• 한국표면공학회지
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• 제16권3호
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• pp.98-107
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• 1983

A study on the improvement of wear resistance of brasses by electroplating and diffusion treatment of tin was carried out. The optimum condition of the treatment obtained was as follows. Plating thickness of tin : 5 - 9 $\mu\textrm{m}$ Condition of diffusion treatment : atmosphere ; fused nitrate bath (KNO3 + NaNO3) temperature and time ; 1st step 320$^{\circ}C$, 60min. and 450$^{\circ}C$, 30min. During the diffusion treatment, internetallic compounds of Cu-Sn were formed and these compounds were identified as η, $\varepsilon$ and $\delta$ phase from the outer tin layer. It was considered that the improvement of wear resistance of brasses by the treatment is because of the formation of intemetallic compounds particalarly $\varepsilon$phase which is very hard, between soft tin layer brass.

• 한국환경생물학회:학술대회논문집
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• 한국환경생물학회 2003년도 학술대회
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• pp.38-47
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• 2003

Relationships between accumulations of endocrine disruptors and abnormalities in the reproductive organs in the adult male striped field mice, Apodemus agrarius, were reviewed. High levels of phenolic compounds were detected in the mice collected at an agricultural village in Gaduck island and at a place having a sewage problem in Samdong-myeon, Namhae. High levels of organo tin compounds were found in the mice collected at Jiri Mt. a tourist resort. Considerably high levels of phenolic or organo tin compounds were detected in mice with shrunken reproductive organs accounting for 14∼42% of the mice examined in each area, which suggests that the abnormality of reproductive organs may be induced by the endocrine disruptors. This hypothesis is strongly supported by histological observations of shrunken reproductive organs, such as necrosis of testicular germ and epithelial cells. This was found not only in the mice with shrunken reproductive organs but also in the mice with enlarged reproductive organs, both had accumulated high levels of endocrine disruptors in general.

• 대한화학회지
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• 제53권5호
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• pp.485-490
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• 2009

0.1 M 중탄산소듐 용액에서 납전극부식에 대한 로소니아, 감초뿌리 및 카로브 추출물수용액의 부식방지작용에 대한것을 정전류극성방법을 사용해 연구하였다. 이들 물질들의 부식방지작용을 지적해주는 것으로 이들 물질들이 존재할 때 부식속도가 감소하는 것이 발견되었다. 부식방지효율은 추출물농도가 증가하면 증가한다. 이들 추출물의 부식방지작용은 납표면에 이들 추출물이 흡착되어 물질 및 하전이동의 장벽을 만들어 나타내는 것으로 설명되었다. 이들 추출물의 납표면에 흡착은 자발적으로 일어나며, Freundlich 등온흡착을 따르는 것으로 발견되었다. 또한, 변전위양극분극법을 사용해 이들 추출물은 염소를 포함한 용액에서 납의 움푹패이게 하는 부식으로부터 잘 보호해주는 것이 발견되었다.

• 대한화학회지
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• 제49권6호
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• pp.603-608
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• 2005

• 한국자기학회지
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• 제5권5호
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• pp.376-379
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• 1995

Employing the muffin-tin-orbital theory combined with pseudo-potential concepts, we have evaluated hybridization matrix elements between R and T sites in $RT_{2}$ compounds. The matrix elements are calculated with two parameters, the interatomic distance between R and T atoms from the crystal structure data, and the expectation values of the radial distances for the radial wave functions of the ground state charge densities, which are obtained from the linearized muffin-tin orbital band method within the local density approximation. It is found that the R 4f/T 3d hybridization matrix elements decrease with an increasing atomic number from R=Ce to Gd, and that they are smaller in $RNi_{2}$ than in $RCo_{2}$, which are consistent with trends observed in recent photoemission spectroscopy experiments. It is also found that the magnitudes of the hybridization matrix elements in $RFe_{2}$ are comparable to those in $RNi_{2}$.

• 한국세라믹학회지
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• 제48권4호
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• pp.316-322
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• 2011

Tin oxide thin films were deposited by rf reactive sputtering and annealed at $400^{\circ}C$ for 1 h in vacuum. To minimize the influence such as reduction, oxidation, and doping on tin oxide thin films during annealing, a vacuum ambient annealing was adopted. The structural, optical, and electrical properties of tin oxide thin films were characterized by X-ray diffraction, atomic force microscope, UV-Vis spectrometer, and Hall effect measurements. After vacuum annealing, the grain size of all thin films was slightly increased and the roughness ($R_a$) was improved, however irregular and coalesced shapes were observed from the most of the films. These irregular and coalesced crystal shapes and the possible elimination of intrinsic defects might have caused a decrease in both carrier concentration and mobility, which degrades electrical conductivity.

• 한국분말재료학회지
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• 제10권1호
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• pp.21-25
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• 2003

The Sn - graphite composites were prepared by chemical encapsulation method for anode materials in Li-ion batteries. EDS and XRD analysis confirmed the presence of Sn in the graphite structure. Cyclic voltammometry (CV) measurement shows extra reduction and oxidation peaks, which might to be related to the formations of $Li_xSn$ alloy compounds. Graphite-tin composite electrodes demonstrated higher Lithium storage capacities than graphite electrodes. Due to the nature of fine Sn particles on graphite surface, the graphite-tin composite electrodes have shown a good cycle properties.

• 한국자기학회지
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• 제1권1호
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• pp.6-11
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• 1991

희토류금속과 천이금속의 화합물인 희토류 영구자석의 전기적, 자기적 성질등을 이해하고 자우리는 $SmCo_{5},\;NdB_{6},\;NdFe_{5},\;NdFe_{4}B$등의 비교적 간단한 희토류 화합물에 대한 자체충족적 전자구조 이론연구를 시도하였다. 국재 밀도함수 근사 LMTO(Linearized Muffin Tin Orbital)밴드 방법을 이용하여 $SmCo_{5}$ 영구자석을 포함한 희토류 금속 화학물의 기저상태의 물리적 파라미터들, 즉 에너지 밴드, 상태밀도, Stoner상수, 자기 모멘트 등을 구하여 이들의 전자기적 물성을 고찰하였다. Nd, Sm등의 희토류원소와 Fe, Co등의 천이원소, 또한 boron등의 원소들이 서로 금속 화합물을 형성할 때 일어나는 bonding효과, 즉 희토류금속의 f-전자와 d-전자, 천이금속의 d-전자, 또한 boron 금속의 s,p-전자와의 상호 작용, 그에 따른 전자구조, 자성의 변화에 대한 연구를 수행하였다.

• 한국항해항만학회:학술대회논문집
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• 한국항해항만학회 2002년도 추계공동학술대회논문집
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• pp.39-44
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• 2002

이 논문에서는 IMO-MEPC AFS 협약 채택(2001년 10월 5일)에 대한 국내 업게의 동향을 조사·분석하고 이를 바탕으로 AFS 협약과 연계된 국내법 마련(해양환경관리법 입법 방향, 선박안전법의 개정안)과 아울러 국제방오시스템증서 발급 방안, 효과적인 유해방오시스템 규제 방안(항만국 통제의 방안)을 제시하며, AFS 협약의 효율적 관리를 위한 관련부서의 일원화 방안 등을 마련하였다.

• Journal of Electrochemical Science and Technology
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• 제10권1호
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• pp.29-36
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• 2019

Corrosion inhibition by synthesised ligand, 2-acetylpyridine 4-ethyl-3-thiosemicarbazone (HAcETSc) and its tin(IV) complex, dichlorobutyltin(IV) 2-acetylpyridine 4-ethyl-3-thiosemicarbazone ($Sn(HAcETSc)BuCl_2$) on mild steel in 1 M hydrochloric acid (HCl) was studied using weight loss measurement, potentiodynamic polarisation, electrochemical impedance spectroscopy (EIS), and scanning electron microscopy (SEM). The inhibition efficiency increases by increasing the inhibitor concentrations. The polarisation study showed that both synthesised compounds were mixed type inhibitors. The electrochemical impedance study showed that the presence of inhibitors caused the charge transfer resistance to increase as the concentration of inhibitors increased. The adsorption of these compounds on mild steel surface was found to obey Langmuir's adsorption isotherm with the free energy of adsorption ${\Delta}G{^o}_{ads}$ of -3.7 kJ/mol and -7.7 kJ/mol for ligand and complex respectively, indicating physisorption interaction between the inhibitors and 1 M HCl solution.