• Journal of the Korean Ceramic Society
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• v.35 no.10
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• pp.1049-1054
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• 1998

In order to fabricate ideal powders new processing is necessary in which the solute atoms in solution ra-pidly move to mix each other to the degree of molecular level the viscosity of solution should be low not to effect the moving of solute atoms and the powders could be directly obtained as crystalline. Supercritical fluid is defined as condensed gas sated up to its critical pressure and temperature. In this paper su-percritical fluid methods were studied as a new ceramic processing of powder preparation. The crystalline powders of TiO2 which are useful for electronic ceramic materials were fabricated by hydrolysis of titanium (IV) ethoxide using ethanol as a supercritical fluid at the condition of 270$\pm$3$^{\circ}C$, 7.3 MPa for 2hr. The cry stalline anatase powders could be directly obtained and its primary particle size was 20 min.

• Journal of the Korean Applied Science and Technology
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• v.20 no.4
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• pp.346-352
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• 2003

BaTiO$_3$, powders were prepared by sol-gel process from different aging time and reaction temperature. Particle shape, size and crystal structure of prepared $BaTiO_3$ powders were analyzed by SEM, XRD and FT-IR. Effect of aging time alternation didn't particularly show up. Spherical nano-sized $BaTiO_3$ powders were obtained from condition more than reaction temperature $55^{\circ}C$, and obtained sintered $BaTiO_3$ powders of tetragonal phase from heat-treatment at $1,100^{\circ}C$.

• Journal of Powder Materials
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• v.19 no.4
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• pp.310-316
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• 2012

Nanocrystalline $BaTiO_3$ powder could be synthesized by solid-state reaction using the mixture which was prepared by a high energy milling process in a bead mill for $BaCO_3$ and nanocrystalline $TiO_2$ powders mixture. Effect of the milling time on the powder characteristic of the synthesized $BaTiO_3$ powder was investigated. Nanocrystalline $BaTiO_3$ with a particle size of 50 nm was obtained at $800^{\circ}C$. High tetragonal $BaTiO_3$ powder with a tetragonality(=c/a) of 1.009 and a specific surface area of $7.6m^2/g$ was acquired after heat-treatment at $950^{\circ}C$ for 2 h. High energy ball milling was effective in decreasing the reaction temperature and increasing the tetragonality.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2002.10b
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• pp.237-239
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• 2002

The effect of particle sizes of the metal matrix composites containing 10 wt.%SiCp was investigated with using various tools. The results showed that tool life decreased considerably with increasing particle size and cutting speed. The wear resistance of TiC-coated tools was considerably higher than that of the other tools. It was observed that abrasive wear was the main responsible mechanism for wear of the tool thermal cracks were at high speed while a built-edge formation was also evident at lower speed.

• Korean Journal of Metals and Materials
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• v.48 no.5
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• pp.401-409
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• 2010

This study was performed to develop an antibacterial film that can be dried at room temperature. A nanosized TiO$_2$ particle-dispersed solution was prepared by the hydrothermal treatment of peroxo-titanic acid at 160${^{\circ}C}$ for 4h. The binder was synthesized through the hydrolysis and condensation reactions of TEOS (10cc) and GPTS (3.5cc) in the mixture of H$_2$O (30cc) and EtOH (30cc). The synthesized binder was mixed with 0.1 M of TiO$_2$ solution in a volume ratio of binder/TiO$_2$ solution=0.25~0.5. The glass substrate was coated after using the dip coating method, which was then followed by drying for over 2h at room temperature. Although the TiO$_2$ particles did not chemically-bond to the binder, the coating layer strongly adhered to the substrate and displayed good antibacterial properties.

• Journal of the Korean Ceramic Society
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• v.43 no.2 s.285
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• pp.114-120
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• 2006

Nano-size Au particle doped $TiO_2$ films were prepared with $Ti(OC_3H_7^i)_4$, polyvinylpyrrolidone(PVP), $HAuCl_4$ and $C_3H_7OH$ etc. by sol-gel method. $TiO_2$ gel films were obtained by the dip-coating method on the $SiO_2$ glass substrates, and then heat-treated at $700^{\circ}C$ for 10 min. The thickness of $TiO_2$ films were $0.7\~1.8\;{\mu}m$. It was found that the thickness of films prepared from PVP containing solution was about $2\~8$ times higher values than that of thin films without PVP. The size of Au particles doped in the films were about $350\~750\;nm$. Nano-size Au particle dispersed $TiO_2$ films showed high absorption peak at visible region 450nm, which made them good candidates for non-linear optical materials and photo-catalytic materials. The contact angle of $TiO_2$ film for water was $12.5^{\circ}$, and therefore it is clear that $TiO_2$ films have very high hydrophilic properties and the self-cleaning effects.

• Journal of the Korean Ceramic Society
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• v.21 no.4
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• pp.323-326
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• 1984

In this study we are going to develop the process of a synthesis about BaTiO3 at the room temperature. We use BaTiO3 as a high dielectric constant in many dielectric materials and more stable in the temperature, We need high temperature over 1300$^{\circ}C$ for the synthesis of BaTiO3 by the process of industrials and there are difficulty which synthesize a final products not to have a intermediate composition. So we studied to synthesize a pure BaTiO3 from the room temperature to 90$^{\circ}C$ and also to develop the process of synthesis which can control the particle size and which has the final product not to have a intermediate composition.

• Bulletin of the Korean Chemical Society
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• v.20 no.12
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• pp.1394-1398
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• 1999

The structures of modified Ti$(OPr^i)_4$ with chelating ligands (L) such as ethylacetoacetate (Etac), acetylacetone (Acac) and methylacetoacetate (Mtac) were identified by using IR, ¹H NMR and $^13C$ NMR spectroscopies, and the octahedral structure was confirmed after modification. The pre-edge peaks of XANES spectra of modified metal alkoxides also denoted the mixture of five-fold and six-fold structures. The EXAFS fitting results showed the local structure around Ti atom after alkoxide modification. The hydrolysis-condensation rates of modified Ti alkoxide with organic additives were investigated by ¹H NMR spectroscopy. The Ti$(OPr^i)_4$ modified by Acac was less reactive toward hydrolysis-condensation reaction than those modified by the other alkoxides, which can be attributed to the stable ligand structure between Ti$(OPr^i)_4$ and Acac. The small particle size of modified Ti$(OPr^i)_4$ sol was obtained when Acac was employed.

• Particle and aerosol research
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• v.11 no.3
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• pp.87-92
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• 2015

MCM-41 (Mobil Composition of Matter) and SBA-15 (Santa Barbara Amorphous) were used as a supported catalyst for ethylene polymerization due to their combination of large surface area and wide range of pore size distribution. The morphology of supports was used to control the morphology of the resulting polymer. Different molar ratios of Al/Ti were used for ethylene polymerization at $60^{\circ}C$ under atmospheric pressure. The effect of different mass ratios of MCM-41/SBA-15 and 1-hexene concentration on polymerization activity and polymer properties was investigated. The catalytic activity and the crystallinity reached the highest value at Al/Ti of 480. Upon incorporation of MCM-41 and SBA-15 into $MgCl_2/TiCl_4$ catalyst, the molecular weight and crystallinity of polyethylene were enhanced. The obtained polyethylene showed melting temperature between 130 and $135^{\circ}C$. The polyethylene with replication structure of support and bimodal MWD was expected.

• Journal of the Korean Ceramic Society
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• v.39 no.4
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• pp.413-419
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• 2002

Particulate composites of $Al_2O_3$/TiC/SiC, $Al_2O_3$/TiC and $Al_2O_3$/SiC have been fabricated by hot pressing and their R-curve behaviors and mechanical properties were investigated. $Al_2O_3$ containing 30 vol% TiC particles showed higher toughness by 8% than that for monolithic alumina and its fracture strength was increased significantly by approximately 30%. On the other hand, the addition of 30 vol% SiC of $3{\mu}m$ in $Al_2O_3$ decreased the fracture strength slightly but induced a rising R-curve behavior owing to the strong crack bridging of SiC particles. In case of $Al_2O_3$/TiC/SiC, arising R-curve behavior was also observed and the fracture toughness reached 6.6 MPa${\cdot}\sqrt{m}$ at the crack length of $1000{\mu}m$, which was lower than that of $Al_2O_3$/SiC, however, while the fracture strength was higher by about 20%. The fracture toughness seemed to be decreased as smaller TiC particles roughened the SiC interface and pullout of the SiC particles for crack bridging became less active.