• Journal of Korea Foundry Society
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• v.21 no.5
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• pp.286-289
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• 2001

The glass formation behavior was investigated in the melt spun Zr-Ti-Cu-Ni-X (X=B, P and Si) ribbons. The magnitude of supercooled liquid region of Zr-Ti-Cu-Ni alloy increased with an addition of alloying element. The glass transition temperature and the crystallization temperature increased and the magnitude of supercooled liquid region decreased with increasing the content of alloying elements. The largest supercooled liquid region was observed in the Si containing alloy. This is believed to be due to the dense atom packing with the optimum atomic size ratio of constituent elements.

• Journal of Mechanical Science and Technology
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• v.18 no.3
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• pp.453-459
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• 2004

TiNi/ Al6061 shape memory alloy (SMA) composite was fabricated by hot press method to investigate the microstructure and mechanical properties. Interface bonding between TiNi reinforcement and A1 matrix was observed by using SEM and EDS. Pre-strain was imposed to generate compressive residual stress inside composite. A tensile test for specimen, which under-went pre-strain, was performed at high temperature to evaluate the variation of strength and the effect of pre-strain. It was shown that interfacial reactions occurred at the bonding between matrix and fiber, creating two inter-metallic layers. And yield stress increased with the amount of pre-strain. Acoustic Emission technique was also used to nondestructively clarify the microscopic damage behavior at high temperature and the effect of pre-strain of TiNi/ Al6061 SMA composite.

• Transactions of Materials Processing
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• v.12 no.4
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• pp.290-295
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• 2003

High temperature deformation behavior and prediction of final microstructure after forming of Ti-6Al-4V alloy were investigated in this study. Equiaxed and Widmanstatten microstructures of Ti-6Al-4V alloys were prepared as initial microstructures and compression tests were performed to obtain the flow curves at high temperatures (700∼110$0^{\circ}C$) and various strain rates (10$^{-4}$ ∼10$^2$/s). From the results of compression test, strain rate sensitivity (m) and activation energy (Q) were calculated and used to establish constitutive equation. To predict the final microstructure after farming, finite element analysis was performed considering the microstructural parameters such as grain size and volume fraction of second phase.

• Journal of the Korean institute of surface engineering
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• v.30 no.5
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• pp.320-332
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• 1997

The development of colored surface on zinc coating by the oxidation of a melten alloy of zinc with a minor amount of oxygen-avid additive such as tianium has been studied. Using a galvanizing Zinc alloy containing 0.1 to 0.3wt%Ti, gold, purple or blue color was developed clearly and stably, depending upon the extent of oxidation, by air cooling after hot dipping in a bath at temperature of $550^{\circ}C$ to $600^{\circ}C$. The source of the color is light interference with surface oxide layer. THe final color depends on the thickness of the color depends on the thickness of $TiO_2$, played So compositing, temperature and time at elevated temperature after are all controlling variables. Since oxidation film such as $TiO_2$ played role of passivation film, the corrosion resistance in a colored galvanized steel sheet. It is also thought that surface oxide layer of $TiO_2$ inhibited dissolution of the coating layer.

• Journal of the Korean Society of Safety
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• v.29 no.4
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• pp.28-33
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• 2014

Recently, the actuator worked by the driving recovery-force of the thermo elastic martensitic transformation of shape memory alloys(SMA) has been studied. This paper presents a study on the fatigue life of shape memory alloy (SMA) actuators undergoing thermally induced martensitic phase transformation under various stress levels. shape memory recoverable stress and strain of Ti-44.5at.%Ni-8at.%Cu alloys were by means of constant temperature tensile tests. Differential scanning calorimetry (DSC) was employed in order to investigate the transformation characteristics of the alloy before the tests. the results were summarized as follows. The martensite inducing stress incerased with the increasing of the Cu-contents. The fatigue life decreased with the increasing of the test load and the Cu-content. The data acquired will be very useful during the design process of an SMA NiTiCu element as a functional part of an actuator.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2000.07a
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• pp.108-110
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• 2000

The aim of this paper is to investigate the effect of Al and Ti on microstructure of Fe-Cr-Al alloy systems for applying electrical resistance wires of electrical furnace. From the preliminary study, the amount of recovered addition elements increased in the case of both vacuum and Ar-atmosphere melting than that in the case of air-atmosphere melting. Also, optimum Cr content for good performance at high temperature was approximately 24wt% from the observation of microstucture. The precipitates of Fe-Cr, Al-Cr and Al phases were observed, adding Al and Ti. Especially, Sharp rectangular shapes of precipitates were observed with increasing amount of Ti.

• Korean Journal of Materials Research
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• v.2 no.5
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• pp.313-319
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• 1992

The mechanisms of fatigue crack growth (FCG) in a Ti$_3$Al-based (${\alpha}_2$) alloy, Ti-24Al-11Nb (a/o) with acicular microstructure were studied with particular attention focused on the fatigue crack path through the microstructure and on the effects of specimen orientation and crack closure. The results showed that the fatigue cracks of Ti-24Al-11Nb alloy grew much faster than conventional titanium alloys, with little difference in FCG rates for TL and TS orientations. The fatigue crack paths revealed crystallographic transgranular fracture with frequent serrations and branching. This is in agreement with the known effects of slip planarity and microstructure on the FCG behavior. The load-displacement hysteresis loops showed that the crack closure influenced the FCG behavior.

• Transactions of Materials Processing
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• v.28 no.1
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• pp.27-33
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• 2019

The effect of hardening methods and process parameters on surface hardening of a Ti-6Al-4V Alloy has been investigated in this study. To characterize the effectiveness of the respective surface hardening methods, samples of a Ti-6Al-4V alloy were self-quenched, laser-nitrided, laser-carburized, laser-carbonitrided at the same laser irradiation conditions. This experimental procedure was followed by comparing the microstructural evolutions and mechanical properties of the respective samples after the laser surface hardenings. The hardening characteristics of the respective laser surface hardenings were well defined in this study, and the hardness was significantly influenced by the reaction compounds and laser energy density.

• Journal of Dental Rehabilitation and Applied Science
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• v.32 no.3
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• pp.194-201
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• 2016

Purpose: The purpose of this study was to evaluate of Zirconium Nitride (ZrN) coating on shear bond strength with denture base resin in Co-Cr and Ti-6Al-4V alloy. Materials and Methods: Co-Cr and Ti-6Al-4V alloy disks (10 mm in diameter, 2.5 mm in thickness; each other: n = 14) were prepared and divided with 2 groups each other by ZrN coating. After primer was applied to disks surface, denture base resin with diameter 6 mm, height 5 mm was bonded on metal disk surface. After surface roughness was measured by Profiler, shear bond strength was determined with Universal testing machine and analyzed with two-way ANOVA. The specimen surfaces and failure mode were examined using a scanning electron microscope. Results: ZrN coated groups showed significantly higher rough surface than non-coated groups (P < 0.05). Irrespective of alloy materials, shear bond strength of ZrN coated groups were lower than non-coated groups (P < 0.001). The scanning electron microscope (SEM) of ZrN coated groups showed mixed and adhesive fractures. Conclusion: ZrN coating weakened bonding strength between denture base resin and Co-Cr, Ti-6Al-4V alloy.

• Journal of the Korean Ceramic Society
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• v.37 no.4
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• pp.381-387
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• 2000

Si3N4/stainless steel 316 joints with Ni buffer layer were fabricated by direct active brazing method (DIB) using Ag-Cu-Ti brazing alloy only and double brazing method (DOB) using Ag-Cu brazing alloy with Si3N4 pretreated with Ag-Cu-Ti brazing alloy. For the joint brazed by DIB method, Ti was segregated at the Si3N4/brazing alloy interface, but was not enough to form a stable joint interface. In addition, large amounts of Ni-Ti inter-metallic compounds were formed in tehbrazing alloy near the joint interface, which could deplete the contents of Ti involved in the interfacial reaction. However, for the joint brazed by DOB method, segregation of Ti at the joint interface were enough to enhance the formation of stable interfacial reaction products such as TiN and Ti-Si-Ni-N-(Cu) multicompounds, which restricted the formation of Ni-Tio inter-metallic compounds in the brazing alloy during brazing with Ni buffer layer. Fracture strength of Si3N4/S.S 316 joints with Ni buffer layer was much improved by using DOB method rather than DIB method. It could be deduced that the differences of fracture strength of the joint with Ni buffer layer depending on brazing process adapted were directly affected by the formation of stable joint interface and the change in microstructure of the brazing alloy near the joint interface. It was found that fracture strength of Si3N4/S.S 316 joints with Ni buffer layer was gradually reduced as the thickness of interface. It was found that fracture strength of Si3N4/S.S 316 joints with Ni buffer layer was gradually reduced as the thickness of Ni buffer layer in the joint was increased from 0.1 mm to 10 mm. It seems to due to the increased residual stress in the joint as the thickness of Ni buffer layer is increased. The maximum fracture strength of Si3N4/S.S 316 joints with Ni buffer layer was 386 MPa, and the fracture of joint was originated at Si3N4/brazing alloy joint interface and propagated into Si3N4 matrix.