시료는 $C_2H_2ClF_3$ 성분($1311.47{\mu}mol/mol$)이 가장 높은 몰분율을 나타냈다. 본 연구에서는 이 분석법을 기반으로 하여, 표준 물질이 존재하지 않아 정량화하기 어려운 복합 성분들의 정성 및 정량 분석의 확장 적용이 가능할 것으로 보인다.

PCB 파원이 내장된 금속 함체의 공진 특성 해석 (Analysis of Resonant Characteristics for a Metallic Shielding Enclosure with a PCB Source)

  • 조병두;김기채
    • 한국전자파학회논문지
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    • 제23권4호
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    • pp.507-514
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    • 2012
  • 본 논문에서는 함체 내부의 PCB에 있는 트레이스 파원에 의한 함체의 공진 특성 해석법을 제안하고 있다. 함체 내부의 전자계를 계산하기 위해 PCB 트레이스에 형성되는 전류 분포 및 PCB 유전체의 경계면에서 만족하는 경계면 전계 분포에 관한 연립 적분방정식을 유도하였으며, 연립 적분방정식의 해는 Galerkin의 모멘트 법으로 구하고 있다. 그 결과, 함체의 공진 특성은 실험 결과 및 HFSS 툴에 의한 시뮬레이션 결과와도 잘 일치하고 있으며, 함체의 공진 주파수는 PCB 트레이스의 위치에 의해 달라진다는 것을 확인하고 있다. 이론 해석의 타당성을 검증하기 위해 반사 계수의 이론치를 측정치와도 비교하고 있다.

Comparative study of constitutive relations implemented in RELAP5 and TRACE - Part I: Methodology & wall friction

  • Shin, Sung Gil;Lee, Jeong Ik
    • Nuclear Engineering and Technology
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    • 제54권9호
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    • pp.3526-3539
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    • 2022
  • Nuclear thermal-hydraulic system analysis codes have been developed to simulate nuclear reactor systems, which solve simplified governing equations by replacing source terms with constitutive relations for simulating entire reactor systems with low computational resources. For half a century, many efforts have been made for wider versatility and higher accuracy of system codes, but various factors can affect the code analysis results, and it was difficult to isolate these factors and interpret them individually. In this study, two system codes, RELAP5 and TRACE, which have many users and are highly reliable, are selected to analyze only the effects of constitutive relations. The influence of constitutive relations is analyzed using in-house platforms that replicate constitute relations of RELAP5 and TRACE equally to exclude factors that may affect analysis results, such as governing equation solvers and user effects. Among the various constitutive relations, the analysis is performed on the wall variables expected to have the most influence on the analysis results. Part 1 paper presents the methodology and wall friction model comparison, while Part 2 paper shows wall heat transfer comparison of the two selected codes.

Chemical Speciation of Trace Metals in Natural Water by Ultrafiltration/Size Exclusion Chromatography/UV Absorption/ICP-MS

  • Haraguchi, Hiroki;Itoh, Akihide;Kimata, Chisen
    • 분석과학
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    • 제8권4호
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    • pp.405-410
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    • 1995
  • A study on elemental speciation of trace metals in lake water (Lake Biwa in Japan) has been carried out by a size exclusion chromatography (SEC) / inductively coupled plasma mass spectrometry (ICP-MS) system. Before analysis, the water sample was preconcentrated with a ultrafiltration technique, where the large molecules with molecular weight larger than 10,000 were concentrated. Then the preconcentrated water samples (500-1000 fold) were analyzed by a SEC/ICP-MS system. Most trace metals were found at the UV absorption peaks corresponding to the molecular weights of ca. 300,000 and 10,000-50,000, where trace metals were on-line detected by ICP-MS. The results suggest that many of trace metals exist as the large organic molecules-metal complexes in natural water.

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지구 통계학적 방법에 의한 충남 탄전 지역 하상퇴적물의 미량원소 오염조사 (Investigation of trace element contamination in steam sediments in the Chungnam coal mine area using geostatistical approach)

  • 황춘길
    • 자원환경지질
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    • 제32권1호
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    • pp.63-72
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    • 1999
  • In order to examine the contamination levels of trace elements in stream sediments in the Chungnam coal mine area, stream sediment and water samples were collected and analyzed for trace elements. The pH of stream water was neutral or weak-alkaline and the mobility of metal in stream sediments was supposed to be low. From the result of cluster analysis, non-polluted sampling stations can be distinguished from polluted sampling stations influenced by mining activities. The trace element concentrations in sediments from non-polluted zone were considered to be the natural backround concentrations of this area. The trace element concentrations in sediment samples from the mining area were higher than those from non-polluted area, and contaminated area of enriched trace element levels need to be properly managed. From the results of discriminant and regression analyses, concentrations of Cd, Cu, Pb AND zN and predicted values of Be, Mo, and Ni in Chungnam coal mine area were found to be lower than those in metal mining areas in Korea.

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제어봉구동장치의 동작 시뮬레이션 (Simulation of the Operation of the Control Element Drive Mechanism)

  • 김현민;김인용;김일곤
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 추계학술대회
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    • pp.468-473
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    • 2004
  • The magnetic jack type Control Element Drive Mechanism (CEDM) had been developed and verified through electromechanical testing including the testing of the magnetic force required to lift the control element assembly. It would become inefficient in view of cost and time for parametric studies to be performed by test to improve the CEDM system. So it becomes necessary to develop a computational model to simulate the electromagnetic characteristics of the CEDM in order to improve the CEDM design efficiently. In this paper it is presented that the electromagnetic analysis using a 2D axisymmetric FEM model has been carried out to simulate the operation of the latch magnet of the CEDM to generate a current trace for latch coil. The results show the calculated current trace is very similar to the real current trace taken from the CEDM.

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울산지역 주변의 토양 및 곡류(쌀,콩)중의 미량금속 함량에 관한 조사연구 (A Study on Trace Metal Contents in Rice, Soybean and Soils in the Vicinity of Ulsan Area)

  • 김종욱;이용욱
    • 한국환경보건학회지
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    • 제22권2호
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    • pp.69-82
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    • 1996
  • The samples for testing have been collected from Kangdong-myon, Nongso-myon, Beomseo-my on, and Cheongryang-myon in Ulju-Ku, Ulsan-city from July 1994 to March 1995 in order to grasp status of trace metals contained in some rice, soybean and soils, and to provide references in establishing their standard 96 collected samples(48 for cereals and 48 for soils) have been tested to measure levels of Hg, Pb, Cd, Cu, and Zn through methods of trace metal containing analysis and heavy metal analysis. moisture content was also analyzed. And at the same time 0.1N-HCl soluble heavy metal content of soil was measured. The average Hg containing level of samples is 0.006 ppm for cereal and 0.062 ppm for soil, Pb is 0.302 ppm for cereal and 1.137 ppm for soil, Cd is 0.012 ppm for cereal and 0.027 ppm for soil, Cu is 2.01 ppm for cereal and 0.885 ppm for soil, and Zn is 7.853 ppm for cereal and 2.366 ppm for soil.

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Walking load model for single footfall trace in three dimensions based on gait experiment

  • Peng, Yixin;Chen, Jun;Ding, Guo
    • Structural Engineering and Mechanics
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    • 제54권5호
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    • pp.937-953
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    • 2015
  • This paper investigates the load model for single footfall trace of human walking. A large amount of single person walking load tests were conducted using the three-dimensional gait analysis system. Based on the experimental data, Fourier series functions were adopted to model single footfall trace in three directions, i.e. along walking direction, direction perpendicular to the walking path and vertical direction. Function parameters such as trace duration time, number of Fourier series orders, dynamic load factors (DLFs) and phase angles were determined from the experimental records. Stochastic models were then suggested by treating walking rates, duration time and DLFs as independent random variables, whose probability density functions were obtained from experimental data. Simulation procedures using the stochastic models are presented with examples. The simulated single footfall traces are similar to the experimental records.