• 한국안전학회지
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• 제6권1호
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• pp.26-30
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• 1991

Flammability, and released toxic halogen gases during combustion about two kinds of flame-retardant flexible foam(F.R. flexible PV foam) were investigated. One of the above was F.R. flexible PU foam with the containment of halogen and the other was manufactured with pure flexible PU foam in aqueous solution of alumina trihydrate(ATH) and dried 4 hours at 10$0^{\circ}C$. Flammability by L.O.I and UL94 HF-1 of the two materials were similarly shown. And combustion gases were analyzed with GC-Mass. HCI, CI$_2$ and HF were detected at both halogen being contained F.R. flexible PU foam and ATH dolng one The reason, to find halogen gases from burning ATH-containing F, R. flexible PU foam which wasn't used for any halogenated F.R., could be considered as by using trichlorofluoromethane with blowing agent to make PU foam. The relative quanity of relesed halogen gases of F.R. flexible PU foam with the containment of halogen had been indicated tree times HCI and CI$_2$, two times HF than ATH containing, respectively.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2005년도 추계학술대회 논문집
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• pp.1254-1260
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• 2005

The advanced country established the test standard (e.g., BS, EN) to measure the toxic gases quantitatively and, have applied to enhance the fire safety of railway car. We must also follow the procedures to use interior material for railway car as stated the Safety regulation for the urban railway car. Currently, various interior materials are used to obtain the fire safety of railway car. The amount of toxic gases moved into the FT-IR gas cell via sampling line from the ISO 5659 chamber using cone heater was measured and compared the results for each materials.

• 한국안전학회지
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• 제32권2호
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• pp.72-77
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• 2017

In S. Korea, recently, building fire accidents of residential accommodations or recreational facilities have taken place more frequently than before. Among various building constructions, Multi-layered structure, such as office-residential complex, are mostly made in S. korea. $O_2$, $CO_2$, CO, $NO_x$, $SO_x$, and HCl, these gases has toxic hazard and harmful for human body. And it is predicted that different concentration of released gases from diesel pool fire with upper and lower layer. Therefore, this study reports the fire characteristics of Multi-layered structure by analyzing the fire behavior and concentration of combustion gases of a experimental compartment via real scale fire experiment, in order to predict risks and secure safety for similar fire accidents.

• 한국대기환경학회지
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• 제15권2호
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• pp.151-158
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• 1999

Offsite consequences resulting form worst-case scenarios involving release of toxic substances in the Yochon area were estimated using the ALOHA(Areal Locations of Hazardous Atmospheres) model. Eight toxic substances, including NH3, were considered; five were toxic gases and three were toxic liquids at ambient temperature. For toxic gases, the entire quantity was assumed to be released at a constant rate during a 10-minute period. For toxic liquids, the entire quantity stored in the tank was assumed to be spilled and spread and spread instantaneously to form a pool with a depth of 1cm, and then evaporated over some period of time. Except for phosgene and toluene 2,4-diisocyanate, for which concentration levels corresponding to human health effects are very low, average distances of the area at risk of adverse health effects for a 1- tom release were predicted to be $2.3{\pm}1.1 km$ for the worst-case meteorological conditions and $0.93{\pm}0.69km$ under typical meteorological conditions of the Yochon are. Because a large number of people were predicted to be affected in the current analysis, refined analyses considering both realistic accident scenarios and topographic effects were warranted.

• 한국화재소방학회논문지
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• 제32권5호
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• pp.52-56
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• 2018

화재로 인한 피해는 열상에 의한 피해보다는 연소 독성에 의한 피해가 치명적이며, 인명피해를 줄이기 위해 화재 상황에서 젖은 수건을 사용하여 화재로부터 발생되는 독성가스를 방호하도록 권장하고 있다. 본 연구에서는 젖은 수건을 통해 실제 화재에서 발생되는 가스를 대상으로 필터링 효과를 정량화하였다. 화재가스 중 세 가지 가스($CO_2$, HCl, HCN)를 대상으로 젖은 수건의 필터효과를 확인하기 위해 FT-IR을 이용하여 필터를 통과한 가스를 실시간 분석을 하였으며, 물에 잘 녹지 않는 $CO_2$에 비해 유독가스이며, 수용성 가스인 HCl, HCN은 젖은 수건에 의해 가스가 필터링 되면서 가스 검출 시점이 지연됨을 확인하였다. 따라서 실제 화재 시 독성가스 중 특히 수용성 가스의 경우 젖은 수건을 이용하게 되면 일정 시간 피난 시간을 확보할 수 있음을 확인하였다.

• 한국가스학회지
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• 제19권6호
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• pp.92-98
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• 2015

독성가스는 고압가스안전관리법에 의해 관리된다. 독성가스는 "고압가스안전관리법에서 규정한, 31종의 가스와 $LC_{50}$이 5000 ppm 이하인 가스"이다. 전자산업의 발달에 따라 우리나라 독성가스 사용량은 폭발적으로 증가하였다. 이에 국내 대학교 실험실의 독성가스 관련 연구 수요도 함께 증가해 왔다. 그러나 국내 실험실 독성가스 안전관리와 관련한 연구는 전무한 상태이다. 본 연구에서는 국내 대학 실험실의 실태조사를 통해 독성가스 안전관리에 있어서의 약점들을 파악하였다. 이 같은 약점을 극복하기 위해 독성가스 안전관리 방안을 제시하였다. 또한 제시된 방안에 따라 독성가스 시설이 안전하게 관리되는지를 확인하고, 이를 통한 개선을 위해 표준 체크리스트를 개발하였다. 이 연구 결과는 국내 대학 실험실에서 독성가스 시설의 안전관리를 강화할 것이며, 이를 모든 실험실에 대한 안전 지침으로 제공한다.

• 한국화재소방학회논문지
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• 제27권5호
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• pp.44-56
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• 2013

한국기준 표준화된 A급 목재 및 B급 유류 화재 시험에서 룸코너시험기(RCT)를 사용하여 연소유독가스의 생성을 정량적으로 알아보고, 시험자들에게 미치는 인체유해성을 확인하였다. 그 결과 A급의 경우 유독가스가 시험자들에 직접적으로 노출되는 초기 3분 동안, 분당호흡량(RMV) 2단계에서 40% 카복시헤모글로빈(COHb)가 넘어가는 경우는 A급 9, 10단위에 해당하며, RMV 3단계에서 A급 5~10 단위까지가 모두 40% COHb을 초과함을 확인하였다. 한편 B급의 경우 유독가스가 시험자에게 직접 노출되는 초기 1분 동안은 A급에 비해 다소 안전하나 총 연소시간에는 RMV 3단계에서 B급 16~20 단위까지가 모두 20% COHb을 초과한 수치가 나옴을 확인하였다. 따라서 이 연구에서는 시험자들은 소화시험의 단위수를 고려하여 자급 호흡보조기나 그와 동일한 기능의 장치를 착용하는 규정을 제안한다.

• 분석과학
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• 제8권4호
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• pp.731-738
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• 1995

Toxic air pollutants are investigated in a petrochemical industrial park in Taiwan by using a movable open path FTIR. The results show the qualitative and quantitative analysis of emission gases from plants, and also provide the emission rate of different compounds. More than twenty compounds under usual operation are found from this industrial park. The concentration variation with time can be correlated exactly with wind direction. It means that by changing the measuring points, the source of emission can be unambiguously identified. An EPA proved PAL model is applied to estimate the emission rate of either a point or an area source. Local atmospheric stability is determined by releasing the $SF_6$ tracer. The origins of errors come mainly from the uncertainty of source's configuration and the variation of meteorological condition. Through the continuous measurement (half an hour base in this study) of OP-FTIR sensor, the maximum value of emission rate and the annual amount of emission can be derived. The emission rate of the measured toxic gases are derived by the model technique and the results show that the emission amount are in the order of ten to hundred tons per year.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2008년도 춘계학술대회 논문집
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• pp.2213-2217
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• 2008

The important factor is keeping the temperature condition in quantifying several toxic components in combustion gases. In case of not keeping the temperature as it was in combustion, the change of component and concentration of smoke gases was inevitable. To solve this problem, FT-IR spectroscopy with gas cell was applied. But, there is also a difficulty in quantitative analysis of specific toxic component because of water vapor. Thus, in this study, water vapor FT-IR spectra with different concentrations were obtained and applied them to quantitative analysis.

• 한국세라믹학회지
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• 제55권5호
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• pp.473-479
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• 2018

Highly toxic gases such as hydrogen sulfide ($H_2S$), carbon dioxide ($CO_2$), and ammonia ($NH_3$) are generated by both nature and human activities and affect human health. In this research, activated carbon combined with $Ca(OH)_2$ and $CaCO_3$ (AC-CO and AC-CC, respectively) were fabricated and applied in absorbing toxic gases from air pollutants. Activated charcoal powder was compressed in the form of pellets and used in the designated conditions. The optimum operating conditions and material properties, such as adsorption capacity, effect of weight ratio of the mixture, and hardness, have been investigated after combining with the calcium derivative. The good performance exhibited in this study suggests that this material is expected to be an effective and economically viable adsorbent for $NH_3$, $CO_2$, and $H_2S$ removal from the air system.