• 분석과학
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• 제24권5호
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• pp.378-386
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• 2011

본 연구는 호수바닥에 있는 침전물로부터 인의 용출 메커니즘을 규명하고자, 인이 물로 용출될때 미치는 온도의 영향을 조사하였다. 연구 결과를 보면, 온도가 증가하면 PO4-P가 평형에 빨리 도달하고, 평형농도가 증가하며, $PO_4$-P의 용출 증가로 인하여 pH가 감소한다. 즉, $PO_4$-P의 용출이 pH의 감소에 영향을 미침을 알 수 있었다. 탁도물질에서 용출된 $PO_4$-P는 물에 용존하며, 탁도물질에 흡착되지 않기 때문에 탁도의 변화에 관계없이 점진적인 증가를 나타냈지만, $PO_4$-P는 탁도에서 용출되기 때문에 탁도와 관련이 있다. 총인(Total phosphorous, T-P)은 용존성 $PO_4$-P와 탁도물질에 포함된 인을 포함하기 때문에 탁도의 변화에 직접 관련이 있음을 알 수 있었다. 온도가 감소하면 물의 밀도가 증가하여 탁도의 침전이 감소하기 때문에 탁도의 농도가 높아져 T-P 농도를 증가시키며, 온도가 증가하면 물의 밀도감소로 인하여 탁도물질의 침전이 용이해져서 탁도는 감소하지만 $PO_4$-P의 용출이 증가하여 T-P 농도가 증가했다. 따라서 동일 시간대의 T-P는 온도가 달라도 유사한 농도를 가졌다. 호수가 깊어지면 저층수의 온도가 감소하여 인의 용출이 감소하므로 이 메카니즘은 호수 바닥으로부터 물로 용출되는 인에 대하여 온도가 미치는 영향을 이해하는데에 중요하다.

• 한국환경과학회지
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• 제7권4호
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• pp.433-440
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• 1998

This study was carried out to develop the stream water quality model for the intaking station of Kongju waterworks in the Keum River system. The monthly water quality(total nitrogen and total phosphorus) with periodicity and trend were forecasted by multiplicative ARIU models and then the applicability of the models was tested based on 7 years of the historical monthly water quality data at Kongju intaking strate. The parameter estimation was made with the monthly observed data. The last one year data was used to compare the forecasted water Quality by ARU model with the observed one. The models are ARIMA(2,0,0)$\times$(0,1,1)l2 for total nitrogen, ARIMA(0,1,1)x(0,1,1)l2 for total phosphorus. The forecasting results showed a good agreement with the observed data. It is implying the applicability of multiplicative ARIMA model for forecasting monthly water quality at the Kongju site.

• 한국물환경학회지
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• 제24권4호
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• pp.499-503
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• 2008

In order to control the non-point source pollution, a vegetative filter strips (VFS) was set up and the site-monitoring was performed. The objective of this study is to investigate the influence of the plant coverage on treatment efficiency of total nitrogen (T-N) and total phosphorus (T-P) using vegetative filter strips. According to the results, it seemed that the treatment efficiencies of T-N and T-P were closely related with the plant coverage ratio. The results showed that treatment efficiency of T-P average 50% at higher than 50% of the plant coverage and 20~23% at lower than 50% of the plant coverage. Also, the treatment efficiency of T-N increased with the increase of the plant coverage ratio.

• 한국농공학회:학술대회논문집
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• 한국농공학회 1999년도 Proceedings of the 1999 Annual Conference The Korean Society of Agricutural Engineers
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• pp.759-764
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• 1999

In intensive agriculture, exceeded chemical fertilizer application would increase the concentration of nitrate nitrogen in groundwater. Consequently, it could bring the eutrophication in lakes and streams. The present study examined runoff loading of nitrogen and phosphorus from the paddy field during non-cropping season. The runoff loading of total-N, ammonia-N, nitrate-N and total-P were 12.96kg/ha, 5.42kg/ha, 1.52kg/ha and 1.41kg/ha. When the runoff loading of nutrients was compared by runoff water and sediments. About 70-80% of total-N by runoff water and the rest 20-30% by runoff sediments were flowed into streams. But 60-70% of total-P by runoff sediments and the rest 30-40% by runoff water were flowed into streams. The phosphorus compounds, which were flowed into streams by runoff sediments and then sedimented, keep exchanging with water at water body in undelivered condition. And it moves gradually into water layer. This process can cause eutrophication continually and repeatedly in water environment. So, a sound program is needed to reduce soil erosion from farmlands.

• 한국농공학회논문집
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• 제53권4호
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• pp.59-65
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• 2011

The purpose of this study was to analyze the water quality change when wastewater applied to study paddy fields. CREAMS-PADDY (Chemical, Runoff and Erosion from Agricultural Management System) model was used to estimate the field-scale water quality. Simulated results were compared with observed data monitored from Byeongjeom study paddy fields which is located near the Suwon sewage treatment plant in Gyeonggi-do. Significance analysis was performed for the three different irrigation water quality level and five fertilizer reduction scenarios using LSD (Least Significant Difference) and DMRT (Duncan's Multiple Range Test). Total nitrogen was found to be significant for both irrigation water quality level and fertilizer reduction while total phosphorus was not. Annual drainage load for total nitrogen was reduced by 66~92 % compared to irrigation load when treated wastewater irrigated to study paddy fields from 2002 to 2007. Total phosphorus was reduced by 70~86 %.

• Journal of Ecology and Environment
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• 제40권1호
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• pp.66-74
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• 2016

Background: When developing water quality improvement strategies for eutrophic lakes, questions may arise about the relative importance of point sources and nonpoint sources of phosphorus. For example, there is some skepticism regarding the effectiveness of partial reductions in phosphorus loading; because phosphorus concentrations are too high in hypertrophic lakes, in-lake phosphorus concentrations might still remain within typical range for eutrophic lakes even after the reduction of phosphorus loading. For this study, water quality and the phytoplankton and zooplankton communities were monitored in a hypertrophic reservoir (Lake Wangsong) before and after the reduction of phosphorus loading from a point source (a sewage treatment plant) by the installation of a chemical phosphorus-removal process. Results: Before phosphorus removal, Lake Wangsong was classified as hypertrophic with a median phosphorus concentration of $0.232mg\;L^{-1}$ and a median chlorophyll-a concentration of $112mg\;L^{-1}$. The dominant phytoplankton were filamentous cyanobacteria for the most of the ice-free season. Following the installation of the advanced treatment process, phosphorus concentrations were reduced to $81mg\;L^{-1}$, and the N/P atomic ratio increased from 42 to 102. Chlorophyll-a concentrations decreased to $42{\mu}g\;L^{-1}$, and the duration of cyanobacterial dominance was confined to the summer season. Cyanobacteria in spring and autumn were replaced by diatoms and cryptomonads. Filamentous cyanobacteria in summer were replaced by colony-forming unicellular Microcystis spp. It was remarkable that zooplankton biomass increased despite the decrease in phytoplankton biomass, and especially cladoceran zooplankton which increased drastically. These responses to the reduction of point source P loading to Lake Wangsong imply that reducing the point source P loading can have a big impact even when nonpoint sources account for a large fraction of the total annual phosphorus loading. Conclusions: Our results also show that the phytoplankton community can shift to decreased cyanobacterial dominance and the zooplankton community can shift to higher cladoceran dominance, even when phosphorus concentrations remain within the typical range for eutrophic lakes following the reduction of phosphorus loading.

• 한국토양비료학회지
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• 제21권1호
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• pp.21-29
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• 1988

인산(燐酸) 축적지(畜積地) 토양(土壤) 149점(點)(시건설원예지(施設園藝地) 60점(點), 마늘, 양파, 고추 재배지(栽培地) 89점) 에 대한 무기태인산(無機態燐酸)의 형태별(形態別) 조성(造成)과 유효인산(有效燐酸) 함량(含量)과의 관계(關係)를 검토(檢討)한 결과(結果)를 요약(要約)하면 다음과 같다. 1. 총(總) 인산(燐酸)에 대한 무기태인산(無機態燐酸)의 분포비(分布比)는 68.9%(Sa-p 2.7, Al-p 26.4, Fe-p 27.6, Ca-p 12.2), 유기태인산(有機態燐酸)은 6.7%, 유효인산(有效燐酸)은 26.0%이었따. 2. 유효인산함량(有效燐酸含量)과 무기태인산(無機態燐酸) 함량(含量)과의 상관관계(相關關係)에서 Al-p와는 0.1%에서 유의성(有意性)있는 상관관계(相關關係)를 나타내었으며, Sa-p, Ca-p 순으로 유의성(有意性)을 보였고 Fe-p와는 일정한 상관관계(相關關係)를 나타내지 않았다. 3. 유효인산함량(有效燐酸含量)과 무기태인산(無機態燐酸) 함량(含量)과의 다중회귀분석(多重回歸分析) 결과(結果) $Av.P=81.694+0.858Sa-p^{***}+0.648Al-p^{***}+0.091Ca-p^{**}(R=0.826^{***})$의 관계식(關係式)을 얻었으며, 각 성분(成分)의 기여도(奇與度)는 Sa-p 26.1, Al-p 65.2, Ca-p 8.7%이었다. 4. 유효인산함량(有效燐酸含量)과 수용성인산(水溶性燐酸), 수용성인산(水溶性燐酸)과 $0.01M-CaCl_2-p$와는 고도(高度)의 유의성(有意性) 있는 상관관계(相關關係)를 나타내었고, $0.01M-CaCl_2$ 용액(溶液)에 의한 30분(分) 추출법(抽出法)은 토양용액(土壤溶液) 인산(燐酸)을 신속(迅速) 간편(簡便)하게 추정(推定)할 수 있는 방법(方法)으로 생각되었다.

• 한국농공학회지
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• 제45권7호
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• pp.49-56
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• 2003

Nonpoint source pollutant loading from watershed may cause a problem to the water quality of the reservoir and stream. The characteristics of stream flow and water quality were monitored to investigate the runoff loading of the Namdae-cheon watershed from May in 1999 to October in 2003. Stage-discharge rating curve at the stream gauging site was established, and annual stream runoff of the study watershed was estimated as 499.4∼1,330.8mm during four years. The concentrations of total-nitrogen and total-phosphorus of stream water quality ranged from 0.76 to 6.95mg/L and from 0.0010 to 0.2276 mg/L, respectively, where T-N was generally higher than the water quality standard 1.0 mg/L for agricultural water use. The loads by unit generation of pollutant mass with respect to population, livestock, land use in this watershed were calculated. The runoff pollutant loadings by concentrations of total-N and total-P were estimated during study period, where the annual runoff loading of total-P was much less than the load by pollutant mass unit generation. The relations between stream discharge and water quality were analysed, and there was a high correlation for total-N but low for total-P. These results will be used to develop the monitoring techniques and water quality management system of agricultural watershed.

• Journal of Ecology and Environment
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• 제39권1호
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• pp.31-42
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• 2016

The object of this study was to determine long-term temporal and spatial patterns of nutrients (nitrogen and phosphorus), suspended solids, and chlorophyll (Chl) in Chungju Reservoir, based on the dataset of 1992 - 2013, and then to develop the empirical models of nutrient-Chl for predicting the eutrophication of the reservoir. Concentrations of total nitrogen (TN) and total phosphorus (TP) were largely affected by an intensity of Asian monsoon and the longitudinal structure of riverine (Rz), transition (Tz), and lacustrine zone (Lz). This system was nitrogen-rich system and phosphorus contents in the water were relatively low, implying a P-limiting system. Regression analysis for empirical model, however, showed that Chl had a weak linear relation with TP or TN, and this was mainly associated with turbid, and nutrient-rich inflows in the system. The weak relation was associated with non-algal light attenuation coefficients (Kna), which is inversely related water residence time. Thus, values of Chl had negative functional relation (R² = 0.25, p < 0.001) with nonalgal light attenuation. Thus, the low chlorophyll at a given TP indicated a light-limiting for phytoplankton growth and total suspended solids (TSS) was highly correlated (R² = 0.94, p < 0.001) with non-algal light attenuation. The relations of Trophic State Index (TSI) indicated that phosphorus limitation was weak [TSI (Chl) - TSI (TP) < 0; TSI (SD) - TSI (Chl) > 0] and the effects of zooplankton grazing were also minor [TSI (Chl) - TSI (TP) > 0; TSI (SD) - TSI (Chl) > 0].

• 한국수산과학회지
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• 제43권5호
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• pp.540-546
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• 2010

We investigated variations in alkaline phosphatase (APase) activity and alkaline phosphatase hydrolyzable phosphorus (APHP) in northern Gamak Bay from September to December 2009. Dissolved inorganic nitrogen (DIN) and dissolved inorganic phosphorus (DIP) decreased gradually, and the DIN/DIP ratio was higher than the Redfield ratio (16) based on molecular concentrations during most of the observation period. The total APase (T-APase) activity increased with decreasing DIP concentration; i.e., the Relationship between T-APase and DIP showed a high negative correlation (r=-0.80, P<0.001), with APase activity being a good indicator of DIP limiting the Redfield ratio. The T-APase was positively correlated with the concentration of chlorophyll a (r=0.73, P<0.001). This suggests that a major portion of APase activity in northen Gamak Bay seawater is attributed to phytoplankton. The proportion of APHP among dissolved organic phosphorus (DOP) was low in September and high in November. Thus, APase-producing phytoplankton may be able to grow by utilizing APHP as a phosphorus source in autumn when DIP is limiting. Thus, APase activity and the use of DOP by phytoplankton may play an important role in the growth of phytoplankton under DIP limiting conditions such as those of northern Gamak Bay.