• 제목/요약/키워드: Time in film

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Sol-Gel 공정으로 Plastic표면에 Glass박막 제조에 관한 연구 (Preparation of Glass Thin Film onto Plastic Surface by Sol-Gel Process)

  • 양천회
    • 한국안전학회지
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    • 제13권1호
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    • pp.85-91
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    • 1998
  • Sol-gel derived silica films were prepared by dip-coating onto polymethylmethacylate with Tetraethoxysilane(TEOS) as starting materials. Film properties such as viscosity and thickness were investigated as a function of dip speed, waterprecursor ratio, sol aging time. IR spectra of the gel films prepared from TEOS at various R are given. At small values of R the absorption peaks assignable to C-H vibration in $-OC_2H_5$ groups are observed around 3000 and 1500-1300 $cm^{-1}$. These bands indicate that the -$-OC_2H_5$ groups are retained in the gel at small values of R because of incomplete hydrolysis of TEOS. Film behaviour was interpreted in terms of the dependence of hydrolysis and condensation rates on the interplay between sol pH and waterprecursor ratio. Film thickness was found to increase by approximately a factor of two as waterprecursor ratio increased from two to six. Film thickness also increased with sol prepolymerization time. Surface quality was correlated with processing conditions.

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Copper-tetra-tert-butylphthalocyanine(CuTBP) LB 막의 NO$_2$ 가스탐지 특성에 관한 연구 (A study on the NO$_2$gas detection characteristics of the Copper - tetra - tert -butylphthatsocyanine (CuTBP ) LB Film)

  • 김형석;유병호;조형근;한영재;김태완;김정수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1994년도 추계학술대회 논문집
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    • pp.118-121
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    • 1994
  • The NO$_2$ gas-detection characteristics were investigated using the functional organic Langmuir-Blodgett(LB) film of Copper-tetra-tert-butylphalocyanine(CUTBP). The optimum conditions for a film deposition were obtained through a study of $\pi$-A isotherm and the deposited film status was confirmed by ellipsometry measurements. In the NO$_2$ response experiments, first of all, the proper number of layer was obtained by a change of the electrical conductivities depending on the number of layer when the film is exposed to the gas. And response time, recovery time, and reproducibility were measured on it. On the other hand, how the NO$_2$ gas interacts to the LB film was studied by UV/visible absorption spectra.

Strategies of Caffeine Loading into Silk Fibroin Film for Weight Loss Patch

  • Yun, Na Kyong;Lee, Ki Hoon
    • International Journal of Industrial Entomology and Biomaterials
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    • 제27권2호
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    • pp.312-316
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    • 2013
  • Caffeine is a thermogenic agent that can be used in weight loss products. In order to achieve a sustained release of caffeine, silk fibroin (SF) film was uses as carrier. It has been shown that the loading method of caffeine into SF film affected the uniform distribution of caffeine in the SF film. When caffeine was added directly into SF solution, gelation has been occurred immediately and prevented the uniform distribution of caffeine. On the other hand, caffeine was dissolved in methanol in order to load the caffeine in SF film and crystallize the SF film at the same time. However, due to the fast evaporation of methanol, caffeine was recrystallized on the surface of SF film rather than penetrating into the film. Finally, caffeine was loaded into pre-crystallized SF film and uniform distribution of caffeine could be achieved. There was an initial burst of caffeine during the first 15 min, but after that a sustained release was achieved.

현상액의 사용 시일 경과에 따른 필름 특성의 변화 (THE CHANGE OF FILM CHARACTERISTICS ACCORDING TO THE PROCESS OF USING TIME OF PROCESSING SOLUTION)

  • 정문성;정현대
    • 치과방사선
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    • 제22권1호
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    • pp.128-136
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    • 1992
  • This study was undertakened to investigate the change of image characteristics on dental films according to the process of using time of processing solution in automatic processor. Base + fog density, film density and subject contrast were measured with the digital densitometer, the pH of developing and fixing solution were measured with Digital pH / ION Meter. The following results were obtained: 1. Base + fog density was increased with the process of using time of the processing solution and was over the maximum permissible base + fog density 0.25 from the 3rd day. 2. Film density was increased with the process of using time of the processing solution. 3. Subject contrast was decreased with the process of using time of the processing solution. 4. The pH of the developing solution was decreased with the process of using time, the pH of the fixing solution was increased.

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PVD방식을 이용한 NDLC 박막에서의 액정 배향 효과 (Liquid Crystal orientation on the NDLC Thin Film Deposited using physical deposition method)

  • 이원규;오병윤;임지훈;나현재;이강민;박홍규;서대식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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    • pp.301-301
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    • 2008
  • Ion beam (IB)-induced alignment of inorganic materials has been investigated intensively as it provides controllability in a nonstop process for producing high-resolution displays[1][2]. LC orientation via ion-beam (IB) irradiation on the nitrogen doped diamond like carbon (NDLC) thin film deposited by physical deposition method-sputtering was embodied. The NDLC thin film that was deposited by sputter showed uniform LC alignment at the 1200eV of the ion beam intensity. The pretilt angle of LC on NDLC thin films was measured with various IB exposure time and angle. The maximum pretilt angle were showed with IB irradiation angle of $45^{\circ}$ and exposure time of 62.5 sec, respectively. To show NDLC thin film stability in high temperature, thermal stability test was proceeded. The uppermost of the thermal stability of NDLC thin film was $200^{\circ}C$. In this investigation, the electro-optical (EO) characteristics of LC on NDLC thin film were measured.

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나노 가스 감지 소자의 특성에 미치는 촉매 구조의 영향 (Elect of Catalytic Configuration on Sensing Properties of Nano Gas Sensor)

  • 홍성제;;한정인
    • 한국전기전자재료학회논문지
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    • 제18권10호
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    • pp.917-923
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    • 2005
  • In this paper, effect of catalytic configuration on the sensing properties of $SnO_2$ nanoparticle gas sensitive thick film was investigated. Two types of catalytic configuration, mono and binary, were made on the $SnO_2$ nanoparticle. In case of mono catalytic system, $3 wt\%$ Pd or Pt catalyst was doped onto the $SnO_2$ nanoparticle, respectively. In case of binary catalytic system, Pd and Pt was doped simultaneously with concentration ratio of 1:2 to 2:1 onto the $SnO_2$ nanoparticle. After doping, gas sensitive thick film was printed on alumina substrate and heat-treated at 450 to $600^{\circ}C$. Gas sensing properties was evaluated using 500 to 10,000 ppm $CH_4$ gas. As a result, gas sensitive thick film with binary catalytic system showed unstable phenomena that the gas sensitivity was changed according to aging time. In contrary, the mono catalytic system showed relatively stable phenomena despite of aging time. Especially, gas sensitive thick film doped with $3 wt\%$ Pt catalyst and heat-treated at $500^{\circ}C$ showed good sensing properties such as 0.57 of $R_{3500}/R_{1000}$ and very small variation within $3.5\%$ after aging for 5 hours, and response time was very short less than 20 seconds.

YBCO film을 이용한 저항형 초전도 한류기의 전류제한 특성 (Current limiting characteristics of the resistive SFCL using YBCO film)

  • 최효삼;김혜림;황시돌;현옥배;김상준
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 하계학술대회 논문집 A
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    • pp.277-280
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    • 1999
  • We fabricated a resistive superconducting fault current limiter of two stripe meander type based on a YBCO film, and performed current limitation experiments. In order to disperse the heat generated at hot spots in the YBCO film the film was coated with a gold shunt layer. At $0^{\circ}$ fault angle the minimum quench current was $9.6 A_{peak}$(meander line cross section: $5{\times}10^{-6}cm^2$) and the fast quench time was 0.63 msec. The resistance of the limiter continued to increase for three cycles due to heat generation in the gold layer and was stabilized afterwards. At $45^{\circ}$ and $90^{\circ}$ the fast quench time were 0.56 msec and 0.26 msec, respectively. The quench time is believed to be reduced because faults occurred when the current was increasing or was at the peak value. With the limiter we could effectively limit the fault current about 1/5 times right after the fault and about 1/8.5 times three cycles after.

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절단 원추형 Squeeze Film Damper 베어링과 회전축계의 동특성에 관한 연구 (A Study on the Dynamic Characteristics of Truncated Cone Type Squeeze Film Damper Bearing and Rotor System)

  • 윤석철
    • 한국안전학회지
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    • 제12권1호
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    • pp.9-18
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    • 1997
  • This paper is a study on the dynamic characteristics of truncated cone type squeeze film damper(SFD) bearing and rotor system. This model can alter the radial oil film gap which Is Important to the performance of rotor-bearing system and manufactured easily to change the shape concept of traditional circular type SFD bearing. In theoretical analysis, the oil film pressure distribution, the oil film force, the film damping coefficient and the eccentricity ratio, etc. were induced with regard to the film inertia effect. The film damping coefficients and optimum design parameters are calculated. When unbalance parameter U is greater than 0.2, the nonlinear vibration such as "Jump" phenomena appears in the vicinity of rotor critical speed. At this time, the increases of bearing parameter U, journal distance S, Reynolds number Re can control this unstable vibration. The experimental results show that SFD hearing and rotor system which are designed according to the design parameters in the stable region are operated stably in rotational speed 9,600rpm without nonsynchronous behavior.

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동일 재질의 투명 및 써클콘택트렌즈 착용 시 정상안과 건성안의 눈물막 안정성 차이 (The Difference in Tear Film Stability between Normal and Dry Eyes by Wearing Clear and Circle Contact Lenses made of the Same Materials)

  • 이세희;박미정;김소라
    • 한국안광학회지
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    • 제21권1호
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    • pp.11-21
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    • 2016
  • 목적: 본 연구에서는 동일재질의 투명 및 써클소프트콘택트렌즈(써클렌즈)를 정상안과 건성안에 착용시켰을 때 착용시간 경과에 따른 눈물막 안정성의 차이를 분석하고자 하였다. 방법: 연구대상자를 눈물량에 따라 정상안과 건성안으로 분류한 후 hilafilcon B 재질과 nelfilcon A 재질의 투명 및 써클렌즈를 각각 착용시키고, 렌즈 착용 30분 후, 6시간 후에 비침입성 눈물막 파괴시간, 렌즈중심안정위치, 눈물막깨짐 시작부위를 측정하여 눈물막 안정성의 변화를 알아보였다. 결과: 정상안과 건성안 모두 투명 및 써클콘택트렌즈 착용 시 착용시간경과에 따라 눈물막파괴시간은 통계적으로 유의한 감소를 보였다. 눈물막깨짐 시작 비율은 두 렌즈 모두 투명렌즈보다 써클렌즈의 주변부에서 높았고, 정상안보다는 건성안의 주변부에서 높게 나타났다. Hilafilcon B 재질보다는 nelfilcon A 재질 렌즈의 주변부에서 눈물막깨짐 시작 비율이 높았으나 착용시간경과에 따른 변화는 서로 다른 양상으로 나타났다. 한편, hilafilcon B 재질의 써클렌즈 착용 시 단위면적 당 눈물막깨짐 개수는 모두 주변부에서 많게 나타났던 반면, nelfilcon A 재질 써클렌즈의 경우는 착용시간 경과에 따라 중심부에서의 수가 증가하였다. 또한, 렌즈중심안정위치는 착용시간 경과에 따라 두 재질 모두 써클렌즈에 비해 투명렌즈가 동공중심 가까이에 존재하였으나 정상안에 비해 건성안의 중심이탈이 크게 나타났다. 결론: 본 연구결과 렌즈착용시간이 경과함에 따라 착색공정을 거친 써클렌즈 뿐만 아니라 투명렌즈도 눈물막에 미치는 영향이 달라질 수 있으며, 렌즈재질에 따라 눈물막 안정성에 영향을 주는 요인 또한 달라짐을 알 수 있었다. 따라서 투명 및 써클렌즈를 착용하고자 할 때에는 착용자의 일일착용시간이나 착용기간 등과 같은 사용습관에 따라 렌즈의 착색공법/염료 뿐만 아니라 렌즈 재질 또한 고려하여 적절한 렌즈를 선택하여야 할 것이다.

질화와 재산화를 이용한 얇은 게이트 산화막의 질적 향상 (Improvement of Thin-Gate Oxide using Nitridation and Reoxidation)

  • 이정석;장창덕;이용재
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1998년도 추계학술대회 논문집
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    • pp.1-4
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    • 1998
  • In this paper, we have studied a variation of I-V characteristics, and time-dependent dielectric breakdown(TDDB) of thin layer NO and ONO film depending on nitridation and reoxidation time, respectively, and measured a variation of leakage current and charge-to-breakdown(Q$\_$bd/) of optimized NO and ONO film depending on ambient temperature, and then compared with the properties of conventional SiO$_2$. From the results, we find that these NO and ONO thin films are strongly influenced by process time and the optimized ONO film shows superior dielectric characteristics, and Q$\_$bd/ performance over the NO film and SiO$_2$, while maintaining a similar electric field dependence compared with NO layer.

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