• Journal of Hydrogen and New Energy
• /
• v.5 no.1
• /
• pp.41-49
• /
• 1994

Ti-Bi alloy was prepared by arc melting of appropriate amounts of titanium and bismuth powder. The photocurrent($I_{ph}$) of Ti-Bi oxide electrode was increased with the increase of Bi content, up to 10wt%. The maximum $I_{ph}$ showed $7.6mA/cm^2$ at V=0.5V vs. SCE. The band gap energy of Ti-Bi oxide electrode was observed to 3.0~2.87eV. Surface barrier($V_s$) of Ti-10Bi oxide electrode showed maximum value(1.08V) but didn't exceed 1.23V, then it was impossible to run $H_2$ generation without any other energy sources other than the light. Ti-Bi oxide electrode was found to be quite stable under alkaline solution and showed no signs of photodecomposition.

• Corrosion Science and Technology
• /
• v.11 no.5
• /
• pp.196-204
• /
• 2012

Corrosion failure of petrochemical facilities is one of the difficulties in maintenance, since operating conditions of crude oil production, storage, and refinement are very aggressive. UNS N08810, which has been used for crude oil transportation pipes and storage tanks in petrochemical industries, shows good resistance to general corrosion and localized corrosion in several environments. Among its environments, UNS N08810 showed better corrosion resistance in fuel gas containing sulfuric acid and phosphoric acid and sulfur. However, ductility and toughness at high temperature over about $500^{\circ}C$ were greatly reduced due to microstructural change. In general, welding process is the representative method to join the parts in industrial components. Because the alloy by welding can be sensitized and corroded, the manufacturing process should be controlled. In this work, UNS N08810 was used and heat treatment conditions including solution and stabilization treatments were controlled. Oxalic acid etch test by ASTM A262 Practice A was done to evaluate the qualitative sensitization in room temperature. Huey test by ASTM A262 Practice C was done to evaluate the intergranular corrosion rate in boiling 65% $HNO_3$ solution. Also, the microstructure by thermal history was analyzed. Experimental alloy showed high intergranular corrosion rate and its corrosion mechanism was elucidated.

• Korean Journal of Materials Research
• /
• v.26 no.1
• /
• pp.13-16
• /
• 2016

Morphology and formation processes of lamellar grain boundaries in titanium rich binary TiAl intermetallics were studied. TiAl alloys containing aluminum content of 44 to 48 at.% were induction-heated to 1723 K followed by helium-gas-quenching at various temperatures. For the Ti-44%Al, few lamellae were observed in samples quenched from higher than 1473 K. Although small peaks of beta phase were detected using X-ray diffraction, only the ordered hexagonal phase (${\alpha}_2$) with clear APB contrast was observed in TEM observation. For the Ti-48 at.%Al alloy, almost no lamellar structure, and straight grain boundaries were observed in samples quenched from higher than 1623 K. The formation of lamellae along grain boundaries was observed in the sample quenched from 1573 K. The fully lamellar microstructures with serrated boundaries were observed in samples quenched from lower than 1473 K. It was found that the formation of ${\gamma}$ platelets took place at higher temperatures in Ti-48 at.%Al than in Ti-44 at.%Al. Although the size of the serration is different, serrated lamellar grain boundaries could be obtained for all alloy compositions employed. The serration appeared to be due to the grain boundary migration induced by precipitation and growth of ${\gamma}$. Differences in transformation characteristics with aluminum content are discussed.

• Korean Journal of Materials Research
• /
• v.9 no.2
• /
• pp.199-204
• /
• 1999

As the engine design change to get high efficiency and performance of commercial diesel engine, surface wear of the cam follower becomes an important issues as applied load increasing at the contact face between cam follower and cam. Purpose of this study is the developing of the ceramic cam follower made of silicon nitride ceramic which is more wear resistant than the cast iron and sintered cam follower. Ceramic cam follower was made by direct brazing of thin ceramic disk to steel can follower body using active bracing alloy. Effect of joining condition on the interfacial phases and joining strength wer examined at bvarious joining temperatures, times, and cooling rates. Crowning resulted from the difference of thermal expansion coefficient after direct brazing without using any stress-relieving inter layer was measured. Interfacial phases are mainly titanium silicide and titanium nitride which are the products between active metal(Ti) in brazing alloy and silicon nitiride. Maximum joining strength of the ceramic metal joint, measured by DBS method, was 334MPa. Crowning(R) of the prototype ceramic cam follower was 1595mm. As machining for crowning is not necessary, production cost can be reduced.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.5 no.1
• /
• pp.129-135
• /
• 1997

Previous studies has shown that the curve of low-cycle fatigue life was not expressed with the single line subjected to Manson-Coffin's law type and bent to short life in low ${\Delta}{\varepsilon}_p$ region. The main cause of this phenomenon has been considered that the localization of plastic strain in the crack initiation process fosters the crack initiation. In this study, the low-cycle fatigue life was investigated for each specimens omitted crack initiation process and it was found that fatigue life curve in log(${\Delta}{\varepsilon}_p$)-log($N_f$)was bent in low ${\Delta}{\varepsilon}_p$ region as ever. Therefore, the main cause of appearance of knee point in fatigue life curve is not found in the crack initiation process but in the crack propagation process. In the crack propagation process, the localization of the plastic strain in the vicinity of crack tip and the influence of test environment on the crack propagation rate were observed and these inclinations were more remarkable in low ${\Delta}{\varepsilon}_p$ region. Hence, it was concluded that these two phenomena in the crack propagation process were proved to the main cause which accelerates the crack propagation in low ${\Delta}{\varepsilon}_p$ region and bent the fatigue life curve in result.

• Structural Engineering and Mechanics
• /
• v.56 no.3
• /
• pp.369-383
• /
• 2015

In this study, effect of various material hardening models based on Holloman's isotropic, Ziegler's linear kinematic, non-linear kinematic and mixture of the isotropic and nonlinear kinematic hardening laws on springback prediction of titanium alloy (Ti-3Al-2.5V) in a tube rotary draw bending (RDB) process was investigated with presenting the keynotes for a comprehensive step by step ABAQUS simulation. Influence of mandrel on quality of the final product including springback, wall-thinning and cross-section deformation of the tube was investigated, too. Material parameters of the hardening models were obtained based on information of a uniaxial test. In particular, in the case of combined iso-nonlinear kinematic hardening the material constants were calibrated by a simple approach based on half-cycle data instead of several stabilized cycles ones. Moreover, effect of some material and geometrical parameters on springback was carried out. The results showed that using the various hardening laws separately cannot describe the material hardening behavior correctly. Therefore, it is concluded that combining the hardening laws is a good idea to have accurate springback prediction. Totally the results are useful for predicting and controlling springback and cross-section deformation in metal forming processes.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.13 no.4
• /
• pp.113-120
• /
• 2005

In order to investigate the characteristics of penatration and the effect of surface treatment in A15052-H34, Al5082-Hl31 and titanium alloy laminates which were treated by anodizing and PVD(Physical Vapor Desposition) method, ballistic tests were conducted. Thickness of surface membrane in A15052-H34, Al5082-Hl31, were $25{\mu}m$ and that of titanium $0.9{\mu}m$ respectively. Surface hardness test was conducted using micro Vicker's hardness tester. Resistance to penetration is determined by the protection ballistic limit(V50), a statistical velocity with $50\%$ probability for complete penetration. Fracture behaviors and ballistic tolerance, described by penetration modes, are observed from the results of V50 test and Projectile Through Plate(PTP) test at velocities greater than protection ballistic limit, respectively. Present experimental results derived from this research help to optimize laminate impact behavior by varing the laminate thickness and surface treated materials.

• Biomaterials Research
• /
• v.22 no.4
• /
• pp.259-270
• /
• 2018

Background: Total hip arthroplasty (THA) is probably one of the most successful surgical interventions performed in medicine. Through the revolution of hip arthroplasty by principles of low friction arthroplasty was introduced by Sir John Charnley in 1960s. Thereafter, new bearing materials, fixation methods, and new designs has been improved. The main concern regarding failure of THA has been the biological response to particulate polyethylene debris generated by conventional metal on polyethylene bearing surfaces leading to osteolysis and aseptic loosening of the prosthesis. To resolve these problems, the materials of the modern THA were developed since then. Methods: A literature search strategy was conducted using various search terms in PUBMED. The highest quality articles that met the inclusion criteria and best answered the topics of focus of this review were selected. Key search terms included 'total hip arthroplasty', 'biomaterials', 'stainless steel', 'cobalt-chromium', 'titanium', 'polyethylene', and 'ceramic'. Results: The initial search retrieved 6921 articles. Thirty-two articles were selected and used in the review. Conclusion: This article introduces biomaterials used in THA and discusses various bearing materials in currentclinical use in THA as well as the newer biomaterials which may even further decrease wear and improve THA survivorship.

• Journal of Powder Materials
• /
• v.31 no.5
• /
• pp.365-373
• /
• 2024

This review examines the microstructural and mechanical properties of a Ti-6Al-4V alloy produced by wrought processing and powder metallurgy (PM), specifically laser powder bed fusion (LPBF) and hot isostatic pressing. Wrought methods, such as forging and rolling, create equiaxed alpha (α) and beta (β) grain structures with balanced properties, which are ideal for fatigue resistance. In contrast, PM methods, particularly LPBF, often yield a martensitic α' structure with high microhardness, enabling complex geometries but requiring post-processing to improve its properties and reduce stress. The study evaluated the effects of processing parameters on grain size, phase distribution, and material characteristics, guiding the choice of fabrication techniques for optimizing Ti-6Al-4V performance in aerospace, biomedical, and automotive applications. The analysis emphasizes tailored processing to meet advanced engineering demands.

• Journal of Advanced Marine Engineering and Technology
• /
• v.29 no.1
• /
• pp.98-106
• /
• 2005

The chemical conversion film formed on magnesium alloy was investigated by using the colloidal silica with some parameters such as solution pH. temperature, solution conditions, and treatment time. Moreover. the solutions consisted of colloidal silica titanium sulfate, and cobalt ions were used for the colloidal silica film to having a good corrosion resistance and adhesion properties. It was thought that the film at 298K was made with combination of Si-O. The quantity of film formed at high temperature such as 333K and 353K is smaller than dissolved quantity during chemical conversion treatment. Adding $CoSO_4$ to the colloidal silica solution enhanced the adhesion force between the silica film and magnesium substrate, The optimum conditions for the chemical conversion treatment solution were PH 2.90 s treatment, and 298K.