• Atmosphere
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• v.17 no.4
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• pp.339-348
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• 2007

Global Environment Laboratory at Yonsei University in Seoul ($37.57^{\circ}N$, $126.95^{\circ}E$) has carried out the ozone layer monitoring program in the framework of the Global Ozone Observing System of the World Meteorlogical Organization (WMO/GAW/GO3OS Station No. 252) since May of 1984. The daily measurements of total ozone and the vertical distribution of ozone amount have been made with the Dobson Spectrophotometer (No.124) on the roof of the Science Building on Yonsei campus. From 2004 through 2006, major parts of the manual operations are automated in measuring total ozone amount and vertical ozone profile through Umkehr method, and calibrating instrument by standard lamp tests with new hardware and software including step motor, rotary encoder, controller, and visual display. This system takes full advantage of Windows interface and information technology to realize adaptability to the latest Windows PC and flexible data processing system. This automatic system also utilizes card slot of desktop personal computer to control various types of boards in the driving unit for operating Dobson spectrophotometer and testing devices. Thus, by automating most of the manual work both in instrument operation and in data processing, subjective human errors and individual differences are eliminated. It is therefore found that the ozone data quality has been distinctly upgraded after automation of the Dobson instrument.

• Food Science and Preservation
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• v.5 no.1
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• pp.73-80
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• 1998

Shelf-life of soybean curd prepared with ozone-treated soybeans investigated on pH, acidity, sour taste, slime formation during storage at 3$0^{\circ}C$. Total Plate counts of raw soybeans showed about log 7.0 CFU/g before ozone treatment. The sterilization efficiency of raw soybeans showed the most effective in 0.5ppm of aqueous ozone treatment at 4$^{\circ}C$ for 90 minutes. Raw soybeans were treated with ozone by different methods; (1) Ozone treatment for 90 + 90 minutes (first 3.5~5 hours and later 8.5~10 hours) of 10 hours during soaking in aqueous solutions at 4$^{\circ}C$ (OW). (2) Ozone treatment by exposure first to 30ppm of gaseous ozone for 90 minutes and then allied to OW method (GO+OW). The log reduction of raw soybeans treated by OW and GO+OW methods showed 3.72 and 4.15, respectively. Soybean curd prepared with OW and GO+OW-treated soybeans kept the shelf-life of 4 and 5.5 days at 3$0^{\circ}C$, respectively, but, that without ozone treatment spoiled at me day.

• Proceedings of the KSRS Conference
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• 2002.10a
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• pp.7-11
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• 2002

This study introduces the first method that determines tropospheric ozone column directly from a space-based instrument. This method is based on the physical differences in the Total Ozone Mapping Spectrometer (TOMS) measurement as a function of its scan-angle geometry. Tropospheric ozone in September-October exhibits a broad enhancement over South America, the southern Atlantic Ocean, and western South Africa and a minimum over the central Pacific Ocean. Tropical tropospheric ozone south of the equator is higher than north of the equator in September-October, the southern burning season. Conversely, ozone north of the equator is higher in March, the northern burning season. Overall, the ozone over the southern tropics during September-October is significantly higher than over the northern tropics. Abnormally high tropospheric ozone occurs over the western Pacific Ocean during the El Nino season when the ozone amounts are as high as the ozone over the Africa.

• Journal of Environmental Science International
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• v.24 no.8
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• pp.993-1001
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• 2015

Comparing to the other air pollutants like $SO_2$, CO, the number of exceedance of the ozone national ambient air quality standard(NAAQS) and the ozone warning increased recently in Busan. The purpose of this study is to find out the preliminary symptoms for high ozone days in Busan area. In order to find out the preliminary symptoms, the hourly ozone data at air quality monitoring stations and the hourly meterological parameters at Busan regional meteorological 2007 to 2013 were used for the analysis. Averaged daily max ozone concentration was the highest(0.055 ppm) at Noksan and Youngsuri in the ozone season from 2007 to 2013. The horizontal distributions of daily max. ozone including all stations in Busan at high ozone days(the day exceeding 0.1 ppm of ozone concentration at least one station) were classified from two to five clusters by hierarchial cluster analysis. The meteorological variables showing strong correlation with daily max. ozone were the daily mean dew point temperature, averaged total insolation, the daily mean relative humidity and the daily mean cloud amount. And the most frequent levels were $19-23^{\circ}C$ in dew point temperature, $21-24 MJ/m^2$ in total insolation on the day before, $2.6-3.0 MJ/m^2$ on the very day, 67-80% in relative humidity and 0-3 in cloud amount.

• Atmosphere
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• v.15 no.2
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• pp.101-118
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• 2005

Atmospheric ozone changes temporally and spatially according to both anthropogenic and natural causes. It is essential to quantify the natural contributions to total ozone variations for the estimation of trend caused by anthropogenic processes. The aims of this study are to understand the intrinsic natural variability of long-term total ozone changes and to estimate more reliable ozone trend caused by anthropogenic ozone-depleting materials. For doing that, long-term time series for Seoul of monthly total ozone which were measured from both ground-based Dobson Spectrophotometer (Beck #124)(1985-2004) and satellite TOMS (1979-1984) are analyzed for selected period, after dividing the whole period (1979~2004) into two periods; the former period (1979~1991) and the latter period (1992~2004). In this study, ozone trends for the time series are calculated using multiple regression models with explanatory natural oscillations for the Arctic Oscillation(AO), North Atlantic Oscillation(NAO), North Pacific Oscillation(NPO), Pacific Decadal Oscillation(PDO), Quasi Biennial Oscillation(QBO), Southern Oscillation(SO), and Solar Cycle(SC) including tropopause pressure(TROPP). Using the developed models, more reliable anthropogenic ozone trend is estimated than previous studies that considered only QBO and SC as natural oscillations (eg; WMO, 1999). The quasi-anthropogenic ozone trend in Seoul is estimated to -0.12 %/decade during the whole period, -2.39 %/decade during the former period, and +0.10 %/decade during the latter period, respectively. Consequently, the net forcing mechanism of the natural oscillations on the ozone variability might be noticeably different in two time intervals with positive forcing for the former period (1979-1991) and negative forcing for the latter period (1992-2004). These results are also found to be consistent with those analyzed from the data observed at ground stations (Sapporo, Tateno) of Japan. In addition, the recent trend analyses for Seoul show positive change-in-trend estimates of +0.75 %/decade since 1997 relative to negative trend of -1.49 %/decade existing prior to 1997, showing -0.74 %/decade for the recent 8-year period since 1997. Also, additional supporting evidence for a slowdown in ozone depletion in the upper stratosphere has been obtained by Newchurch et al.(2003).

• Korean Journal of Remote Sensing
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• v.19 no.1
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• pp.11-19
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• 2003

This paper applies the Scan-Angle Method (SAM) to the Total Ozone Mapping Spectrometer (TOMS) aboard Earth Probe (EP) satellite for determining tropospheric ozone based on TOMS scan geometry. In the northern tropical Africa burning season, the distribution of the SAM-derived tropospheric ozone presents a tropospheric ozone enhancement related to biomass burning. This distribution is consistent with that of fire counts observed from Along Track Scanning Radiometer (ATSR) and that of carbon monoxide, the tropospheric ozone precursor, observed from Measurements of Pollution In The Troposphere (MOPITI). However, this feature is not shown in the distribution of tropospheric ozone derived from other TOMS-based algorithms for the northern burning season. In the high latitudes, the influence of pollution in the SAM results is seen over the northern continents in agreement with carbon monoxide for northern summer when the dynamical activity is weak in the northern hemisphere.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.42 no.3
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• pp.67-73
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• 2010

Pine (Pinus densiflora) and aspen (Populus euramericana) wood meals were treated with ozone at various time schedule in acidic condition. The lignin contents and surface area of the ozone treated wood meals were determined and the enzymatic hydrolysis rate of ozonated wood meals was evaluated. The feasibility of enzymatic hydrolysis of the ozone treated wood meal was obviously influenced with the degree of delignification. After ozone treatment of wood meal for 10min, total pore volume were slightly increased in the surface of wood meal. When wood meals were treated with ozone longer than 10min, few change in the pore volume was observed. However, the area of over $50{\AA}$ of pore size is increased with ozonation time. As a conclusion, the rate of enzymatic hydrolysis of wood is more effective with the pore size distribution than the total pore volume.

• Journal of Environmental Science International
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• v.23 no.4
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• pp.697-705
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• 2014

The exposed population of a vulnerable group to high ozone episodes (exceeding 60 ppb/8h) was estimated in Busan metropolitan city from 2000 to 2010. The frequency of high ozone days at monitoring sites and the number of the population aged over 65 were used to calculate the accumulated (total, seasonal, and yearly) number of the exposed older population (EOP) to high ozone episodes during the study period based on administrative areas, by interpolation and zonal mean methods in ArcGIS software. The older population in this city had increased significantly from 2000 to 2010 (representing over 10% of the total population in 2010). The vulnerable areas (e.g. the eastern area of the city) of the EOP to high ozone episodes were different from the areas with frequent high ozone episodes (e.g., the western area) due to the increase of the older population in particular areas. The difference was more significant in spring than in any other season, and in 2010 than in previous years (2000 and 2005).

• Journal of the Korean earth science society
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• v.27 no.7
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• pp.778-786
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• 2006

In Korea, the ozone profiles have been acquired by using ozonesonde at Pohang station of the Korea Meteorological Administration (KMA) since 1995. These ozone soundings were performed at 0500 UTC on a weekly basis (every Wednesday) in a clear sky. The ozonesonde is equipped with the model 5A ECC sensor, which is one of the most common ozonesonde systems. There have been no attempts to evaluate the Pohang ozonesonde profiles compared with satellite. This paper will provide the first evaluation results for the ozonesonde profiles against HALogen Occultation Experiment (HALOE) measurements over Korea. During 1995-2004 periods, a total of 450 and 188 ozone profiles were obtained from the ozonesonde measurements from HALOE measurements over Korea, respectively. Hence, a total of 34 coincident profile pairs are extracted. Among those total profiles, 26 profiles from ozonesonde are compared against nearly coincident HALOE measurements in time and space. For ozone profiles, the results of statistical analyses showed that the best agreement between two measurements occurs in the 20-25 km and 30-35 km region, where the mean and RMS percent differences are less than ${\pm}5$ and 14%, respectively. For temperature profiles, the mean and RMS percent differences in 20-25 km region are estimated to be about -0.1 and 1.7%, respectively. According to the scatter plots between two measurements, ozone data are strongly correlated each other above 20 km altitude range with more than 0.8 correlation coefficients. It is found that the altitude (pressure level) differences between two measurements would mainly lead to the discrepancy (over 40% below 18 km) below 20 km in ozone profiles.

• Asian Journal of Atmospheric Environment
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• v.9 no.2
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• pp.146-157
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• 2015

Emissions of ozone precursors ($NO_x$ and VOCs) and photochemical ozone creation potentials (POCPs) of VOC emission sources were investigated in the largest port city (i.e., Busan), Korea during the year 2011. This analysis was performed using the Clean Air Policy Support System (CAPSS) national emission inventory provided by the National Institute of Environmental Research (NIER), Korea. For $NO_x$, the emissions from off-road mobile sources in Busan were the most dominant (e.g., $31,202ton\;yr^{-1}$), accounting for about 60% of the total $NO_x$ emissions. The emission from shipping of off-road mobile sources (e.g., $24,922ton\;yr^{-1}$) was a major contributor to their total emissions, amounting to 47% of the total $NO_x$ emissions due to the port-related activities in Busan. For VOCs, the emission source category of solvent usage was predominant (e.g., $36,062ton\;yr^{-1}$), accounting for approximately 82% of the total VOC emissions. Out of solvent usages, the emission from painting was the most dominant ($22,733ton\;yr^{-1}$), comprising 52% of the total emissions from solvent usages. The most dominant VOC species emitted from their sources in Busan was toluene, followed by xylene, butane, ethylbenzene, n-butanol, isopropyl alcohol, and propane. The major emission sources of toluene and xylene were found to be painting of coil coating and ship building, respectively. The value of POCP for the off-road mobile source (61) was the highest in ten major activity sectors of VOC emissions. Since the POCP value of ship transport of off-road mobile source (72) was also high enough to affect ozone concentration, the ship emission can play a significant role in ozone production of the port city like Busan.