• Title/Summary/Keyword: Titanium Nitride

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NEW PROGRESS IN TiN-BASED PROTECTIVE COATINGS DEPOSITED BY ARC ION PLATING

  • Huang, R.F.;Wen, L.S.
    • Journal of the Korean institute of surface engineering
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    • v.32 no.3
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    • pp.265-275
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    • 1999
  • Titanium nitride and related overlayers produced by arc ion plating (AIP) are applied as commercial coatings in world-wide scale since the middle of 80s. Due to the achievements of low temperature deposition (LTD), they begin now to be used as wear and corrosion-resistant coatings for machine parts, besides applications on cemented carbide and high speed steel cutting tools. On the other side, TiN can be now applied successfully to brass, Al-alloy, ZnAl alloy articles as decorative coating through LTD. Various nitrides, carbonitrides, borides and other refractory compounds, such as (Ti, Al)N, TiCN, CrN, are used as the coatings for special heavy-duty working conditions instead of TiN since 90s. More and more multilayer coatings are applied now substituting single layer ones. Duplex processes are under development.

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Selective Carbonization and Nitridation of Titanium in (ZrTi)O2 Powders Synthesized by Copreciptation Method

  • Shin Soon-Gi
    • Korean Journal of Materials Research
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    • v.15 no.10
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    • pp.662-666
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    • 2005
  • Solid solutions of $(Zr/Ti)O_2$ were prepared in powder form by the coprecipitation technique. After mixing with carbon or exposing to nitrogen gas at elevated temperature, titanium cations selectively diffused out from the oxide compound to form titanium carbide (TiC) or titanium nitride (TiN), respectively. TiN formed strong interfacial contacts between the oxide grains. In contrast, TiC formed as small crystallites on oxide grains but did not bind the matrix grains together. TiN therefore played a role in strengthening the interparticle bonding, but TiC weakened the bonding between grains. Partial diffusion of titanium cations also led to nanolayered structure being formed between the oxide grains, which provided weak interfacial layers that fractured in a step-wise fashion.

The Reactions of the Ti Melt with CaO and Graphite and the Effect of Pressure on the Formation of Gas Porosity (티타늄 용탕의 산화칼슘 및 흑연과의 반응 및 기포 결함의 형성에 미치는 압력의 영향)

  • Bae, Chang-Gun;Kwon, Hae-Wook
    • Journal of Korea Foundry Society
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    • v.20 no.4
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    • pp.247-253
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    • 2000
  • Titanium was melted in the CaO-coated alumina crucible and the reaction between the melt and the coating layer was negligible. The volume fraction of the gas porosity was decreased with increasing pressure and the sound bar castings with no porosity was obtained under the Ar atmosphere of the pressure of $300kN/mm^2$. The surface of the casting obtained from CaO-coated graphite mold was slightly rougher than that from graphite without coating. The reaction product of titanium melt with the layer of CaO was mainly titanium oxide and that with graphite crucible was titanium cabide with small amount of titanium nitride.

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Measurement of Nitrogen Solubility with Ti addition in Stainless Steel (스테인레스강중의 Ti첨가에 따른 질소용해도 측정)

  • Lee, Young-Uk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.11
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    • pp.3043-3047
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    • 2009
  • Nitrogen solubility and nitride formation in liquid 304 Stainless steel has been measured by sampling method at various temperatures. Also values of thermodynamic functions are determined. Nitrogen solubility in molten 304 Stainless steel is increased with temperature and under the 1atm nitrogen atmosphere, titanium nitride is formed over 0.03wt%Ti in 304Stainless steel. Produced nitride is identified TiN by EDS analysis.

Numerical Analysis of Thermal Characteristics of a Milling Process of Titanium Alloy Using Nanofluid Minimum-Quantity Lubrication (티타늄 합금의 나노유체 극미량 윤활 밀링 공정 열특성에 관한 수치 해석 연구)

  • Kim, Young Chang;Kim, Jin Woo;Kim, Jung Sub;Lee, Sang Won
    • Journal of the Korean Society for Precision Engineering
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    • v.34 no.4
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    • pp.253-258
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    • 2017
  • This paper presents a numerical study on the thermal characteristics of a milling process of titanium alloy with nanofluid minimum-quantity lubrication (MQL). The computational fluid dynamics (CFD) approach is introduced for establishing the numerical model for the nanofluid MQL milling process, and estimated temperatures for pure MQL and for nanofluid MQL using both hexagonal boron nitride (hBN) and nanodiamond particles are compared with the temperatures measured by thermocouples in the titanium alloy workpiece. The estimated workpiece temperatures are similar to experimental ones, and the model is validated.

A Study of Weldability for Pure Titanium by Nd:YAG Laser(I) - Weld Properties with Shield Conditions - (순티타늄판의 Nd:YAG 레이저 용접성에 관한 연구(I) - 실드 조건에 따른 용접특성 -)

  • Kim, Jong-Do;Kwak, Myung-Sub;Kim, Chang-Soo
    • Journal of Welding and Joining
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    • v.27 no.5
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    • pp.55-61
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    • 2009
  • Pure titanium and its alloys have good formability, excellent corrosion resistance and high strength to weight ratios. Therefore, it has been using to heat exchangers, offshore plants, sports equipments, and etc. As broad as its application fields, it also increases welding locations. Conventional GTAW and GMAW are very popular welding methods of titanium, but it has a high heat input and wide HAZ. It has a possibility of inducing Stress Corrosion Cracking. So, laser welding method has been using to get reliable welds by reducing heat input. Weld beads change its color to silver, gold, brown, blue, and gray by shied conditions. And the closer to gray, the more oxidize, nitride and embrittlement. The most effective atom to embrittlement was nitrogen. And shield gas flow was not so effective over the constant flow rates. In this study, weld properties of the pure titanium were investigated by pulsed & CW Nd:YAG lasers and evaluated by various shield conditions. And It is observed that nitrogen is more effective to oxidation and embrittlement of titanium compared with oxygen by oxygen and nitrogen quantitative analysis.