• Title/Summary/Keyword: Toxic gas

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Properties and Development of Halogen Free Flame Retardant Cable (Halogen Free 난연 케이블의 제특성 및 개발)

  • Choi, W.K.;Choi, W.;Seo, S.J.;Yang, H.J.;Won, J.H.
    • Proceedings of the KIEE Conference
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    • 1992.07b
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    • pp.768-770
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    • 1992
  • Conventional flame retardant cable using PVC or CR materials generate considerable amount of toxic and acidic gas (HCI etc.) together with excessive black smoke during a fire. The newly developed halogen free materials have dissolved the problem of halogen acid gases. This paer describes the development of this power cable insulation and sheath, using halogen free materals.

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Determination of Toxic Elements in Blood by Inductively Coupled Plasma Mass Spectrometry

  • Park, Chang-Jun
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.3 no.1
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    • pp.99-99
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    • 1993
  • 혈액 및 생체시료 중 필수원소 혹은 독극성 원소의 극미량상분 정밀측정과 동위원소비율측정에 널리 사용되는 유도결합플라즈마 질량분석기(ICP-MS)의 기본원리를 소개하고 ICP-SM를 이용한 혈액중 낮은 ppb수준의 Cd, Hg 그리고 Pb의 정밀분석법을 소개한다. 혈액은 많은 양의 유기물을 포함하고 있으므로 digestion bomb에 질산과 과산화수소를 넣어 microwave oven에서 고온고압 상태로 분해시켜 많은 용액을 얻어 이 용액을 플라즈마에 주입시켜 분석한다. 그리고 수온은 tin(II) chloride 용액을 환원제로하여 생성시킨 수은원소증기를 membrane liquid-gas separator를 이용하여 뽑아내어 플라즈마에 주입시켜 낮은 ppt 수준의 검출한계를 얻는다. 또한 높은 정밀도와 정확도와 극미량 원소 측정에 사용되는 동위원소 회석법율 소개하고 실제 혈액분석에의 응용방법을 제시한다.

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Evaluation of the Measurement of Trace Phenols by Adsorption/Thermal Desorption/Gas Chromatography/Mass Spectrometry (ATD/GC/MS) in Artificial Air (흡착관/열탈착 GC/MS 방법에 의한 모사시료 중의 미량 페놀 분석에 관한 평가)

  • 허귀석;이재환;황승만;정필갑;유연미;김정우;이대우
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.2
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    • pp.127-137
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    • 2002
  • Phenolic compounds in air are toxic even at their low concentrations. We had evaluated a total of five phenolic compounds (Phenol, o-Cresol, m-Cresol, 2-Nitrophenol and 4-Chloro-3-methylphenol) in artificial air using a combination of ATD/GC/MS. To compare the adsorption efficiency of these phenolic compounds, three adsorbents (Tenax TA, Carbotrap and Carbopack B) were tested. Tenax TA adsorbent was most effective of all the adsorbents used for the efficiency test. Five phenolic compounds were found to be very stable on adsorbent tubes for 4 days at room temperature. Detection limit of five phenolic compounds ranged from 0.05 to 0.08 ppb (when assumed to collect 10 L air). The calibration curve was linear over the range of 22∼ 164 ng. The reproducibility was less than 4%. Sampling of duplicate pairs (DPs) was made to demonstrate duplicate precision and sampling efficiency.

Gaseous by-products from the TiO2 Photocatalytic Oxidation of Benzene

  • Han, Sang-Wook;Lee, Jin-Hong;Kim, Jin-Seog;Oh, Sang-Hyub;Park, Young-Kwon;Kim, Hyun-Ook
    • Environmental Engineering Research
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    • v.13 no.1
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    • pp.14-18
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    • 2008
  • Photocatalytic oxidations of benzene gas using the closed system (batch reactor) were induced to determine its by-products and investigate the effect of humidity and oxygen concentration on their generation. The study was able to identify 11 gaseous by-products: 2-methylpropene, acetaldehyde, acetone, pentane, methylcyclobutane, methylcyclopentane, cyclohexane, 2,3-dimethylbutane, 2-methylpentane, 3-methylpentane, and hexane. All the by-products were saturated hydrocarbons, which are less toxic than benzene and were probably formed through hydrogenation reaction on the photocatalytic surface. The photocatalytic oxidation of benzene under higher humidity produced less by-products. However, the amount of acetone released increased with higher humidity and oxygen concentration.

A Study on Surface properties of Cr-Mo-V Steel by Eco-friendly Salt Bath Nitriding Treatment (Cr-Mo-V강의 친환경 염욕질화처리에 의한 표면특성 연구)

  • Jung, Gil-Bong
    • Journal of the Korea Institute of Military Science and Technology
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    • v.13 no.2
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    • pp.275-282
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    • 2010
  • The improved properties of surface layer can be achieved by so-called "new salt bath nitriding(NSBN)", which has been developed by a domestic company. This process based upon modified traditional salt bath nitriding process, increased hardenability with minimum toughness deterioration. This process also offers not only less white layer surfaces but also more eco-friendly one. That is, NSBN is the new eco-friendly surface treatment technology removing harmful $CN^-$ and toxic gas. According to the research of applying NSBN to Cr-Mo-V steel which has been used in defense industry, showed the improved result of wear resistance and surface hardening than non-coated condition. In further, we expect NSBN to curtail expenses and productivity improvement applied to the various defense industry parts.

Synthesis of the $CaGa_2S_4:Eu^{2+}$ phosphors and Application in White LEDs

  • Kim, Jae-Myung;Kim, Kyung-Nam;Park, Joung-Kyu;Kim, Chang-Hae;Jang, Ho-Gyeom
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1623-1626
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    • 2005
  • The thiogallate phosphors which are well known for a long time as phosphor materials for CRT or EL device were reported. Those have high luminescent properties at long-wavelength region. Among those phosphors, the samples with divalent europium doped CaGa2S4 were prepared by a simple process under the reduction atmosphere $(5%\;H_2/\;95%\;N_2)$ without toxic gas such as H2S or CS2. The prepared phosphor shows a higher luminescent efficiency (about 120%) than that of $YAG:Ce^{3+}$ phosphor. Consequently, this phosphor is possible to be applicable to white LED lamp because of the high luminescent efficiency.

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A Study of Fire-resistance Light-weight Inorganic Foam Material Using Cullet and Fly-ash (유리분말과 플라이애시를 사용한 내화성 경량 무기발포 소재 연구)

  • Shin, Hyeon-Uk;Song, Hun;Chu, Yong-Sik;Lee, Jong-Kyu
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.11a
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    • pp.79-81
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    • 2011
  • To prevent energy waste in buildings used heat insulator. Heat insulator materials can be classified inorganic and organic. The organic material is due to toxic gas emission, when a fire occurs. And it has lower water resistance. The inorganic material is heavy and worse thermal performance than organic materials. This study focused on evaluation of the physical properties and fire-resistance of inorganic foam material for using industrial by-products materials for the applicability of Fire-resistance Light-weight material.

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The study of Taxonomy of Performance Shaping Factors for Human Error Management (인적오류 관리를 위한 수행영향인자 분류에 관한 연구)

  • Jung, Kyung-Hee;Cho, Jai-Rip
    • Proceedings of the Korean Society for Quality Management Conference
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    • 2010.04a
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    • pp.157-160
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    • 2010
  • Almost all companies have paid much attention to the safety management ranging from maintenance to operation even at the stage of designing in order to prevent accidents, but fatal accidents continue to increase throughout the world. In particular, it is essential to systematically prevent such fatal accidents sa fire, explosion or leakage of toxic gas at factories in order to not only protect economic losses and environmental pollution. In addition, HRA may be used to detect the human errors which may cause accidents or trace back to any mistake on the part of workers. This work focuses on the coincidence of human error and mechanical failure for management of human error, and on some important performance shaping factors to propose a method for improving safety effectively of the process industries.

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Comparison of combustion gas release for FRP and seat cover materials to the Furnace temperature (연소온도 조건에 따른 FRP 및 시트커버 내장재의 연소가스 발생량 비교)

  • Lee, Duck-Hee;Jung, Woo-Sung;Lee, Cheul-Kyu;Yu, Mun-Chun
    • Proceedings of the KSR Conference
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    • 2007.05a
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    • pp.1527-1532
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    • 2007
  • We have evaluated the toxicity of interior materials for the railway passenger car by checking the release of $CO_2$, CO, NOx, SO2, HCl, HF, HBr, HCN. The NOx is one of the most effective for the determination of Toxic Index R value. It is generally known that the mechanism of thermal NOx generation without the Interior Material nitrogen source. This study started from the idea to check the NOx difference according to the furnace temperature. But from the results, it was revealed that NOx is not so sensitive for the furnace temperature in case of solid burning. Other gases such as HCN, CO were more changeable to the furnace Temp. We reported the test result as for toxicity index r(x).

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Classification of Hazard Events and Causes for Railway Fire Accident (열차 화재안전성 향상을 위한 위험사건 정의 및 원인분류 연구)

  • Kwak, Sang-Log;Wang, Jong-Bae;Park, Chan-Woo;Park, Joo-Nam
    • Proceedings of the KSR Conference
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    • 2007.05a
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    • pp.1163-1167
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    • 2007
  • Many railway safety measures are carried out after Daegue subway fire accident. Such as replacement of train interior material, fire extinguish and toxic gas evacuation facilities, exercise on emergency response, setting up of national safety management system, and safety technology research. But these safety measures are not considered by system safety due to lack of risk and hazard information. In order to assess fire risk on system level, we proposed hazard events and causes classification for railway fire accident risk analysis.

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