• Title/Summary/Keyword: Ti-Al-Si-N

검색결과 208건 처리시간 0.027초

Development of CNT-dispersed Si3N4 Ceramics by Adding Lower Temperature Sintering Aids

  • Matsuoka, Mitsuaki;Yoshio, Sara;Tatami, Junichi;Wakihara, Toru;Komeya, Katsutoshi;Meguro, Takeshi
    • 한국세라믹학회지
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    • 제49권4호
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    • pp.333-336
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    • 2012
  • The study to give electrical conductivity by dispersing carbon nanotubes (CNT) into silicon nitride ($Si_3N_4$) ceramics has been carried out in recent years. However, the density and the strength of $Si_3N_4$ ceramics were degraded and CNTs disappeared after firing at high temperatures because CNTs prevent $Si_3N_4$ from densification and there is a possibility that CNTs react with $Si_3N_4$ or $SiO_2$. In order to suppress the reaction and the disappearance of CNTs, lower temperature densification is needed. In this study, $HfO_2$ and $TiO_2$ was added to $Si_3N_4-Y_2O_3-Al_2O_3$-AlN system to fabricate CNT-dispersed $Si_3N_4$ ceramics at lower temperatures. $HfO_2$ promotes the densification of $Si_3N_4$ and prevents CNT from disappearance. As a result, the sample by adding $HfO_2$ and $TiO_2$ fired at lower temperatures showed higher electrical conductivity and higher bending strength. It was also shown that the mechanical and electrical properties depended on the quantity of the added CNTs.

공정 Al-Si 합금의 개량처리와 주단조에 의한 조직변화에 관한 연구 (Study on the Microstructural Changes with Modification and Cast-forging in Eutectic Al-Si Alloys)

  • 윤지현;설은철;박승민;이광학
    • 한국주조공학회지
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    • 제22권1호
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    • pp.17-25
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    • 2002
  • Recently, many studies have been carried out to process on the purpose of lightness in a transport parts because of the saving energy, the environmental problem. The cast-forging process can be expected to lower costs without decreasing the mechanical properties. So, the finest microstructure is needed to get for applying the cast-forging process with Al-Si alloy because the microstructure affects to the cast-forging process. For refinement treatment of eutectic Si and Al solid-solution phase, Sr and TiB were added in Al-Si alloys. The finest microstructure could be observed when 0.075 wt.%Sr and 0.1 wt.%TiB were added respectively. In this case, tensile strength and elongation much more increased than as casting. After high temperature deformation simulation test with grain refinement specimens was carried out, about 70N per unit $area(mm^2)$ of specimen was confirmed. After hot forging, tensile strength and elongation were increased. It was considered because casting defect was removed by compressive working.

FeRAM 소자 제작 중에 발생하는 Pt/Al 반응 기구 (Pt/Al Reaction Mechanism in the FeRAM Device Integration)

  • 조경원;홍태환;권순용;최시경
    • 한국재료학회지
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    • 제14권10호
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    • pp.688-695
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    • 2004
  • The capacitor contact barrier(CCB) layers have been introduced in the FeRAM integration to prevent the Pt/Al reaction during the back-end processes. Therefore, the interdiffusion and intermetallic formation in $Pt(1500{\AA})/Al(3000{\AA})$ film stacks were investigated over the annealing temperature range of $100\sim500^{\circ}C$. The interdiffusion in Pt/Al interface started at $300^{\circ}C$ and the stack was completlely intermixed after annealing over $400^{\circ}C$ in nitrogen ambient for 1 hour. Both XRD and SBM analyses revealed that the Pt/Al interdiffusion formed a single phase of $RtAl_2$ intermetallic compound. On the other hand, in the presence of TiN($1000{\AA}$) barrier layer at the Pt/Al interface, the intermetallic formation was completely suppressed even after the annealing at $500^{\circ}C$. These were in good agreement with the predicted effect of the TiN diffusion barrier layer. But the conventional TiN CCB layer could not perfectly block the Pt/Al reaction during the back-end processes of the FeRAM integration with the maximum annealing temperature of $420^{\circ}C$. The difference in the TiN barrier properties could be explained by the voids generated on the Pt electrode surface during the integration. The voids were acted as the starting point of the Pt/Al reaction in real FeRAM structure.

초경엔드밀 적용 표면처리 조성별 마모특성 영향 평가 (The Evaluation of Wear Characteristics Depending on Components of Surface Treatment for Cemented Carbide Endmill)

  • 윤일채;김동배;윤국태;윤인준;이지형;고태조
    • 한국정밀공학회지
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    • 제31권6호
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    • pp.513-519
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    • 2014
  • For depth machining in die and mold, Electrical Discharge Machining (EDM) is used generally. To make deep hole and deep shape efficiently, cemented carbide endmill for depth machining is necessary. For this purpose, cemented carbide endmill was designed using design of experiment (DOE). To improve cutting performance, endmill was coated with multilayer surface treatment, TiAlCrSiN and TiAlCrN, for higher wear resistance. In order to evaluate the endmill, Transverse Rupture Strength (TRS) test was tried for investigating the relationship between surface treatment and strength in endmill body. Scratch test was also used for measuring adhesion force of each surface treatment. To evaluate hardness of surface treatment, Atomic Force Microscope (AFM) analysis was carried out. Wear test was executed for characteristics of each surface treatment in high temperature. Consequently, TiAlCrSiN was superior to the TiAlCrN coating in case of high temperature environment such as cutting.

광촉매용 $TiO_2$ 강유전체 박막의 증착 두께에 따른 Photon Energy 특성에 관한 연구 (A Study on the Photon Energy Characteristics of Photocatalytic $TiO_2$ Ferroelectrics Thin Film According to Coating Thickness)

  • 김병인;전인주;이상일
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 2002년도 학술대회논문집
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    • pp.329-334
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    • 2002
  • This study evaporates TiO$_2$ layer thickness differently with RF sputtering method on Si Wafer(n-100). Thin film is made with the structure of Si+TiO$_2$ and Si+TiO$_2$+Al by evaporating TiN which is used as Antireflection of superintegrated semiconductor integrated circuit with Photo Catalyst. The research is performed to increase the characteristics of photon energy according to TiO$_2$ thickness and the reliability and reproducibility of TiO$_2$ thin film. Reversal of electric Permittivity values is induced by dipole polarization shown in the dielectric of thin film. Complex electric constant ($\varepsilon$$_1$, $\varepsilon$$_2$) has larger peak values as it's thickness is thinner and then it is larger according to the increase of frequency. Electric Permittivity by photon energy has large value in imaginary number and is reduced exponentially by the increase of carrier density according to that of photon energy.

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DRAM에서 $Al_2O_3$를 식각 정지막으로 이용한 레지스터 형성에 관한 연구 (Study on the Resistor Formation using an $Al_2O_3$ Etch-Stop Layer in DRAM)

  • 박종표;김길호
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.153-156
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    • 2005
  • 원자층 증착 (atomic layer deposit : ALD) 방식으로 증착한 $Al_2O_3$의 건식식각 특성을 연구하였다. 전자 싸이클로트론 공진 (electron cyclotron resonance : ECR) 방식의 건식식각장치에서 source power, bias power, 압력 그리고 $Cl_2$ 가스를 변수로 하여 $Al_2O_3$의 식각속도와 Poly-Si 의 $Al_2O_3$에 대한 선택비를 측정하였다. bias power가 감소할수록 그리고 압력이 증가할수록 $Al_2O_3$의 식각속도는 감소하였고 Poly-Si 의 $Al_2O_3$에 대한 선택비는 증가하였다. 이 특성을 이용하여 TiN/$Al_2O_3$/Poly-Si 구조의 캐패시터와 Periphery 회로영역의 레지스터를 $Al_2O_3$를 식각 정지막으로 이용하여 구현하였다.

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Failure and Phase Transformation Mechanism of Multi-Layered Nitride Coating for Liquid Metal Injection Casting Mold

  • Jeon, Changwoo;Lee, Juho;Park, Eun Soo
    • 한국재료학회지
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    • 제31권6호
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    • pp.331-338
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    • 2021
  • Ti-Al-Si target and Cr-Si target are sputtered alternately to develop a multi-layered nitride coating on a steel mold to improve die-casting lifetime. Prior to the multi-layer deposition, a CrN layer is developed as a buffer layer on the mold to suppress the diffusion of reactive elements and enhance the cohesive strength of the multi-layer deposition. Approximately 50 nm CrSiN and TiAlSiN layers are deposited layer by layer, and form about three ㎛-thickness of multi-layered coating. From the observation of the uncoated and coated steel molds after the acceleration experiment of liquid metal injection casting, the uncoated mold is severely eroded by the adhesion of molten metallic glass. On the other hand, the multi-layer coating on the mold prevents element diffusion from the metallic glass and mold erosion during the experiment. The multi-layer structure of the coating transforms the nano-composite structured coating during the acceleration test. Since the nano-composite structure disrupts element diffusion to molten metallic glass, despite microstructure changes, the coating is not eroded by the 1,050 ℃ molten metallic glass.

Pt 전극을 이용한 ${Al_0.33}{Ga_0.67}N$ 쇼트키형 자외선 수광소자의 동작특성 (Properties of Pt/${Al_0.33}{Ga_0.67}N$ Schottky Type UV Photo-detector)

  • 신상훈;정영로;이재훈;이용현;이명복;이정희;이인환;한윤봉;함성호
    • 대한전자공학회논문지SD
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    • 제40권7호
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    • pp.486-493
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    • 2003
  • 유기금속 화학기상 증착법(MOCVD)을 이용하여 사파이어 기판에 AlGaN/n/sup +/-GaN 구조와 AlGaN/AlGaN interlayer/n/sup +/-GaN 구조로 성장시킨 AlGaN 층을 이용하여 쇼트키형 자외선 수광소자를 제작하였다. 성장층은 약 1018의 캐리어 농도와 각각 236과 269 ㎠/V·s의 이동도를 가진다. 메사구조를 형성하기 위해 ICP 장비로 식각한 후, Si₃N₄로 절연한 뒤 Ti/Al/Ni/Au와 Pt를 이용하여 저항성 전극 및 쇼트키전극을 형성하였다. 그리고 interlayer를 갖는 Pt/Al/sub 0.33/Ga/sub 0.67/N의 전기적 특성은 -5 V에서 1 ㎁의 낮은 누설전류를 보였고, interlayer가 없는 Pt/Al/sub 0.33/Ga/sub 0.67/N은 0.1㎂로 나타났다. 광측정 결과, interlayer를 갖는 Pt/Al/sub 0.33/Ga/sub 0.63/N 쇼트키 수광소자는 차단파장이 약 300 ㎚이며, 광응답도는 280 ㎚에서 0.15 A/W, 그리고 자외선 대 가시광선 제거비는 1.5×10⁴로 우수한 반응특성을 보였다.

Effect of Al Doping Concentration on Resistance Switching Behavior of Sputtered Al-doped MgOx Films

  • 이규민;김종기;박성훈;손현철
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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    • pp.307-307
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    • 2012
  • In this study, we investigated that the resistance switching characteristics of Al-doped MgOx films with increasing Al doping concentration and increasing film thickness. The Al-doped MgOx based ReRAM devices with a TiN/Al-doped MgOx/Pt/Ti/SiO2 were fabricated on Si substrates. The 5 nm, 10 nm, and 15 nm thick Al-doped MgOx films were deposited by reactive dc magnetron co-sputtering at $300^{\circ}C$ and oxygen partial ratio of 60% (Ar: 16 sccm, O2: 24 sccm). Micro-structure of Al-doped MgOx films and atomic concentration were investigated by XRD and XPS, respectively. The Al-doped MgOx films showed set/reset resistance switching behavior at various Al doping concentrations. The process voltage of forming/set is decreased and whereas the initial current level is increased with decreasing thickness of Al-doped MgOx films. Besides, the initial current of Al-doped MgOx films is increased with increasing Al doping concentration in MgOx films. The change of resistance switching behavior depending on doping concentration was discussed in terms of concentration of non-lattice oxygen of Al-doped MgOx.

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