• Title/Summary/Keyword: Toxic metal

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Transmissions of Toxic Substances and Trade between Korea and America : Using International Input-Output Analysis (한·미 국제무역에 따른 독성물질의 이전 : 국제산업연관분석의 응용)

  • Rhee, Hae-Chun
    • Environmental and Resource Economics Review
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    • v.17 no.3
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    • pp.31-59
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    • 2008
  • This paper is intended to analyze the toxic substances transmission between South Korea and U.S. through international trade, based on 2000 international input-output data and both country's toxic substances. According to result, The high TEI sectors are metal, chemical and general machinery in Korea, and the high TEI sectors of America are electric & electronics, Chemicals, Rubber and Plastics. Korea's export structure to America is more pollutant than America's export structure to Korea.

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Toxic Interactions of Perfluorinated Compounds (PFCs) with Heavy Metals Using Vibrio fischeri (발광박테리아 Vibrio fischeri를 이용한 과불화합물과 중금속의 복합독성평가)

  • Lee, Woo-Mi;Kim, Ji-Sung;Kim, Il-Ho;Kim, Seog-Ku;Yoon, Young-Han
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.2
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    • pp.119-126
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    • 2014
  • The object of this study was to evaluate the combined toxic interactions of the perfluorooctanoic acid (PFOA) or perfluorooctane sulfonate (PFOS) with six heavy metals (Cu, Zn, Cr, Cd, Hg, and Pb). The individual and combined toxic effects were assessed using the Vibrio fischeri assay. In case of the individual toxicity, PFOA was higher toxic than PFOS and toxicity of PFOA and PFOS were lower than heavy metal. In the toxicity of heavy metals, the $Hg^{2+}$ was found to be most toxic followed by $Pb^{2+}$, $Cr^{6+}$, $Cu^{2+}$, $Zn^{2+}$, and $Cd^{2+}$. The combined toxicity of PFOA or PFOS with $Cr^{6+}$ were synergistic effect because the $EC_{50}$ mix values were less than 1 TU. PFOA + $Zn^{2+}$, PFOS + $Zn^{2+}$, PFOA + $Cd^{2+}$ and PFOS + $Cd^{2+}$ produced addictive effect. Except in these case, all of binary mixtures show antagonistic effect. This study proved potential risk of coexistent with perfluorinated compounds and heavy metals in water environment.

Toxicity Evaluation of Complex Metal Mixtures Using Reduced Metal Concentrations: Application to Iron Oxidation by Acidithiobacillus ferrooxidans

  • Cho, Kyung-Suk;Ryu, Hee-Wook;Choi, Hyung-Min
    • Journal of Microbiology and Biotechnology
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    • v.18 no.7
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    • pp.1298-1307
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    • 2008
  • In this study, we investigated the inhibition effects of single and mixed heavy metal ions ($Zn^{2+},\;Ni^{2+},\;Cu^{2+},\;and\;Cd^{2+}$) on iron oxidation by Acidithiobacillus ferrooxidans. Effects of metals on the iron oxidation activity of A. ferrooxidans are categorized into four types of patterns according to its oxidation behavior. The results indicated that the inhibition effects of the metals on the iron oxidation activity were noncompetitive inhibitions. We proposed a reduced inhibition model, along with the reduced inhibition constant ($\alpha_i$), which was derived from the inhibition constant ($K_I$) of individual metals and represented the tolerance of a given inhibitor relative to that of a reference inhibitor. This model was used to evaluate the toxicity effect (inhibition effect) of metals on the iron oxidation activity of A. ferrooxidans. The model revealed that the iron oxidation behavior of the metals, regardless of metal systems (single, binary, ternary, or quaternary), is closely matched to that of any reference inhibitor at the same reduced inhibition concentration, $[I]_{reduced}$, which defines the ratio of the inhibitor concentration to the reduced inhibition constant. The model demonstrated that single metal systems and mixed metal systems with the same reduced inhibitor concentrations have similar toxic effects on microbial activity.

Preparation of Energetic Metal Particles and Their Stabilization (에너제틱 금속입자 제조 및 안정화 기술)

  • Lee, Hye Moon;Kim, Kyung Tae;Yang, Sangsun;Yu, Ji-Hun;Kim, Yong-Jin
    • Particle and aerosol research
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    • v.9 no.3
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    • pp.173-185
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    • 2013
  • Oxidations of metal generate large quantity of thermal and light energies but no toxic pollutants, so that metals with high calorific values, such as beryllium, boron, aluminum, magnesium, and lithium, are possible to be used as clean fuels instead of fossil fuels. However, they are so explosive due to very high oxidation rates that they should be stabilized by their surface passivation with oxides, organics and inorganics. For reasonable use of energetic metal particles as solid fuel, therefore, some detail information, such as thermal properties, preparation and passivation methods, and application area, of the energetic metals is introduced in this manuscript.

Influence of Nickel Electroplating on Hydrogen Chloride Removal of Activated Carbon Fibers

  • Park, Soo-Jin;Jin, Sung-Yeol;Ryu, Seung-Kon
    • Carbon letters
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    • v.5 no.4
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    • pp.186-190
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    • 2004
  • In this work, a nickel metal (Ni) electroplating on the activated carbon fiber (Ni/ACFs) surfaces was carried out to remove the toxic hydrogen chloride (HCl) gas. The surface properties of the treated ACFs were determined by using nitrogen adsorption isotherms at 77 K, SEM, and X-ray diffraction (XRD) measurements. HCl removal efficiency was confirmed by a gas-detecting tube technique. As a result, the nickel metal contents on the ACF surfaces were increased with increasing the plating time. And, it was found that the specific surface area or the micropore volume of the ACFs studied was slightly decreased as increasing the plating time. Whereas, it was revealed that the HCl removal efficiency containing nickel metal showed higher efficiency values than that of untreated ACFs. These results indicated that the presence of nickel metal on the ACF surfaces played an important role in improving the HCl removal over the Ni/ACFs, due to the catalytic reactions between nickel and chlorine.

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Physico-mechanical properties and prosthodontic applications of Co-Cr dental alloys: a review of the literature

  • Al Jabbari, Youssef S.
    • The Journal of Advanced Prosthodontics
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    • v.6 no.2
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    • pp.138-145
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    • 2014
  • Cobalt-Chromium (Co-Cr) alloys are classified as predominantly base-metal alloys and are widely known for their biomedical applications in the orthopedic and dental fields. In dentistry, Co-Cr alloys are commonly used for the fabrication of metallic frameworks of removable partial dentures and recently have been used as metallic substructures for the fabrication of porcelain-fused-to-metal restorations and implant frameworks. The increased worldwide interest in utilizing Co-Cr alloys for dental applications is related to their low cost and adequate physico-mechanical properties. Additionally, among base-metal alloys, Co-Cr alloys are used more frequently in many countries to replace Nickel-Chromium (Ni-Cr) alloys. This is mainly due to the increased concern regarding the toxic effects of Ni on the human body when alloys containing Ni are exposed to the oral cavity. This review article describes dental applications, metallurgical characterization, and physico-mechanical properties of Co-Cr alloys and also addresses their clinical and laboratory behavior in relation to those properties.

Research Trends in Heavy-Metal-Free Quantum Dot Sensitized Solar Cells (무독성 양자점 감응형 태양전지 연구동향)

  • Kim, Jae-Yup;Ko, Min Jae
    • Current Photovoltaic Research
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    • v.3 no.4
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    • pp.126-129
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    • 2015
  • Over the last two decades, quantum dot (QD) solar cells have attracted much attention due to the unique properties of QDs, including band gap tunability, slow hot electron cooling, and multiple exiton generation effect. However, most of the QDs employed in photovoltaic devices contain toxic heavy-metals such as cadmium or lead, which may limit the commercial application. Therefore, recently, heavy-metal-free QDs such as Cu-In-S or Cu-In-Se have been developed for application in solar cells. Here, we review the research trends in heavy-metal-free QD solar cells, mainly focusing on Cu-In-Se QD-sensitized solar cells (QDSC).

Studies on Mechanisms of Copper Metabolism Using Comparative Models

  • Lee, Jaekwon
    • Proceedings of the Korean Society of Toxicology Conference
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    • 2003.10b
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    • pp.33-33
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    • 2003
  • Organisms have evolved to use metal ions as cofactors for many proteins involved in critical biological processes. However, these metals are highly toxic when present in excess or if released in its free reactive form, and environmental contamination by non-physiological metals has been a concern for public health.(omitted)

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Studies on Cd and Removal Ability and Detoxification of Oenanthe stolonifera (미나리 ( Oenanthe stolonifera ) 의 Cd, Zn 제거능과 내성에 관한 연구)

  • Lee Soo;In Sook Lee
    • The Korean Journal of Ecology
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    • v.19 no.6
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    • pp.519-527
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    • 1996
  • To examine the possibility of biomonitoring of heavy metal removal ability and soil, a study was performed to investigate the heavy metal removal ability and metal-binding protein (MBP) as detoxification process using Oenanthe stolonifera. After O. stolonifera was exposed to individuals (cadmium, zinc) and mixture (cadmium+zinc)for 4 days, removal rate of heavy metal and pH in the treatment medium was measured. MBP was assayed by means of ion exchange column chromatography. The exposure to mixture (Cd:76.8%, Zn:75%) rather than individuals (Cd:82.9%, Zn:90.4%) showed a synergism raising the toxic effect. Initial removal rate was different for each heavy metal : in case of exposure to cadmium it was over 60% on day 1, while for zinc it was 75~90% on day 4. Throughout the experimental period, pH value of treatment medium continuously decreased, since cortex in the roots may secret organic acid to adjust and prevent toxicity of metals. The existence or MBP in the 70~80 fraction and the presence of Zn-enzyme pool was ascertained with the column chromatography. This study demonstrated a possibility that heavy utilized as a biomarker of heavy metal pollution.

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