• 제목/요약/키워드: Total porosity

검색결과 282건 처리시간 0.025초

3D Printing of Biocompatible PM-materials

  • Dourandish, Mahdi;Godlinski, Dirk;Simchi, Abdolreza
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.252-253
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    • 2006
  • The fabrication of complex-shaped parts out of Co-Cr-Mo alloy and 316L stainless steel by three-dimensional printing (3DP) was studied using two grades of each alloy with average particle size of 20 and $75\;{\mu}m$, respectively. To produce sound specimens, the proper 3DP processing parameters were determined. The sintering behavior of the powders was characterized by dilatometric analysis and by batch sintering in argon atmosphere at $1280^{\circ}$ for 2h. The 3DP process has successfully produced complex-shaped biomedical parts with total porosity of 12-25% and homogenous pore structure, which could be suitable for tissue growth into the pores.

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초음파를 적용한 PET 직물의 알칼리 가수분해에 관한 연구(II) - 기공특성과 올리고머 분석 - (A Study on the Alkali Hydrolysis of PET fabrics with Ultrasonic Application(II)- Surface Porosity and Oligomer Analysis -)

  • 김삼수;서말용;박성우;윤태희;이승구;허만우
    • 한국염색가공학회지
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    • 제14권6호
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    • pp.305-312
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    • 2002
  • In order to give a silk-like touch to PET fabrics, the PET fabrics were treated with NaOH alkaline solution in various conditions. In alkaline treatment, the liquor flow type pilot weight reduction apparatus with magnetostrictive ultrasonic transducer was used for the study. The effects of ultrasonic application, treatment time and temperature at NaOH 4% and 6"A solution on the decomposition rate of PET fabrics. From the results of the decomposition rate of PET fabrics, the qualitative and quantitative analysis of oligomer after decomposition of PET fabrics carried out by the HPLC. On the other hand, the surface pore characteristics of decomposition PET fabrics measured by porosimetery. The pore characteristics on the surface of treated PET fiber depended on the decomposition rate and did not depend on the ultrasonic cavitation. The pore diameter of alkaline untreated PET fiber were 15A and those of treated PET fibers were 5~6$\AA$ at the maximum pore volume. The average pore sizes of fiber before and after treatment were 141 h and 160h, respectively. Total amount of oligomer of the untreated PET fibers were 1.70wt% and 67.7% of total oligomer occupied with PET cyclic trimer and PET cyclic tetramer. Total amount of oligomer of fiber with 26.9% and 48.0% of weight loss without ultrasonic application were 1.78wt% and 1.79wt%, respectively. Also total amount oligomer of fibers which were reduced 27.7% and 48.2% of weight loss with ultrasonic application were 1.74wt%. This result showed that the removal rate of oligomer in the process of alkaline hydrolysis with ultrasonic higher than that of without ultrasonic application.tion.

Properties of Soils under Different Land Uses in Chittagong Region, Bangladesh

  • Akhtaruzzaman, Md.;Osman, K.T.;Sirajul Haque, S.M.
    • Journal of Forest and Environmental Science
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    • 제31권1호
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    • pp.14-23
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    • 2015
  • In this study, we investigated the effects of three land uses on soil properties in two soil layers; surface soil (0~15 cm) and subsoil (15~30 cm). Soil samples were collected from planted forest, barren lands and cultivated lands from different areas in Chittagong Cox's Bazar and analyzed for some physical and chemical properties. Results showed that soil textural class varied from sandy clay loam in planted forest and barren land site to sandy loam in cultivated soils. Maximum water holding capacity was higher in forest followed by barren land and the lowest in cultivated lands. At both soil depths, soils of cultivated land showed the highest values of bulk density (1.42 to $1.50g\;cm^{-3}$), followed by barren lands (1.37 to $1.46g\;cm^{-3}$) and the least (1.32 to $1.45g\;cm^{-3}$) in forest soils. Total porosity decreased with depth ranging from 40.24% to 41.53% in subsoils and from 42.04 to 43.23% in surface soil of cultivated and of planted forest sites respectively. The result further revealed that organic carbon (OC) and total nitrogen (TN) contents were higher in the planted forest soil than in other two land uses. The soils of all land uses under study are acidic in nature and the lowest pH was found in both surface and subsoils of barren land. Cultivated soil contained the highest amount of available P, Ca, Mg and K in both surface soil and subsoils. In contrast, barren site had the lowest contents of available P, Ca, Mg and K in both layers. The soil organic carbon (SOC) and total N storage were higher in planted forest than in barren and cultivated land uses.

Polyacrylamide 고흡수성 수지의 혼합 비율이 상토의 물리성에 미치는 영향 (Effect of Incorporation Rate of Polyacrylamide Hydrogel on Changes in Physical Properties of Root Media)

  • 왕현진;최종명;이종석
    • 생물환경조절학회지
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    • 제14권3호
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    • pp.182-189
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    • 2005
  • 본 연구는 혼합상토의 보수성 증가를 위하여 polyacrylamide 고흡수성 수지 Stocksorb C를 혼합할 경우 상토의 물리성에 미치는 영향을 밝히기 위하여 수행하였다. 네종류 혼합상토, 피트모쓰 + 버미큘라이트(1:1 , v/v; PV), 피트모쓰+부숙왕겨(1:1, v/v; PR), 피트모쓰+부숙톱밥(1:1, v/v; PS), 그리고 피트모쓰+부숙수피(1:1, v/v; PB)를 조제하는 과정에서 STSB를 혼합하고, 플라스틱 포트에 충전하였으며, 5주 후에 상토의 물리적 특성을 측정하였다. STSB의 혼합비율이 증가할수록 PV, PS 및 PB 상토의 공극률이 증가하여 $5{\%}$ 수준의 통계적인 차이가 인정되었고, 직선 또는 2차곡선회귀가 성립하여 경향을 찾을 수 있었다. STSB의 혼합비율 증가로 PS와 PB상토의 용기용수량이 뚜렷하게 증가하였으나 PV 및 PR상토에서는 STSB의 혼합비율에 따른 처리간 차이가 인정되지 않았다. 특히 STSB의 혼합은 PV PS및 PB 상토의 기상률을 뚜렷하게 증가시켜 처리간 통계적인 차이와 함께 직선 및 2차곡선회귀가 성립하여 경향이 뚜렷하였다. 고흡수성 수지의 혼합비율이 높아질수록 4.90 kPa, 9.81 kPa, 29.4 kPa및 1.5 MPa 토양 수분장력 하에서 존재하는 수분량이 많았다. 각 상토별로 29.4 kPa이나 1.5 MPa에서 존재하는 수분은 PV 혼합상토에서 적었고, PB와 PR 혼합상토에서 유사한 수준이었으며, PS 혼합상토에서 가장 많았다. 이는 고흡수성 수지의 혼합비율이 높아짐에 따라 상토가 보유하는 수분량이 증가하지만 식물이 쉽게 흡수할 수 있는 수분량이 증가하지 않음을 의미한다.

지하댐 건설로 인한 지하수 증가량 계산 및 유황 분석 (Analysis of Flow Duration and Estimation of Increased Groundwater Quantity Due to Groundwater Dam Construction)

  • 김종태;김규범;정일문;정교철
    • 지질공학
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    • 제24권1호
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    • pp.91-98
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    • 2014
  • 본 연구는 지하댐 건설에 의한 지하수 증가량을 계산하고 지표수에 미치는 영향을 검토하는 것이 목적이다. 이를 위해 연구지역 면적과 지하수위, 유효공극률을 이용해 지하수량을 계산하였으며 영덕 오십천의 유황분석을 실시하여 지하수량 증가에 따른 지표수 변화를 검토하였다. 분석 결과 지하수 증가량은 지하댐 유역 기준으로 최대 $91,746m^3$이며 지하댐 하류의 지하수 감소량은 최대 $11,259m^3$인 것으로 계산되었다. 따라서 연구지역의 지하수 확보량은 총 $80,487m^3$이며 지하수 감소량은 지하수 증가량에 비해 12.27%에 불과한 것으로 나타났다. 댐 건설 후 하류지역의 유황곡선을 분석한 결과 댐건설로 인해 유출량의 변화가 최대 $3.00{\times}10^{-2}m^3/s$ 발생하였으나 댐 건설 전과 비교해 전반적인 차이는 거의 없는 것으로 나타났다. 이 연구 결과는 지하댐이 지표수 환경에 영향을 주지 않으며 충분한 대체 수자원이 될 수 있다는 것을 의미한다.

산소공여입자에 의한 석탄의 직접연소 특성 (Direct Combustion Characteristics of Coal by Oxygen Carrier)

  • 류호정;이충원;이동호;배달희;이승용;박영성
    • 한국수소및신에너지학회논문집
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    • 제25권1호
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    • pp.87-96
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    • 2014
  • Direct combustion characteristics of coal and oxygen carrier were measured in the thermogravimetric analyzer using four coals and two different oxygen carriers. The direct combustion efficiency decreased in order of Roto, Kideco, Sunhwa and Hyper coal for both oxygen carriers. Moreover, OCN703-1100 oxygen carrier showed better combustion efficiency than OCN706-1100 oxygen carrier for all four coals. The reduction characteristics of two oxygen carriers for $CH_4$, CO and $H_2$ gases were measured in the thermogravimetric analyzer to investigate why OCN703-1100 oxygen carrier showed better combustion efficiency than OCN706-1100 for all coals. The OCN703-1100 oxygen carrier represented higher reduction rate than OCN706-1100 for all reducing gases. Moreover, the total pore area and the porosity of OCN703-1100 were higher than those of OCN706-1100 oxygen carrier. The total volatile gas and volatile components of four coals were measured in a batch type fluidized bed reactor to investigate why the direct combustion efficiency decreased in order of Roto, Kideco, Sunhwa and Hyper coal for both oxygen carriers. The direct combustion efficiency was proportional to the total amount of ($CH_4+CO+H_2$) produced during devolatilization of coals.

BOTANI: High-fidelity multiphysics model for boron chemistry in CRUD deposits

  • Seo, Seungjin;Park, Byunggi;Kim, Sung Joong;Shin, Ho Cheol;Lee, Seo Jeong;Lee, Minho;Choi, Sungyeol
    • Nuclear Engineering and Technology
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    • 제53권5호
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    • pp.1676-1685
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    • 2021
  • We develop a new high-fidelity multiphysics model to simulate boron chemistry in the porous Chalk River Unidentified Deposit (CRUD) deposits. Heat transfer, capillary flow, solute transport, and chemical reactions are fully coupled. The evaporation of coolant in the deposits is included in governing equations modified by the volume-averaged assumption of wick boiling. The axial offset anomaly (AOA) of the Seabrook nuclear power plant is simulated. The new model reasonably predicts the distributions of temperature, pressure, velocity, volumetric boiling heat density, and chemical concentrations. In the thicker CRUD regions, 60% of the total heat is removed by evaporative heat transfer, causing boron species accumulation. The new model successfully shows the quantitative effect of coolant evaporation on the local distributions of boron. The total amount of boron in the CRUD layer increases by a factor of 1.21 when an evaporation-driven increase of soluble and precipitated boron concentrations is reflected. In addition, the concentrations of B(OH)3 and LiBO2 are estimated according to various conditions such as different CRUD thickness and porosity. At the end of the cycle in the AOA case, the total mass of boron incorporated in CRUD deposits of a reference single fuel rod is estimated to be about 0.5 mg.

총 사이징 시스템 (Total sizing system)

  • Proverb, Robert J.;Pawlowska, Lucyna;Komarowska, Kasia;Garro, Gina;Dilts, Kimberly
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 2004년도 제30회 국제세미나
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    • pp.19-42
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    • 2004
  • Sizing properties in paper are generally developed through the application of both internal and surface sizes. Rosin, wax, and synthetic sizes including ASA, AKD, and stearic anhydride are and have been used to provide wet-end sizing to paper. In many cases, the use of some of these sizes leads to runnability problems that are inherent in the wet-end operation. Variability in furnish, fines, broke, filler, water chemistry, conductivity, and pH control impacts the wet-end operation. Size press chemicals including starch and polymers such as styrene-acrylic, styrene-maleic, and styrene acrylate emulsions are used in conjunction with internal sizes to improve the paper surface for printing and strength properties, porosity, and opacity improvement. This paper will discuss results from a new, proprietary formulation and process that allows application of sizing chemistry more totally at the size press with reduced emphasis on wet end sizing. Runnability issues are thus minimized at the wet-end, chemical usage is more efficient, and significant cost savings can be realized. Case histories will be presented illustrating the advantages of this new application in commercial trials.

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전자빔 증착법에 의한 티타늄 전극 구조 염료 태양전지 제작에 관한 연구 (A Study on the Fabrication of Dye-Sensitized Solar Cells Consisting of Ti Electrodes by Electron-beam Evaporation Method)

  • 김윤기;심충환;김현규;성열문;김동현;이해준;박정후;이호준
    • 전기학회논문지
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    • 제59권4호
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    • pp.754-758
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    • 2010
  • In general, Dye-sensitized Solar Cells(DSCs) consist of the nanocrystalline titanium dioxide($TiO_2$) layer which is fabricated on a transparent conductive oxide(TCO) layer such as $F/SnO_2$ glass, a dye adhered to the $TiO_2$, an electrolyte solution and platinum-coated TCO. Among these components, two TCO substrates are estimated to be about 60% of the total cost of the DSCs. Currently novel TCO-less structures have been investigated in order to reduce the cost. In this study, TCO-less DSCs consisting of titanium electrodes were investigated. The titanium electrode is deposited on top of the porous $TiO_2$ layer using electron-beam evaporation process. The porosity of the titanium electrode was found out by the SEM analysis and dye adhesion. As a result, when the thickness of the titanium electrode increased, the surface resistance decreased and the conversion efficiency increased relatively.

산과 염기의 개질에 의해 변화된 활성탄의 표면특성과 흡착특성 비교 (Comparison of Surface Characteristics and Adsorption Characteristics of Activated Carbons Changed by Acid and Base Modification)

  • 이송우;이민규;박상보
    • 한국환경과학회지
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    • 제17권5호
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    • pp.565-571
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    • 2008
  • The surface properties of activated carbon modified by acids and base were studied. The influence of the surface chemistry on the adsorption of benzene and acetone vapor on modified activated carbons has been investigated The modified activated carbons were obtained by treatment with acetic acid ($CH_3COOH$), nitric acid ($HNO_3$) and sodium hydroxide (NaOH). The modified activated carbons had similar porosity but different surface chemistry and adsorption characteristics. The total surface acidity (sum of functional groups) of activated carbon (AC-AN) treated by nitric acid was 2.6 times larger than that of activated carbon (AC) before the acid treatment. Especially, carboxyl group was much developed by nitric acid treatment. The benzene equilibrium adsorption capacity of AC-AN decreased 20% more than that of AC. However, the acetone equilibrium adsorption capacity of AC-AN increased 20% more than that of AC because of the large increase of carboxyl group and acidity.