• Title/Summary/Keyword: Torsion angle

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Structure of Fluorometholone (Fluorometholone 의 구조)

  • Young Ja Park;Mee Youn Lee;Sung Il Cho
    • Journal of the Korean Chemical Society
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    • v.36 no.6
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    • pp.812-817
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    • 1992
  • Fluorometholone $(C_{22}H_{29}FO_4)$, M.W. = 376.5, monoclinic, $P2_1$, a = 6.410(4), b = 13.431(3), c = 10.996(3)$\AA$, $\beta$ = 92.81$(3)^{\circ}$, Z = 2, F(000) = 404, T = 292K, $\lambda$(Mo-$K_\alpha$) = 0.7107$\AA$, $\mu$ = 0.57$cm^{-1}$, $D_c$ = 1.32 $g/cm^3$, $D_m$ = 1.31 $g/cm^3$ and final R = 0.032 for 1769 observed reflections. All bond lengths and angles are within normal limits. Ring A is almost planar, B ring has a highly symmetrical chair conformation and C ring is in a distorted chair conformation. Ring D is in a intermediate conformation between 13$\alpha$-14$\beta$-half-chair and 13$\alpha$-envelope. Torsion angle C(16)-C(17)-C(20)-O(20) of $-7.9^{\circ}$ is a lower value than those of $-31.9^{\circ}$ and $-16.5^{\circ}$ for 9-fluoro-6-methylprednisolone I and II respectively.

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Kinematic Analysis on the Mogul Short Turn Motion in Interski (인터스키 부정지 숏턴 동작의 운동학적 분석)

  • Joo, Hyun-Sik;Park, Jong-Hoon;Lee, Gye-San;Kim, Won-Kyoung;Park, Jong-Chul;Back, Jin-Ho
    • Korean Journal of Applied Biomechanics
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    • v.18 no.4
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    • pp.67-76
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    • 2008
  • The purpose of this study was to analyze differences in kinematic variables for mogul short turn motion between superior and inferior group, so that it can explore more effective mogul short turn motions. To meet the goals, this study selected total 10 ski players who would participate in mogul short turn event of the National Technical Ski Championship 2007, so that it could analyze kinematic variables by way of 3D motion analysis using DLT method. As a result, this study came to the following conclusions; For total and phase-specific duration, it was found that superior group took shorter time than inferior group. Superior group's Center of Mass was stands for more high value in up-down movement skill than inferior group. However right-left movement scale was less than them. In this reason, superior group was made a straight descent at the same time made a fast front-rear velocity. In the part of up-down movement velocity show that move slowly in the drop-in phase while increased in the bump-up phase. It is show that superior group was less tinny than inferior group include joint angle and knee joint angle. However leaning angle of trunk and the body inclination angle were more high figured than inferior group. Leaning angle of lower limbs also showed high figure at the center mogul. Lastly, In the part of body torsion angle show that superior group was high figure direction of right turn in the drop-in phase while in bump-up phase, made a high figure direction of left turn.

Differences in Static Lower Extremity Alignment according to the History of Lateral Ankle Sprain: Efficacy and Limitation of Static Lower Limb Alignment Measurement as a Predictor of Lateral Ankle Sprain (외측 발목 염좌 병력에 따른 정적 하지 정렬 차이: 외측 발목 염좌의 예측인자로서 정적 하지 정렬 검사의 효용성과 한계점)

  • Jeon, Hyung Gyu;Ha, Sunghe;Lee, Inje;Kang, Tae Kyu;Kim, Eun Sung;Lee, Sae Yong
    • Korean Journal of Applied Biomechanics
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    • v.31 no.1
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    • pp.1-15
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    • 2021
  • Objective: The aim of this study was to investigate 1) the difference in static lower extremity alignment (SLEA) according to a history of lateral ankle sprain (LAS), 2) to identify SLEA factors affecting LAS, and 3) to present the cut-off value and 4) the usefulness and limitations of the SLEA measurement. Method: This case-control study recruited 88 men (age: 27.78±4.69 yrs) and 39 women (age: 24.62±4.20 yrs) subjects with and without LAS. SLEA measurement protocol included Q angle, tibiofemoral angle, genu recurvatum, rear foot (RF) angle, tibal varum and torsion, navicular drop, ankle dorsiflexion range of motion (DF ROM). Independent t-test, logistic regression and receiver operating characteristic (ROC) curve were used for statistical analysis. Results: Men with a history of LAS had significantly smaller Q angles both in standing and in supine position, while women with a history of LAS had significantly greater DF ROM in non-weight bearing (NWB; p < 0.05). Logistic regression model suggests tibial varum (OR = 0.779, p = 0.021) and WB DF ROM (OR = 1.067, p = 0.045) were associated with LAS in men. In case of women, there were no significant SLEA factors for LAS, however, ROC curve analysis revealed standing RF angle (AUC = 0.647, p = 0.028) and NWB DF ROM (AUC = 0.648, p = 0.026) could be affecting factors for LAS. Conclusion: There are differences in SLEA according to the history of LAS, furthermore, the identified items were different by sex. In case of men, tibial varum and WB DF ROM affect LAS occurrence. Standing RF angle and NWB DF ROM of women could be a predictor for LAS. However, since the sensitivity and specificity in most of the SLEA measurements are low, kinematic in dynamic tasks should be considered together for a more accurate evaluation of LAS risk.

Comparison of Trunk Strategy to Maintain Balance during the One-Leg Stance on a Medio-Lateral Ramp and an Anterior-Posterior Ramp

  • Lee, Sang-Yeol;Lee, Myoung-Hee
    • The Journal of Korean Physical Therapy
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    • v.29 no.4
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    • pp.223-226
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    • 2017
  • Purpose: This study examined two trunk strategies - medio-lateral ramp and anterior-posterior ram - and their effects on pelvis and trunk movements, providing basic material for safe ramp utilization. Methods: The present study included 20 asymptomatic males recruited from a local university. Participants were asked to stand with their feet shoulder-width apart. Their dorsal side faced the camera, and measurements were performed while standing in a neutral double stance, one leg stance, $15^{\circ}$ of medial and lateral ramp, and $15^{\circ}$ of anterior and posterior ramp. Participants were allowed to practice for 3 minutes, and each participant had a 30 seconds rest between the two ramp conditions. One-way repeated measures analysis of variance was used to determine the effects the ramp conditions on spinal alignment. In all analyses, p<0.05 was used to indicate statistical significance. Results: The trunk-inclination angle on the posterior ramp was significantly lower than that of the double stance position (p<0.05). The trunk imbalance angle was significantly higher on the medial ramp, than that on the double stance position (p<0.05). The pelvic position and pelvic torsion angles were significantly higher in the medial, lateral, and anterior ramp positions than that of the double stance position (p<0.05). The pelvic rotation angles on the medial, lateral, and anterior ramps were significantly lower than that of the double stance position (p<0.05). Conclusion: These findings suggest that when people are exposed to the same form of ramp for an extended period, posture modifications may be triggered.

Toluene-4-sulfonic Acid 4-Allyl-2,6-dimethoxy-phenyl Ester

  • Choi, Kyu-Yong;Han, Byung-Hee;Kang, Sung-Kwon;Sung, Chang-Keun;Kang, Sang-Ook;Suh, Il-Hwan
    • Korean Journal of Crystallography
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    • v.15 no.1
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    • pp.1-4
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    • 2004
  • The title compound, $C_{18}H_{20}O_5S$, crystallized in the centrosymmetric space group $P\={1}$ with one molecule in an asymmetric unit. The S atom in the sulfonate group retains the overall tetrahedral environment of the O and C atoms with an average S-O bond of 1.420(2) ${\AA}$ for double bond and of 1.598(2) ${\AA}$ for single bond and S-C length of 1.742(3) ${\AA}$. The torsion angle C(7)-S-O(3)-C(8) is 100.3(2)$^{\circ}$ and the dihedral angle of the two planar six-membered rings is 42.73(20)$^{\circ}$.

Bend-Twist Coupling Behavior of 10 MW Composite Wind Blade (10 MW급 복합재 풍력 블레이드의 굽힘-비틀림 커플링 거동 연구)

  • Kim, Soo-Hyun;Shin, Hyungki;Bang, Hyung-Joon
    • Composites Research
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    • v.29 no.6
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    • pp.369-374
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    • 2016
  • In this study, a structural optimal design of 10 MW composite blade was performed using bend-twist coupled(BTC) design concept. Bend-twist coupling of blade means the coupling behavior between the bending and torsional deflections due to the composite lamina with fiber angle biased from the blade longitudinal axis. This can potentially improve the overall performance of composite blade and reduce the dynamic loading. Parametric studies on layup angle, thickness and area of off-axis carbon UD were conducted to find the optimum coupling effect with weight reduction. Comparing the results of fatigue load analysis between conventional model and BTC applied model, the damage equivalent load(DEL) of blade root area were decreased about 3% in BTC model. To verify the BTC effect experimentally, a 1:29 scaled model was fabricated and the torsion at the tip under deflection behavior of blade stiffener model was measured by static load test.

An Experimental Investigation of the Aeroelastic Stability of Next-Generation Blade for Helicopter (헬리콥터용 차세대 블레이드의 공력탄성학적 안정성에 관한 시험적 연구)

  • Song, Keun-Woong;Kim, Joune-Ho;Kim, Seung-Ho;Lee, Je-Dong;Rhee, Wook
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2006.05a
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    • pp.680-685
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    • 2006
  • This paper describes the aeroelastic stability test of the small-scaled 'Next-Generation Blade(NRSB)' with NRSH (Next-Generation Hub System) and HCTH hingeless hub system in hover and forward flight conditions. Excitation tests of rotor system installed in GSRTS(General Small-scale Rotor Test System) at KARI(Korea Aerospace Research Institute) were tarried out to get lead-lag damping ratio of blades with flexures as hub flexure. MBA(Moving Block Analysis) technique was used for the estimation of lead-lag damping ratio. First, NRSB-1F blades with HCTH hub system, Then NRSB-1F with NRSH hub system were tested. Second, NRSB-2F blades with NRSH hub system were tested. Tests were done on the ground and in the wind tunnel according to the test conditions of hover and forward flight, respectively. Non-rotating natural frequencies, non-rotating damping ratios and rotating natural frequencies were showed similar level fir each cases. Estimated damping ratios of NRSB-1F, NRSB-2F with HCTH and NRSH were above 0.5%, and damping ratio increased by collective pitch angle increasement. Furthermore damping ratios of NRSB-2F were higher than damping ratios of NRSB-1F in high pitch angle. It was confirmed that the blade design for noise reduction would give observable improvement in aeroelastic stability compared to paddle blade and NRSB-1F design.

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An Experimental Investigation of the Aeroelastic Stability of Next-generation Blade for Helicopter (헬리콥터용 차세대 블레이드의 공력탄성학적 안정성에 관한 시험적 연구)

  • Kim, Joune-Ho;Kim, Seung-Ho;Lee, Je-Dong;Rhee, Wook;Song, Keun-Woong
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.16 no.8 s.113
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    • pp.848-856
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    • 2006
  • This paper describes the aeroelastic stability test of the small-scaled 'Next-generation Blade(NRSB)' with NRSH (next-generation hub system) and HCTH hingeless hub system in hover and forward flight conditions. Excitation tests of rotor system installed in GSRTS (general small-scale rotor test system) at KARI (Korea Aerospace Research Institute) were carried out to get lead-lag damping ratio of blades with flexures as hub flexure. MBA(moving block analysis) technique was used for the estimation of lead-lag damping ratio. First, NRSB-1F blades with HCTH hub system, then NRSB- 1F with NRSH hub system were tested. Second, NRSB-2F blades with NRSH hub system were tested. Tests were done on the ground and in the wind tunnel according to the test conditions of hover and forward flight, respectively. Non-rotating natural frequencies, non-rotating damping ratios and rotating natural frequencies were showed similar level for each cases. Estimated damping ratios of NRSB-1F, NRSB-2F with HCTH and NRSH were above 0.5%, and damping ratio increased by collective pitch angle increasement. Furthermore damping ratios of NRSB-2F were higher than damping ratios of NRSB-1F in high Pitch angle. It was confirmed that the blade design for noise reduction would give observable improvement in aeroelastic stability compared to paddle blade and NRSB-1F design.

Investigation on wind stability of three-tower cable-stayed-suspension hybrid bridges under skew wind

  • Xin-Jun Zhang;Li Bowen;Nan Zhou
    • Wind and Structures
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    • v.38 no.6
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    • pp.427-443
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    • 2024
  • By using a computational program of three-dimensional aerostatic and aerodynamic stability analysis of long-span bridges under skew wind, the dynamic characteristics and structural stability(including the aerostatic and aerodynamic stability) of a three-tower cable-stayed-suspension hybrid bridge with main span of 1 400 meters are investigated numerically under skew wind, and the skew wind and aerostatic effects on the aerostatic and aerodynamic stability of three-tower cable-stayedsuspension hybrid bridge are ascertained. The results show that the three-tower cable-stayed-suspension hybrid bridge is a longspan structure with greater flexibility, and it is more susceptible to the wind action. The aerostatic instability of three-tower cable-stayed-suspension hybrid bridges is characterized by the coupling of vertical bending and torsion of the girder, and the skew wind does not affect the aerostatic instability mode. The skew wind has positive or negative effects on the aerostatic stability of the bridge, the influence is between -5.38% and 4.64%, and in most cases, it reduces the aerostatic stability of the bridge. With the increase of wind yaw angle, the critical wind speed of aerostatic instability does not vary as the cosine rule as proposed by the skew wind decomposition method, the skew wind decomposition method may overestimate the aerostatic stability, and the maximum overestimation is 16.7%. The flutter critical wind speed fluctuates with the increase of wind yaw angle, and it may reach to the minimum value under the skew wind. The skew wind has limited effect on the aerodynamic stability of three-tower cable-stayed-suspension hybrid bridge, however the aerostatic effect significantly reduces the aerodynamic stability of the bridge under skew wind, the reduction is between 3.66% and 21.86%, with an overall average drop of 11.59%. The combined effect of skew and static winds further reduces the critical flutter wind speed, the decrease is between 7.91% and 19.37%, with an overall average decrease of 11.85%. Therefore, the effects of skew and static winds must be comprehensively considered in the aerostatic and aerodynamic stability analysis of three-tower cable-stayed-suspension hybrid bridges.

Ultraviolet Resonance Raman Spectroscopy of Bacteriorhodopsin and Its Photointermediates

  • Hashimoto, Shinji
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.114-117
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    • 2002
  • Ultraviolet resonance Raman (UVRR) spectroscopy was used to elucidate the dynamic change of the protein structure of bacteriorhodopsin (BR) during the photocycle. The photointermediates minus light- adapted (LA) BR difference spectra show Trp difference signals, which are assigned to Trp189 or Trp182 on helix F by using the mutants, W182F and W189F. The Difference signals of Trp 182 indicates an increase in hydrogen bonding strength at the indole nitrogen and a large change in the side chain conformation (X$\^$2,1/ torsion angle) in the M$_1$ \longrightarrow M$_2$ transition. On the other hand, Trp189 shows an increased hydrophobic interaction. These results suggest that the tilt of helix F occurs in the M$_1$\longrightarrow M$_2$ transition. In the M$_2$ \longrightarrow N transition, the hydrophobic interaction of Trp182 decreases drastically, The decrease in hydrophobic interaction of Trp182 in the N state suggests an invasion of water molecules that promote the proton transfer from Asp96 to the Schiff base. Structural reorganization of the protein after the tilt of helix F may be important for efficient reprotonation of the Schiff base.

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