• Title/Summary/Keyword: Total concentrations

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A Case Study on the Measurement Volatile Organic Compounds and Total Hydrocarbon Concentrations in Block Paint-Shops at a Shipyard (조선소 블록 도장시설에서의 휘발성 유기화합물과 총 탄화수소 농도측정 사례)

  • Yang, Sung-Bong;Yu, Mee Seon;Woo, Kyung-Bin
    • Journal of Environmental Science International
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    • v.25 no.8
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    • pp.1177-1189
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    • 2016
  • In order to prepare the information needed to construct a reduction system for volatile organic compounds (VOCs) exhausted from ship-block paint-booths in a giant shipyard, VOCs in paint-shop airs were analyzed and compared to the components in paint thinners. Aromatic hydrocarbons containing eight and nine carbon atoms are known to be major VOC compounds found in shipyard paint-shops. The total hydrocarbon (THC(C7)) concentrations calibrated using toluene gas, were measured in block paint-shops with two photo-ionization detector (PID) meters, and the resulting THC(C7) data were converted to THC(C1) concentrations according to the Standard Methods for the Measurements of Air Pollution in South Korea. THC(C1) concentrations near the spray site ranged from 10 to 2,000 ppm, but they were less than 400 ppm near the walls of the paint-booth. The measurements of THC concentrations, based on the height of the monitoring sites, were related to the height of the target to which the spray paints were applied. The maximum concentrations occurred at almost the same height as the spray targets. When painted blocks had been dried-by warming with no spraying, the THC concentrations were 80~100 ppm.

Evaluation of Percolated Water Quality of Paddy Fields Using Nonparametric Test (비모수검정을 이용한 논침투수 수질의 평가)

  • Oh, Seung-Young;Kim, Jin-Soo;Oh, Kwang-Young
    • Journal of The Korean Society of Agricultural Engineers
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    • v.47 no.2
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    • pp.99-110
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    • 2005
  • Characteristics of concentrations of total nitrogen (TN), total phosphorus (TP), and chemical oxygen demand (COD) pollutant in percolated water at four paddy field sites (Soro, Odong, Munui, and Boeun) were investigated by a nonparametric test. Percolation rate measurement and percolated water sampling were taken during irrigation periods at $5{\sim}10$ day intervals. The normality of percolation rate and pollutant concentrations were examined using histogram, boxplot, and the Kolmogorov-Smirnov (K-S) test. Pollutant concentrations in percolated water showed positively skewed distribution. The median concentrations of pollutant were 1.91 mg/L for TN, 0.021 mg/L for TP, and 6.6 mg/L for COD, which were lower than its arithmetic mean concentrations by $35\%$ for TN, $36\%$ for TP, and $13\%$ for COD. The median concentrations of TN and TP differed significantly among sample sites according to the Kruskal-Wallis test. However, median concentrations were not significantly different among month except for TN and TP of Soro and COD of Odong. The percolation load of pollutants during irrigation periods in the study area were estimated at $3.12{\sim}7.75\;kg/ha$ for TN, $0.033{\sim}0.155\;kg/ha$ for TP, and 10.7 kg/ha for COD, which were much lower than respective values reported in Japan.

Assessment of total is ocyanates by OSHA and NIOSH analytical methods : accuracy and precision and airborne concentrations by process (NIOSH와 OSHA 측정 방법을 이용한 이소시아네이트류 발생 공정별 농도 분포 평가)

  • Kang, Hyoung Kyoung;Kim, Hyunwook
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.9 no.2
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    • pp.1-18
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    • 1999
  • The purpose of this study was to compare performances of two analytical methods, the OSHA 42 and the NIOSH 5522, of quantifying total isocyanates in air. These methods were compared in terms of accuracy and precision and the detection limits using four(4) spiked samples in each of four(4) concentration levels which ranged from 0.25 to 2.0 times of the ACGIH TLV-TWA. In addition, two methods were used to as sess airborne concentrations of total isocyanates at the following processes including autobody spray painting, furniture spray painting, polyurethane foaming, urethane adhesion, UV coating, and pigment mixing. The results of this study showed that the NIOSH 5522 method was better than the OSHA 42 method in terms of accuracy, precis ion, and detection limit for quantifying airborne total isocyanates. It was also clear that the NIOSH method was capable of detecting not only monomeric but also non-monomeric isocyanates. The results of air concentrations of total isocyanates among processes studied indicate that some processes may exceed the recommended level of isocyanates. In addition, to evaluate toxicological effects of total isocyanates, it is recommended to consider additive effects of isocyanates present in mixtures.

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Characteristics of Nutrient Concentrations in Groundwater under Paddy and Upland Fields (논과 밭 지하수의 영양물질 농도 특성)

  • Jang, Hoon;Kim, Jin-Soo;Kim, Young-Hyeon;Song, Chul-Min
    • Journal of The Korean Society of Agricultural Engineers
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    • v.53 no.6
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    • pp.67-74
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    • 2011
  • The objective of this study was to compare concentrations of nutrients such as total nitrogen (TN), nitrate nitrogen ($NO_3$-N) total phosphorous (TP), and phosphate phosphorous ($PO_4$-P) in groundwater under paddy and upland fields, and surface water recharging from a rural mixed land-use watershed. Chinese cabbage and hot pepper were cultivated on the upland field plot. The TN concentrations in upland groundwater showed double peaks (4.7, 4.3 mg/L, respectively) in April 2009 shortly after fertilizer application, indicating that TN concentrations are greatly influenced by fertilization. However, the TN concentrations in paddy groundwater were always lower than 2.0 mg/L irrespective of fertilization. Whereas the mean concentrations of TN and $NO_3$-N in upland groundwater significantly (p<0.05) higher than those in surface water, the mean concentrations of TP and $PO_4$-P in upland groundwater were significantly lower than those in surface water. On the other hand, the mean concentrations of TN, $NO_3$-N, TP and $PO_4$-P in paddy groudwater were significantly (p<0.05) lower than those in surface water. The TN concentrations in upland groundwater were generally higher than those in surface water during early April to early December due to the effect of fertilization, but vice versa in the other periods. In contrast, the TP concentrations in upland groundwater were always lower than those in surface water due to the sorption of inorganic phosphorous by soil. Moreover, the TN and TP concentrations in paddy groundwater were always lower than those in surface water, and therefore paddy groundwater may dilute nutrient concentrations in surface water when paddy groundwater and surface water mix.

Effect of Biotic Substances on Isoflavone Content in Soybean Germination (Biotic 물질이 콩 발아 중 Isoflavone 함량에 미치는 영향)

  • Kim, Seo-Young;Song, Young-Ho;Yi, Yoo-Jung;Kim, Hong-Sik;Kim, Yong-Ho
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.65 no.2
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    • pp.84-92
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    • 2020
  • For humans, soybean and soybean products are the main dietary sources of isoflvones, which are polyphenolic compounds that represent one of the most common categories of phytoestrogens. The objective of this study was to determine isoflavone concentrations in soybean cultivars during germination when treated with some biotic substances. Three soybean cultivars were germinated in replicated trials in 2018/2019 and their individual and total isoflavone concentrations were determined using HPLC (High-Performance Liquid Chromatography). Significant differences were observed in total isoflavone content were observed among cultivars regardless of years and treatments. 'Daepung2-ho' and 'Uram' had significantly higher total isoflavones than 'Pungsannaul-kong'. Differences among treatments were also significant for total isoflavone content. In 2018, with chitosan treatment, total isoflavone concentration ranged from 551.15 to 7584.07 ㎍ g-1, with an average of 2972.64 ㎍ g-1 across cultivars. In 2019, there was no significant difference among treatments in total isoflavone content. Regarding individual isoflavone concentrations, the malonyl-glucoside groups accounted for over 85% of the total isoflavone content, which is indicated that these groups play an important role with regard to isoflavone components in soybean seeds. The individual proportions in the total concentrations of isoflavones varied according to germination period and seed tissues. Glucosides and malonyl-glucosides showed differences in concentrations among seed tissues, aglycones were further accumulated as germination period was progressed. This study suggests that biotic substances have an impact on seed isoflavone content during germination. However, cultivars with consistently high or low isoflavone concentrations across biotic substance treatments were identified desspite differences in germination period and seed tissues, demonstrating that the genetic factor plays the most important role in isoflavone accumulation.

Worker Exposure Assessment on Airborne Total Chromium and Hexavalent Chromium by Process in Electroplating Factories (도금업체 공정별 근로자의 총크롬 및 6가 크롬 노출 평가)

  • Yi, Gwang Yong;Kim, Boowook;Shin, Yong Chul
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.25 no.1
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    • pp.89-94
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    • 2015
  • Objectives: The objective of this study was to determine characteristics of workers' exposures to airborne total and hexavalent chromium by job title in electroplating processes. Methods: Total Cr was determined through a modified method based on NIOSH Method 7024. Airborne hexavalent Cr, Cr(VI), was sampled and extracted according to NIOSH Method 7600 and analyzed at 520 nm using an ion chromatograph/visible detector. Results: The geometric mean(GM) of total Cr concentrations from all factories was $11.2{\mu}g/m^3$(GSD=4.9). The GM of Cr(VI) concentrations from all factories was $2.84{\mu}g/m$ (GSD=5.2), and the concentrations among factories were significantly different (p<0.05). The Cr(VI) levels were lower than total Cr levels. Total Cr exposure levels were highest among buffing workers ($21.6{\mu}g/m^3$), but Cr(VI) levels were highest among plating workers($4.15{\mu}g/m^3$). The concentrations of Cr(VI) and total Cr from plating tasks was highly correlated(r=0.91). Conclusions: In the electroplating industry, plating workers were mainly exposed to Cr(VI), but others were not. Oxidation-reduction states of Cr and job titles should be considered in the exposure or risk assessments of chrome electroplating factories.

Study of nutritional status and management of lactating dairy COWS using analysed milk composition (유 성분 분석을 통한 젖소 영양상태 및 개체관리에 관한 연구)

  • Lee, Sung-mo;Kim, Dong-won;Choi, Byung-ryul;Seo, Kang-moon;Hong, Chong-hae
    • Korean Journal of Veterinary Research
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    • v.41 no.2
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    • pp.243-252
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    • 2001
  • Milk constituents and somatic cell count (SCC) were analysed for 4,059 milk samples from 178 dairy farms from April to December in 1999. Correlations among each milk constituents, milk urea (MU) concentration and SCC in association with lactation stage, milk yield and parity, and balancing status of nutrients' supplies were analysed, and the results are summarized as follows; Averages of milk fat percent, total solids percent and milk yield were $3.72{\pm}0.91%$, $12.50{\pm}1.31%$ and $23.80{\pm}8.54kg$, respectively, whereas those were significantly lower during the summer season. In contrast, average of MU concentration was $0.0361{\pm}0.0006%$ which was significantly higher during the summer season. With milk yield, concentrations of fat, protein and SCC in milk decreased but concentrations of lactose and urea in milk and body condition score (BCS) were not altered. Concentrations of fat, protein, lactose, total solids, SNF, and urea in milk were significantly affected by stage of lactation ($P{\leq}0.0001$) but SCC was not changed. Parity of dairy cows had a significant effect on concentrations of fat ($P{\leq}0.02$), lactose ($P{\leq}0.0001$), total solids ($P{\leq}0.002$), and SNF ($P{\leq}0.0001$) in milk and milk yield ($P{\leq}0.0005$) but did not change concentrations of urea and protein in milk. Somatic cell count had significant positive correlationship with percentages of fat, protein and total solids ($P{\leq}0.0001$), respectively, but had negative correlationship with percentages of urea and lactose in milk and milk yield ($P{\leq}0.0001$). Milk urea concentration was negatively correlated with concentrations of protein, fat, total solids, and SNF in milk and milk yield ($P{\leq}0.0001$) and, according to regression analysis using milk urea concentration and SCC, following equation was obtained; $Y(MU)=3.688{\times}10^{-2}-4.04{\times}10^{-7}{\times}X(SCC{\times}1,000)(r^2=0.0038$, $P{\leq}0.0001$). We studied balance between protein and energy supplies to dairy cows in each farm based upon milk urea and protein concentrations, and results showed that 137 of total 178 farms fed cows unbalanced amounts of dietary protein and energy.

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Inhibition of Submerged Macrophytes on Phytoplankton I. Field Evidence for Submerged Macrophyte Inhibition on Phytoplankton Biomass

  • Joo, Sung-Bae;Ji, Young-Jung;Park, Sang-Kyu
    • Korean Journal of Ecology and Environment
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    • v.40 no.4
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    • pp.511-519
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    • 2007
  • It is known that phytoplankton biomass or turbidity are lower in waters with submerged macrophytes than those without submerged plants at a given nutrient level. We hypothesize that presence of submerged macrophytes would lower phytoplankton biomass below levels expected by total phosphorus levels through various mechanisms and that phytoplankton biomass would decrease more as the biomass increase of the submerged macrophytes. To find submerged macrophytes effectively lowering phytoplankton growth, we conducted spatial field surveys at 21 water bodies and a temporal monitoring at Seung-un 1 Reservoir, Anmyyeondo Island. We measured chlorophyll ${\alpha}$ concentrations and total phosphorus (TP) concentrations from waters in patches of submerged macrophytes with measurements of submerged plant biomass. Majority of our sites with submerged macrophytes showed much less chlorophyll a concentrations than the predicted ones from literature. Among submerged macrophytes studied, Myriophyllum spicatum and Hydrilla verticillata showed patterns of lowering chlorophyll ${\alpha}/TP$ ratios with increase of their biomass in both spatial and temporal surveys.

Effects of thinning intensity on nutrient concentration and enzyme activity in Larix kaempferi forest soils

  • Kim, Seongjun;Han, Seung Hyun;Li, Guanlin;Yoon, Tae Kyung;Lee, Sang-Tae;Kim, Choonsig;Son, Yowhan
    • Journal of Ecology and Environment
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    • v.40 no.1
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    • pp.5-11
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    • 2016
  • Background: As the decomposition of lignocellulosic compounds is a rate-limiting stage in the nutrient mineralization from organic matters, elucidation of the changes in soil enzyme activity can provide insight into the nutrient dynamics and ecosystem functioning. The current study aimed to assess the effect of thinning intensities on soil conditions. Un-thinned control, 20 % thinning, and 30 % thinning treatments were applied to a Larix kaempferi forest, and total carbon and nitrogen, total carbon to total nitrogen ratio, extractable nutrients (inorganic nitrogen, phosphorus, calcium, magnesium, potassium), and enzyme activities (acid phosphatase, ${\beta}$-glucosidase, ${\beta}$-xylosidase, ${\beta}$-glucosaminidase) were investigated. Results: Total carbon and nitrogen concentrations were significantly increased in the 30 % thinning treatment, whereas both the 20 and 30 % thinning treatments did not change total carbon to total nitrogen ratio. Inorganic nitrogen and extractable calcium and magnesium concentrations were significantly increased in the 20 % thinning treatment; however, no significant changes were found for extractable phosphorus and potassium concentrations either in the 20 or the 30 % thinning treatment. However, the applied thinning intensities had no significant influences on acid phosphatase, ${\beta}$-glucosidase, ${\beta}$-xylosidase, and ${\beta}$-glucosaminidase activities. Conclusions: These results indicated that thinning can elevate soil organic matter quantity and nutrient availability, and different thinning intensities may affect extractable soil nutrients inconsistently. The results also demonstrated that such inconsistent patterns in extractable nutrient concentrations after thinning might not be fully explained by the shifts in the enzyme-mediated nutrient mineralization.

Effects of Methanol Extracts from Rhynchosia nulubilis on serum Lipid Concentrations in Rats fed High Fat and High Cholesterol Diet (서목태(Rhynchosia nulubilis) 추출물이 고지방 및 고콜레스테롤 식이 급여 흰쥐의 혈청 지질 농도에 미치는 영향)

  • Han, Sung-Hee;Shin, Mee-Kyung
    • Journal of the Korean Society of Food Culture
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    • v.17 no.1
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    • pp.64-69
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    • 2002
  • The effects of the Rhynchosia nulubilis extracts on serum lipid concentrations were evaluated in rats. Forty-two male Sprague-Dawley rats weighing $100{\pm}10g$ were divided into six groups and fed high fat and high cholesterol diets for four weeks. Experimental groups were administered with following diets; basal fat diet(control) and basal and high fat diets with 1% cholesterol and Rhynchosia nulubilis extract(40mg/kg, 400mg/kg and 4000mg/kg). The concentrations of serum triglyceride in rats fed the Rhynchosis mulubilis extract, high fat, 1% cholesterol, and RN-HFC(-40, -400, -4000mg/kg) groups were lower than those in other groups. The concentrations of total cholesterol in the RN-HFC (-40, -400, -4000mg/kg) groups were lower than those in fat diet groups. The concentrations of HDL-cholesterol in serum of the RN-HFC(-40, -400, 4000mg/kg) groups were significantly higer than those of other groups. The levels of LDL-cholesterol in serum of the RN-HFC(-40, -400, -4000mg/kg) groups were tended to be lower than those of other groups. These results suggest that Rhynchosia nulubilis extract may reduce elevated levels of serum lipid concentrations in rats fed high fat diets.