• Journal of the Korean Ceramic Society
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• v.30 no.11
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• pp.881-890
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• 1993

MAS system has narrow sintering temp. range due to the liquid phae sintering and thereby densify rapidly. And especially, its poor mechanical properties limitedthe industrial application. In this study, the improvement of mechanical properties and densification is suggested by the consideration of the toughening mechanisms and isolated pore generation mechanism which is derived by the liquid phase sintering theory in 3Y-TZP added composites. After Pressureless sintering up to 140$0^{\circ}C$ for 5hr, the dihedral angle and contact angle are analyzed by the observation of microstructure. As a result of microstructure analysis, the sintering stage of the specimen sintered for 5hr is analyzed as solid-skeleton stage. And the isolated pore generation mechanisms are considered as (1) The swelling of the liquid phase is predominent due to the facts that dihedral angle is larger than 60$^{\circ}$, contact angle is large and that liquid volume fraction is smaller than 10%. (2) The porous characteristics of the MAS system is also suggested as: the SiO2-rich liquid film is firstly formed at the srface and therefore this reduces the contiguity of the pore, which induces the isolated pore. The strength and fracture toughness increased with the addition of 3Y-TZP and the main fracture toughness improvement mechanisms are analyzed as the crack deflection.

• Steel and Composite Structures
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• v.31 no.2
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• pp.113-123
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• 2019

In this study, carbon fiber/epoxy (CF/EP) composites were interleaved with aramid nonwoven veils with an areal weight density of $8.5g/m^2$ to improve their Mode-I fracture toughness. The control and aramid interleaved CF/EP composite laminates were manufactured by VARTM in a [0]4 configuration. Tensile, three-point bending, compression, interlaminar shear, Charpy impact and Mode-I (DCB) fracture toughness values were determined to evaluate the effects of aramid nonwoven fabrics on the mechanical performance of the CF/EP composites. Thermomechanical behavior of the specimens was investigated by Dynamic Mechanical Analysis (DMA). The results showed that the propagation Mode-I fracture toughness values of CF/EP composites can be significantly improved (by about 72%) using aramid nonwoven fabrics. It was found that the main extrinsic toughening mechanism is aramid microfiber bridging acting behind the crack-tip. The incorporation of these nonwovens also increased interlaminar shear and Charpy impact strength by 10 and 16.5%, respectively. Moreover, it was revealed that the damping ability of the composites increased with the incorporation of aramid nonwoven fabrics in the interlaminar region of composites. On the other hand, they caused a reduction in in-plane mechanical properties due to the reduced carbon fiber volume fraction, increased thickness and void formation in the composites.

• Korean Journal of Metals and Materials
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• v.47 no.1
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• pp.50-58
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• 2009

In this study, alumina matrix composites reinforced with carbon nanotubes (CNTs) were fabricated by ultrasonic dispersion, ball milling, mixing, compaction, and sintering processes, and their relative density, electrical resistance, hardness, flexure strength, and fracture toughness were evaluated. 0~3 vol.% of CNTs were relatively homogeneously dispersed in the composites in spite of the existence of some pores. The three-point bending test results indicated that the flexure strength increased with increasing volume fraction of CNTs, and reached the maximum when the CNT fraction was 1.5 vol.%. The fracture toughness increased as the CNT fraction increased, and the fracture toughness of the composite containing 3 vol.% of CNTs was higher by 40% than that of the monolithic alumina. According to observation of the crack propagation path after the indentation fracture test, a new toughening mechanism of grain interface bridging-induced CNT bridging was suggested to explain the improvement of fracture toughness in the alumina matrix composites reinforced with CNTs.

• Steel and Composite Structures
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• v.44 no.6
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• pp.817-828
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• 2022

In this study, considering dissipated energy in fracture process zone (FPZ), a novel criterion based on maximum strain energy release rate (SER) for orthotropic materials is presented. General case of in-plane loading for cracks along the fibers is assumed. According to the experimental observations, crack propagation is supposed along the fibers and the reinforcement isotropic solid (RIS) concept is employed as a superior model for orthotropic materials. SER in crack initiation and propagation phases is investigated. Elastic properties of FPZ are extracted as a function of undamaged matrix media and micro-crack density. This criterion meaningfully links between dissipated energy due to toughening mechanisms of FPZ and the macroscopic fracture by defining stress intensity factors of the damaged zone. These coefficients are used in equations of maximum SER criterion. The effect of crack initiation angle and the damaged zone is considered simultaneously in this criterion and mode II stress intensity factor is extracted in terms of stress intensity factors of damage zone and crack initiation angle. This criterion can evaluate the effects of FPZ on the fracture behavior of orthotropic material. Good agreement between extracted fracture limit curves (FLC's) and available experimental data proves the ability of the new proposed criterion.

• Structural Engineering and Mechanics
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• v.89 no.2
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• pp.135-153
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• 2024

In this study, the impact response of a nanobeam with a moving nanoparticle is investigated. Timoshenko beam theory is used to model the nanobeam behavior and nonlocal elasticity theory is used to consider the effects of small dimensions. The interaction between the nanoparticle and nanobeam has been described using Lennard-Jones potential theory and the equations are discretized by the radial basis meshless method and a mathematical model is presented for the nanobeam-nanoparticle system. Validation of the proposed model is achieved by comparing the obtained natural frequencies with reference values, demonstrating good agreement. Dimensionless frequency analysis reveals a decrease with increasing nonlocal parameter, pointing out a toughening effect in nanobeam. The dynamic response of the nanobeam and nanoparticle is obtained by time integration of equations of motion using Newmark and Wilson-𝜃 methods. A comparative analysis of the two methods is conducted to determine the most suitable approach for this study. As a distinctive aspect in this study, the analysis incorporates the deformation of the nanobeam resulting from the nanoparticle-nanobeam interaction when calculating the Lennard-Jones force in the nanobeam-nanoparticle system. The numerical findings explore the impact of various factors, including the nonlocal parameter, initial velocity, nanoparticle mass, and boundary conditions.

• The Korean Journal of Rheology
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• v.11 no.1
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• pp.50-56
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• 1999

Melt blends of polyamide 6 (PA 6) with polyester elastomer (PEL) were prepared in a corotating twin screw extruder using two types of coupling agent(CA), viz. diglycidyl ether of bisphenol A (DGEBA) and 1,4-phenylene bis(2-oxazoline) (PBO). Notched impact strength of PA 6 as well as PA 6/PEL blends increased with the addition of coupling agent, especially with DGEBA and the maximum impact toughening of the blend was obtained with 0.6%(by mol) DGEBA, where a minimum domain size was observed from SEM. Melt viscosities of the untreated blends were higher than those of base resins at low frequencies. Viscosities of base resins as well as blends increased with the addition of CA, and the effect was much more pronounced with DGEBA, especially for PA 6 and PA 6-rich blends.

• Polymer(Korea)
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• v.36 no.6
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• pp.745-755
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• 2012

Two types of polymers were tested in this study; poly(ethylene terephthalate) (PET) as a synthetic example and poly(lactic acid) (PLA) as a natural polymer. DSC analyses showed that the use of nanofiller increased the degree of crystallinity ($X_c$) of both PET and PLA polymers, but the effect was more noticeable on PET nanocomposites. The crystallization of PLA and PET nanocomposites occurred at higher temperatures in comparison to neat polymers. According to dynamic mechanical-thermal analysis (DMTA), the damping factor of PET/$TiO_2$ nanoparticles decreased compared to the neat matrix, but for PLA nanocomposites the opposite trend was observed. Results of the mechanical test showed that for both PET and PLA nanocomposites, the most successful toughening effect was observed at 3 wt% loading of $TiO_2$ nanoparticles. SEM micrographs revealed uniform distribution of $TiO_2$ nanoparticles at 1 and 3 wt% loading levels. The results of WAXD spectra explained that the polymorphs of PLA and PET was not affected by $TiO_2$ nanoparticles. UV-visible spectra showed that $TiO_2$ nanocomposite films had high ultraviolet shielding compared to neat polymer, but there was significant reduction in transparency.

• Applied Chemistry for Engineering
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• v.10 no.5
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• pp.711-717
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• 1999

A multilayer-structure material containing ductile and brittle layer simultaneously was examined and compared with a single layer material using fracture mechanical properties. We found that impact strength of multilayer structure material was considerably higher than single layer's and toughness was enhanced by about two times or higher in similar glass transition temperature($T_g$) region and the same dimension. The superposition principle of impact pulse was used for interpretation of kinetic stress wave as a high-velocity crack proceeds in the plastic. It was understood that the optimum condition of ductile/brittle thickness ratio could be designed in the final toughness enhancement of multilayer.

• The Korean Journal of Ceramics
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• v.3 no.2
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• pp.116-123
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• 1997

A chemically stabilized $\beta$-cristobalite, which is stabilized by stuffing cations of $Ca^{2+}$ and $Al^{3+}$, was prepared by a solution-polymerization route employing Pechini resin or PVA solution as a polymeric carrier. The polymeric carrier affected the crystallization temperature, morphology of calicined powder, and particle size distribution. In case of the polyvinyl alcohol (PVA) solution process, a fine $\beta$-cristobalite powder with a narrow particle size distribution (average particle size : 0.3$\mu\textrm{m}$) and a BET specific surface area of 72 $\m^2$/g was prepared by an attrition-milling for 1 h after calcination at 110$0^{\circ}C$ for 1h. Wider particle size distribution and higher specific surface area were observed for the $\beta$-cristobalite powder derived from Pechini resin. The cubie(P1-to-tetraganalb) phase transformation in polynystalline $\beta$-cristobalite was induced at approximately 18$0^{\circ}C$. Like other materials showing transformation toughening, a critical size effect controlled the $\beta$-to-$\alpha$ transformation. Densifed cristobalite sample had some cracks in its internal texture after annealing. The cracks, occurred spontaneoulsy on cooling, were observed in the sample with an average grain sizes of 4.0 $\mu\textrm{m}$ or above. In case of the sintered cristobalite having a composition of CaO.$2Al_2O_3$.40SiO$_2$, small amount of amorphous phase and slow grain growth during annealing were observed. Shear stress-induced transformation was also observed in ground specimen. Cristobalite having a composition of CaO.2Al2O3.80SiO2 showed a more sensitive response to shear stress than the CaO.$2Al_2O_3$.40SiO$_2$ type cristobalite. Shear-induced transformation resulted in an increase of volume about 13% in $\alpha$-cristobalite phase on annealing for above 10 h in the case of the former composition.

• Composites Research
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• v.16 no.4
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• pp.44-50
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• 2003

The damage zone around a crack tip occurring before the fracture is a significant domain. which affects the toughening mechanism of materials. In this study. the growth process of damage zone in the vicinity of crack tip for rubber-modified epoxy resin is investigated using an acoustic emission(AE) analysis. The weight fractions of rubber(CTBN 1300$\times$B) in rubber-modified epoxy resin are 5 wt% and 15 wt%. The fracture toughness($K_{IC}$) and the fracture energy($G_{IC}$) were measured using 3 point bending single-edge notched specimens. The damage zone and rubber particles distributed around the crack tip were observed by a polarized optical microscope and an atomic force microscope(AFM). The damage zone around crack tip of rubber-modified epoxy resin was formed at 13 % loading and developed until 57 % loading of the fracture load. The crack initiated at 57 % loading grew repeatedly in the stick-slip propagation behavior. Based on time-frequency analysis, it was confirmed that AE signals with frequency bands of 0.15~0.20 MHz and 0.20~0.30 MHz were generated from cavitation and stable/unstable cracking inside the damage zone.