• Title/Summary/Keyword: Total neutralizing capability

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Effects of Physicochemical/Mineralogical Characteristics of Limestones and Porosity after Calcination on Desulfurization Reactivities

  • Baek, Chul-Seoung;Seo, Jun-Hyung;Cho, Jin-Sang;Cho, Kye-Hong;Han, Choon
    • Journal of the Korean Ceramic Society
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    • v.53 no.1
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    • pp.34-42
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    • 2016
  • Characteristics of wet flue gas desulfurization and in-furnace desulfurization of domestic and overseas limestone with different crystallinity and crystalline size are studied in this article. Properties of desulfurization were evaluated in relation to physicochemical/ mineralogical characteristics, degree of pore formation for different calcination temperatures and TNC(total neutralizing capability). TNC of domestic high crystalline limestone was lower than that of overseas one. On the other hand, the porosity after calcination was shown to be relatively high for domestic limestone, which had high initial rates of desulfurization reactions in-furnace. Based on low pore formation and porosity with high TNC of crystalline high-Ca limestones compared to macrocrystalline ones, the former are preferred for wet desulfurization processes.

Influence of Physicochemical Characteristic of Donghae-Samcheok Limestones on the Performance of Flue Gas Desulfurization (FGD) (동해-삼척지역 석회석의 물리화학적 특성이 탈황성능에 미치는 영향)

  • Seo, Jun-Hyung;Baek, Chul-Seoung;Kwon, Woo-Tech;Cho, Kye-Hong;Ahn, Ji-Whan
    • Resources Recycling
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    • v.24 no.6
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    • pp.38-44
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    • 2015
  • It studies that effect of limestone of physicochemical characteristic on the performance of flue gas desulfurization (FGD) and application examination for technology of wet type FGD process and to utilize the limestone in Donghae-Samcheok. The experiment method was measured total neutralizing capability (TNC) using the lab scale experimental apparatus based on the HCl titration test. The results of TNC of limestone samples were more dependent on the physical characteristics including particle size rather than chemical compositions such as CaO content and particle size of limestone get smaller, TNC is increased.