• Title/Summary/Keyword: Total Volatile organic compounds

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An Experimental Study on the Benefit of Pre-ventilation Using Solar Sunroof (쏠라 썬루프를 이용한 주차환기 시스템의 효과에 관한 실험적 연구)

  • Lee, Daewoong
    • Transactions of the Korean Society of Automotive Engineers
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    • v.22 no.6
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    • pp.89-95
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    • 2014
  • This study presented the benefit of the pre-ventilation using solar sunroof with integrated photovoltaic. Recent year, auto-makers make an effort to enhance the fuel efficiency and moreover to clean the cabin passenger's health. Solar energy, one of the alternative energies, adapted in automotive air handling system, in order to pre-ventilation when vehicle parked under the sun in summer. The power generated by a prototype solar sunroof has been used to run blower in a air handing system. And the solar sunroof was installed in a vehicle, and evaluated to find out benefit of the pre-ventilation. The effect of reducing the cabin temperature about $3^{\circ}C{\sim}10^{\circ}C$ with 20 ~ 40W power generator from solar sunroof were obtained in the pre-ventilation test. This reduced thermal load can lead to the reduction of air-conditioning operation time than that of current car. Moreover, fuel economy may increase as a results of the short use of the air-conditioning time. Additionally, Total Volatile Organic Compounds in the cabin is reduced maximum 80% than that of the current vehicle.

A study on the economic analysis of the SL(Self Leveling) Inorganic Floor covering (SL 무기질 바닥재의 경제성 분석에 관한 연구)

  • Park, Ho-Geun;Hong, Seong-Wook;Yang, Je-Yong;Kim, Sang-Won;Shin, Chan-Ho;Choe, Min-Kwon
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.05b
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    • pp.105-109
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    • 2011
  • This study is concerned with the development of the SL inorganic floor covering. First, volatile organic compounds, inorganic test profile on the SL through the flooring is environment-friendly inorganic noncombustible floor finishes the event of fire toxic gases (such as volatile organic compounds) emissions have been identified as not at all. Second, SL-breathable material, the concrete floor to prevent aging, long life, which are three levels of noise, shock-absorbing function was decreased. Third, SL economic analysis of mineral flooring terrazzo tile floors compared with the normal material. On a terrazzo tile cost 13,500 won ~ 24,500 won, but It have found that, in terms of labor SL 36,899 won ~ 38,899 won flooring mineral balance. Occurs in the total amount when compared with terrazzo tile floors and 25,399 won 3T, 5T and economical analysis concludes that the original 12,399 won.

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VOCs Emission Characteristics and Mass Contribution Analysis at Wanju Industrial Area (완주지역의 VOCs 배출특성에 따른 공단지역과 일반지역의 기여도 분석)

  • Kim, Deug-Soo;Yang, Go-Soo;Park, Bi-O
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.5
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    • pp.562-573
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    • 2008
  • Concentrations of volatile organic compounds (VOCs) measured from the local industrial sources in Wanju industrial complex during June $2007{\sim}January$ 2008. The samples were collected from the primary sources (6 emission points) in 4 major factories in Wanju industrial complex as well as two general sources in Wanju County to elucidate the abundances of speciated VOCs and their spacial and temporal distributions depending on source bases. Industrial sources are as follows; fabricated metal manufacture, motor vehicle manufacture, rubber and plastic manufacture, and chemical manufacture factories. Two general source samples were collected from gasoline gas station and dry cleaning shop in urban area. In order to understand the near source influence at receptor, samples from the two receptor sites (one is at center of the industrial complex and the other site is at distance residential area downwind from the center) were collected with sample canister, and analyzed by using GC/MSD. The concentrations from different sources were compared and discussed. The mass contributions of the speciated VOCs to total VOCs measured from industrial sources and ambient ai r at two receptors were presented and discussed.

The Concentration Variation of Volatile Organic Compounds before and after Renovation in Apartment Houses (아파트 개조 전후의 휘발성유기화합물 농도변화 실태)

  • Choi, Yoon-Jung;Shim, Hyun-Suk;Shin, Hae-Chul
    • Journal of the Korean housing association
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    • v.18 no.4
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    • pp.59-67
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    • 2007
  • The purposes of this study were to make clear the present condition of the TVOC and HCHO concentration after renovation in apartment houses. The field measurements of TVOC and HCHO concentration according to the Korea Test Method Standard for Indoor Air Quality were carried out in 4 subject apartment houses. The results are as follows; the TVOC concentration after renovation in apartment houses ranged from mean 0.35ppm to mean 5.08ppm and increased of $0.35{\sim}5.08ppm$. The TVOC concentration of 3 subjects exceeded the Indoor Air Quality Management standard for the newly-built apartment houses (0.58ppm). The HCHO concentration after renovation ranged from mean 0.13ppm to mean 0.43ppm and increased of $0.06{\sim}0.26ppm$. The HCHO concentration of 2 subjects exceeded the Standard (0.17ppm). As results of analysis on the relation of concentrated ascension and renovation elements, the amount and the types of finishing materials and adhesives affected concentrated ascension. Also, production method for installed or purchased furniture had certain effect on the TVOC and HCHO concentration ascension.

The Determination of Diffusion and Partition Coefficients of Indoor Bottom Finishing Materials (바닥재의 확산계수 및 분배계수 산정)

  • Park, Jin-Soo;Little, John C.;Kim, Shin-Do;Yun, Joong-Seop
    • Journal of Environmental Health Sciences
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    • v.34 no.3
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    • pp.219-225
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    • 2008
  • Many building materials may contain high concentrations of volatile organic compounds (VOCs) and other hazardous pollutants(HAPs). Specifically, VOCs discharged by indoor building material may cause "new house" syndrome, atopic dermatitis etc. The diffusion coefficient and initially contained total VOC quantity were determined using microbalance experiments and small chamber tests. Interactions between volatile organic compounds (VOCs) and vinyl flooring (VF), a relatively homogenous, diffusion-controlled building material, were characterized. Rapid determination of the material/air partition coefficient (K) and the material-phase diffusion coefficient (D) for each VOC was achieved by placing thin VF slabs in a dynamic microbalance and subjecting them to controlled sorption/desorption cycles. K and D are shown to be independent of concentration for all of the VOCs and water vapor. This approach can be applied to other diffusion-controlled materials and should facilitate the prediction of their source/sink behavior using physically-based models.

Measurement and Estimation of VOC Composition from Gasoline Evaporation

  • Na, K.;Moon, K.-C.;Kim, Y.P.
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.E3
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    • pp.101-107
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    • 2001
  • Source profiles were developed for a total of 45 volatile organic compounds (VOC) that can be emitted from gasoline evaporation. The gasoline samples of five major brands (for each season) were blended on the basis of the market share in Seoul area and analyzed by a GC-MS/FID system. In addition, we calculated gasoline evaporative compositions using the Raoult's law from the liquid gasoline compositions. The measured and estimated gasoline vapor compositions agree well each other. As a group, alkanes are the most abundant in the gasoline vapors profiles (77.4% on average), followed by alkenes (19.1%), and aromatics (1.7%). As a specie in gasoline vapor, i-pentane is the most abundant, followed by n-butane, n-pentane, i-butane, trans-and cis-2-butenes, 2-methyl-2-butene, and trans-and cis-2-pentenes . It was also seen that aromatic content was much lower in the vapor phase compositions. From the comparison between experimental and calculated compositions, we identified the fact that once the gasoline vapor composition is reliably constructed entirely from the measured gasoline composition and the Raoult's law calculations, the need for doing separate chemical analyses of the gasoline vapor can be reduced.

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토양 및 지하수 Investigation 과 Remediation에 대한 현장적용

  • Wallner, Heinz
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.11a
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    • pp.44-63
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    • 2000
  • Situated close to Heathrow Airport, and adjacent to the M4 and M25 Motorways, the site at Axis Park is considered a prime location for business in the UK. In consequnce two of the UK's major property development companies, MEPC and Redrew Homes sought the expertise of Intergeo to remediate the contaminated former industrial site prior to its development. Industrial use of the twenty-six hectare site, started in 1936, when Hawker Aircraft commence aircraft manufacture. In 1963 the Firestone Tyre and Rubber Company purchased part of the site. Ford commenced vehicle production at the site in the mid-1970's and production was continued by Iveco Ford from 1986 to the plant's decommissioning in 1997. Geologically the site is underlain by sand and gravel, deposited in prehistory by the River Thames, with London Clay at around 6m depth. The level of groundwater fluctuates seasonally at around 2.5m depth, moving slowly southwest towards local streams and watercourses. A phased investigation of the site was undertaken, which culminated in the extensive site investigation undertaken by Intergeo in 1998. In total 50 boreholes, 90 probeholes and 60 trial pits were used to investigate the site and around 4000 solid and 1300 liquid samples were tested in the laboratory for chemical substances. The investigations identified total petroleum hydrocarbons in the soil up to 25, 000mg/kg. Diesel oil, with some lubricating oil were the main components. Volatile organic compounds were identified in the groundwater in excess of 10mg/l. Specific substances included trichloromethane, trichloromethane and tetrachloroethene. Both the oil and volatile compounds were widely spread across the site, The specific substances identified could be traced back to industrial processes used at one or other dates in the sites history Slightly elevated levels of toxic metals and polycyclic aromatic hydrocarbons were also identified locally. Prior to remediation of the site and throughout its progress, extensive liaison with the regulatory authorities and the client's professional representatives was required. In addition to meetings, numerous technical documents detailing methods and health and safety issues were required in order to comply with UK environmental and safety legislation. After initially considering a range of options to undertake remediation, the following three main techniques were selected: ex-situ bioremediation of hydrocarbon contaminated soils, skimming of free floating hydrocarbon product from the water surface at wells and excavations and air stripping of volatile organic compounds from groundwater recovered from wells. The achievements were as follows: 1) 350, 000m3 of soil was excavated and 112, 000m3 of sand and gravel was processed to remove gravel and cobble sized particles; 2) 53, 000m3 of hydrocarbon contaminated soil was bioremediated in windrows ; 3) 7000m3 of groundwater was processed by skimming to remove free floating Product; 4) 196, 000m3 of groundwater was Processed by air stripping to remove volatile organic compounds. Only 1000m3 of soil left the site for disposal in licensed waste facilities Given the costs of disposal in the UK, the selected methods represented a considerable cost saving to the Clients. All other soil was engineered back into the ground to a precise geotechnical specification. The following objective levels were achieved across the site 1) By a Risk Based Corrective Action (RBCA) methodology it was demonstrated that soil with less that 1000mg/kg total petroleum hydrocarbons did not pose a hazard to health or water resources and therefore, could remain insitu; 2) Soils destined for the residential areas of the site were remediated to 250mg/kg total petroleum hydrocarbons; in the industrial areas 500mg/kg was proven acceptable. 3) Hydrocarbons in groundwater were remediated to below the Dutch Intervegtion Level of 0.6mg/1; 4) Volatile organic compounds/BTEX group substances were reduced to below the Dutch Intervention Levels; 5) Polycyclic aromatic hydrocarbons and metals were below Inter-departmental Committee for the Redevelopment of Contaminated Land guideline levels for intended enduse. In order to verify the qualify of the work 1500 chemical test results were submitted for the purpose of validation. Quality assurance checks were undertaken by independent consultants and at an independent laboratory selected by Intergeo. Long term monitoring of water quality was undertaken for a period of one year after remediation work had been completed. Both the regulatory authorities and Clients representatives endorsed the quality of remediation now completed at the site. Subsequent to completion of the remediation work Redrew Homes constructed a prestige housing development. The properties at "Belvedere Place" retailed at premium prices. On the MEPC site the Post Office, amongst others, has located a major sorting office for the London area. Exceptionally high standards of remediation, control and documentation were a requirement for the work undertaken here.aken here.

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Study on Indoor Air Pollutants of Public Service Centers in Winter, Seoul (서울지역 공공청사 민원실의 겨울철 실내공기질에 관한 연구)

  • Jeon, Jea-Sik;Kim, Mi-Hyung;Lee, Ju-Yeol;Jeon, Myung-Jin;Ryu, In-Cheol;Park, Duck-Shin;Choi, Han-Young
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.5
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    • pp.569-579
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    • 2011
  • This study evaluated the indoor air quality of 26 government offices located in Seoul. The pollutant samples were taken from Jan. 13th to Jan. 29th and Feb. 20th to Feb. 23rd, 2010 in the offices. The target indoor pollutants for this study were $PM_{10}$, formaldehyde, carbon monoxide, carbon dioxide, total bacteria counts, total volatile organic compounds, radon, nitrogen dioxide, ozone, and asbestos which were controlled by the indoor air quality law for the multiple-use facilities management. The results of this study showed that some pollutants of the 38.5% offices exceeded the standards of the air quality guideline. The correlation analysis of the same pollutants between indoor and outdoor represented that $NO_2$ (r=0.629, p<0.05) and $O_3$ (r=0.459, p<0.01) were significant, however, $PM_{10}$ and CO were not. The correlation analysis between different pollutants showed that CO and TVOC (total volatile organic compounds: r=0.724; p<0.01), CO and $NO_2$ (r=0.674; p<0.01), HCHO and humidity (r=0.605; p<0.01), $CO_2$ and TVOC (r=0.534; p<0.01), TBC (total bacteria counts) and Asbestos (r=0.520; p<0.01) were significant. The energy-saving system of government buildings in winter caused under-ventilated and poor air quality. This study suggests that the concentrations of radon and $CO_2$ should be used as an indicator for monitoring indoor air quality and maintaining effective ventilations.

Identification of Coffee Fragrances Using Needle Trap Device-Gas Chromatograph/Mass Spectrometry (NTD-GC/MS)

  • Eom, In-Yong;Jung, Min-Ji
    • Bulletin of the Korean Chemical Society
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    • v.34 no.6
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    • pp.1703-1707
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    • 2013
  • A fast and simple sampling and sample preparation device, (NTD) has been developed and applied to sample and analyze volatile components from ground coffee beans. Coffee fragrances and other volatile organic compounds (VOCs) were sampled by the NTD and then analyzed by gas chromatograph-mass spectrometry (GC/MS). Divinylbenzene (DVB) particles (80/100 mesh size) were the sorbent bed of the NTD. More than 150 volatile components were first identified based on the database of the mass library and then finally 30 fragrances including caffeine were further confirmed by comparing experimental retention indices (i.e. Kovat index) with literature retention indices. Total sampling time was 10 minutes and no extra solvent extraction and/or reconstitution step need. Straight n-alkanes (C6-C20) were used as retention index probes for the calculation of experimental retention indices. In addition, this report suggests that an empty needle can be an alternative platform for analyzing polymers by pyrolysis-GC/MS.

Chemical and Sensory Characterization of Korean Commercial Rice Wines (Yakju)

  • Lee, Seung-Joo;Kwon, Young-Hee;Kim, Hye-Ryun;Ahn, Byung-Hak
    • Food Science and Biotechnology
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    • v.16 no.3
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    • pp.374-380
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    • 2007
  • Chemical and sensory profiles of 5 Korean commercial rice wines (yakju) were developed using descriptive, physicochemical, and volatile analyses. Color, 6 aroma, and 5 taste attributes of these rice wines were evaluated by a panel of 13 judges. Sample wines were analyzed for titratable acidity, ethanol content, pH, Hunter colorimeter value, organic acids, and free sugars. Volatile analysis of the samples revealed the presence of 2 acids, 7 alcohols, 19 esters, and 5 miscellaneous compounds. Based on principal component analysis of the descriptive data, rice wines were primarily separated along the first principal component, which accounted for 57% of the total variance between the rice wines with high intensities of 'color' and 'sweet aroma' versus 'ginseng' aroma.