• Title/Summary/Keyword: Ti-Al-Fe-Si-O

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Microstructure and Mechanical Properties of Rapidly Solidified Powder Metallurgy Al-Fe-V-Si-X Alloys

  • Genkawa, Takuya;Yamasaki, Michiaki;Kawamura, Yoshihito
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1041-1042
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    • 2006
  • High heat-resistant Al-Fe-V-Si and Al-Fe-V-Si-X rapidly solidified powder metallurgy (RS P/M) alloys have been developed under well-controlled high purity argon gas atmosphere. The $Al_{90.49}Fe_{6.45}V_{0.68}Si_{2.38}$ (at. %) RS P/M alloy exhibited high elevated-temperature strength exceeding 300 MPa and good ductility with elongation of 6 % at 573 K. Reduction of $H_2O$ partical pressure in P/M processing atmosphere led to improvement in mechanical properties of the powder-consolidated alloys under elevated-temperature service conditions. Ti addition to the Al-Fe-V-Si conduced to enhancement of the strength at room temperature. The tensile yeild strength and ultimate strenght were 545 MPa and 722 MPa, respectively.

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The Statistical on Numerical Analysis for The Petrology and Bulk Chemical Composition. In Cheju Volcanic Island (제주화산도의 암석성분에 관한 통계학적인 수치해석)

  • 택훈
    • Journal of the Speleological Society of Korea
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    • v.14 no.15
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    • pp.42-90
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    • 1987
  • Lee, Moon Won reported by 63 kinds lescribing the petrography and bulk chemical Composition in Petrology of Cheju volcanic island. The total Chemical Composition data was analyzed by the program of FORTRAN77. First, the Conversition equations and the scatter diagram were examined to the analysis, by the least square method. Next, a statistical data requested a mean Value, maximum value, minimum value, the range, the standard deviation, the variance, the Standord Error and the Coefficient of variation. In the standard deviation, a small Composition is MnO and P$_2$O$\sub$5/, a large Composition is SiO$_2$, Mgo and FeO. The Standard error and the variance were the tandency looked like the Standard deviation well. However, the Coefficient Variation differs from the Standard deviation. Where, a large Coefficient of variation are H$_2$O$\^$-/ and H$_2$O$\^$+/, a small Coefficient of variation are Al$_2$O$_3$ and SiO$_2$. The Correlation of Coefficient Can be Calculated numerically from the relation between SiO$_2$, Al$_2$O$_3$ and TiO$_2$ to other Compositions.

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Electrochemical Behaviors of PEO-treated Ti-6Al-4V Alloy in Solution Containing Zn and Si Ions

  • Hwang, In-Jo;Choe, Han-Cheol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.160-160
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    • 2017
  • Commercially pure titanium (Cp-Ti) and Ti alloys (typically Ti-6Al-4V) display excellent corrosion resistance and biocompatibility. Although the chemical composition and topography are considered important, the mechanical properties of the material and the loading conditions in the host have, conventionally. Ti and its alloys are not bioactive. Therefore, they do not chemically bond to the bone, whereas they physically bond with bone tissue. The electrochemical deposition process provides an effective surface for biocompatibility because large surface area can be served to cell proliferation. Plasma electrolyte oxidation (PEO) enables control in the chemical composition, porous structure, and thickness of the TiO2 layer on Ti surface. Silicon (Si) in particular has been found to be essential for normal bone and cartilage growth and development. Zinc (Zn) plays very important roles in bone formation and immune system regulation, and is also the most abundant trace element in bone. The objective of this work was to study on electrochemical behaviors of PEO-treated Ti-6Al-4V Alloy in solution containing Zn and Si ions. The morphology, the chemical composition, and the microstructure analysis of the sample were examined using FE-SEM, EDS, and XRD. The potentiodynamic polarization and AC impedance tests for corrosion behaviors were carried out in 0.9% NaCl solution at similar body temperature using a potentiostat. The promising results successfully demonstrated the immense potential of Si/Zn-TiO2 coatings in dental and biomaterials applications.

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Synthesis of Aniline from Nitrobenzene and Fe(CO)5 with PEG/γ-Al2O3 as Phase Transfer Catalyst (PEG/γ-Al2O3 상이동 촉매상에서 니트로벤젠과 Fe(CO)5로부터의 아닐린 합성)

  • Oh, So-Young;Lee, Hwa-Su;Park, Dae-Won;Park, Sang-Wook;Shin, Jung-Ho
    • Applied Chemistry for Engineering
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    • v.4 no.1
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    • pp.144-152
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    • 1993
  • Immobilized polyethylene glycols onto metal oxides such as ${\gamma}-Al_2O_3$, ${\alpha}-Al_2O_3$, $SiO_2$ and $TiO_2$ were used as phase transfer catalysts for the room temperature synthesis of aniline from nitrobenzene and ironpentacarbonyl. The amount of attached PEG molecules increased with specific surface area of metal oxides. Among the immobilized catalysts tested PEG/${\gamma}-Al_2O_3$ showed the highest activity. The reaction rate increased with the chain length of PEG mole-cules and the aqueous NaOH concentration. Mechanistic study carried out using infrared spectrometer revealed that the role of PEG was to increase the formation of $HFe(CO)_4{^-}$ ion, which is known as active species, and its movement from aqueous to organic phase.

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A Study on the Arsenic Removal Characteristics of TiO2 Powders in Ground Water (상용 TiO2의 지하수 비소제거 특성에 관한 연구)

  • Lee, Dong Ho;Kim, Sung Su
    • Journal of Korean Society on Water Environment
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    • v.31 no.6
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    • pp.632-636
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    • 2015
  • This study aims to evaluate arsenic adsorption efficiencies over various metal oxides (CeO2, TiO2, Fe3O4, ZrO2, AlOOH, SiO2, α-Al2O3, and γ-Al2O3) and investigate the correlation between physico-chemical characteristics of metal oxides and their efficiencies. From XPS, XRD BET analysis and isotherm adsorption test, TiO2 powder showed that the best adsorption efficiency, and it's mechanism was highly depended on the chemical adsorption.

Characteristics of BaFe12O19 Particles Extracted from Amorphous Ba-Ferrite (비정질 Ba-Ferrite로부터 추출한 BaFe12O19 입자의 특성)

  • 김태옥;오영우;박효열;강원호
    • Journal of the Korean Ceramic Society
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    • v.24 no.6
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    • pp.553-560
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    • 1987
  • Amorphous ferrites with composition B2O3-mBaO-nFe2O3 were prepared by an ultra rapidquenching technique. X-ray patterns and SEM reveal the products to be amrophous at room temperature. BaFe12O19 fine particles extracted from amorphous Ba-ferrites which additived Al2O3, SiO2, TiO2 and CoO have narrow size distribution, average 0.2$\mu\textrm{m}$, and coercive force, average 1400 Oe, increased with increasing TiO2 amounts. The obtained BeFe12O19 fine particles would be appreciated as perpendicular magnetic recording media.

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Occurrence and Chemical Composition of White Mica and Chlorite from Laminated Quartz Vein of Unsan Au Deposit (운산 금 광상의 엽리상 석영맥에서 산출되는 백색운모와 녹니석의 산상 및 화학조성)

  • Yoo, Bong Chul
    • Korean Journal of Mineralogy and Petrology
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    • v.34 no.1
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    • pp.1-14
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    • 2021
  • The Unsang gold deposit has been one of the three largest deposits (Daeyudong, Kwangyang) in Korea. The geology of this deposit consists of series of host rocks including Precambrian metasedimentary rock and Jurassic Porphyritic granite. The deposit consists of Au-bearing quartz veins which filled fractures along fault zones in Precambrian metasedimentary rock and Jurassic Porphyritic granite, which suggests that it is an orogenic-type deposit. Quartz veins are classified as 1) galena-quartz vein type, 2) pyrrhotite-quartz vein type, 3) pyrite-quartz vein type, 4) pegmatic quartz vein type, 5) muscovite-quartz vein type and 6) simple quartz vein type based on mineral assembles. The studied quartz vein is pyrite-quartz vein type which occurs as sericitization, chloritization and silicification. The white mica from stylolitic seams of laminated quartz vein occurs as fine or medium aggregate associated with white quartz, pyrite, chlorite, rutile, monazite, apatite, K-feldspar, zircon and calcite. The structural formular of white mica from laminated quartz vein is (K0.98-0.86Na0.02-0.00Ca0.01-0.00Ba0.01-0.00 Sr0.00)1.00-0.88(Al1.70-1.57Mg0.22-0.09Fe0.23-0.10Mn0.00Ti0.04-0.02Cr0.01-0.00V0.00Ni0.00)2.06-1.95 (Si3.38-3.17Al0.83-0.62)4.00O10(OH2.00-1.91F0.09-0.00)2.00. It indicated that white mica of laminated quartz vein has less K, Na and Ca, and more Si than theoretical dioctahedral micas. Compositional variations in white mica from laminated quartz vein are caused by phengitic or Tschermark substitution [(Al3+)VI+(Al3+)IV <-> (Fe2+ or Mg2+)VI+(Si4+)IV] and direct (Fe3+)VI <-> (Al3+)VI substitution. The structural formular of chlorite from laminated quartz vein is((Mg1.11-0.80Fe3.69-3.14Mn0.01-0.00Zn0.01-0.00K0.07-0.01Na0.01-0.00Ca0.04-0.01Al1.66-1.09)5.75-5.69 (Si3.49-2.96Al1.04-0.51)4.00O10 (OH)8. It indicated that chlorite of laminated quartz vein has more Si than theoretical chlorite. Compositional variations in chlorite from laminated quartz vein are caused by phengitic or Tschermark substitution (Al3+,VI+Al3+,IV <-> (Fe2+ or Mg2+)VI+(Si4+)IV) and octahedral Fe2+ <-> Mg2+ (Mn2+) substitution. Therefore, laminated quartz vein and alteration minerals of the Unsan Au deposit was formed during ductile shear stage of orogeny.

달과 화성의 토양에서 지하 깊이에 따른 고에너지 우주선 환경 영향 분석

  • Jeong, Jong-Il;Son, Jong-Dae;Lee, Yu;O, Su-Yeon
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.2
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    • pp.104.2-104.2
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    • 2012
  • 미국, 중국, 일본, 인도 등과 같은 세계 여러 국가들이 달 및 화성 탐사를 수행하고 있는 현시점에서 우리나라도 2025년에 달 탐사를 계획하고 있다. 인간에게 있어서 우주공간은 고에너지 환경의 영향을 많이 받는 곳이다. 향후 달, 화성과 같은 다른 행성으로의 이주를 생각하고 있는 현 시점에서 우리는 고에너지우주방사선 환경의 영향을 고려해야 한다. 지구에서의 인간은 지구 자기장과 대기에 의해 고에너지 우주선 환경으로부터의 영향을 덜 받는다. 그러나 달과 화성의 경우는 다르다. 달의 대기는 거의 없고 자기장도 무시할 정도로 매우 작으며, 화성 또한 자기장이 거의 없으며 대기 또한 얇아서 Galactic Cosmic Ray (GCR)나 Solar Energetic Proton (SEP) 등으로부터 인간은 많은 영향을 받을 수 있다. 이러한 위험으로부터 인간이 보호받을 수 있는 곳은 달과 화성의 지표 아래나 동굴이라고 볼 수 있다. 그래서 달 및 화성의 표면과 지하 영역에 대한 고에너지 우주선 환경의 깊이에 따른 영향을 분석하여 어느 정도로 두터운 천장을 가진 동굴이어야 우주인들이 상주하는 지하공간을 지구표면에서의 방사선 환경과 같은 수준으로 유지할 수 있는지를 추정해 보려고 한다. 달 표면 토양의 화학적 구성성분은 Maria와 Highlands로 구분되어 약간의 차이가 있다. 달의 Maria 토양은 $SiO_2$ - 45.4%, $Al_2O_3$ - 14.9%, CaO - 11.8%, FeO - 14.1%, MgO - 9.2%, $TiO_2$ - 3.9%, $Na_2O$ - 0.6%이고 Highlands의 토양은 $SiO_2$ - 45.5%, $Al_2O_3$ - 24.0%, CaO - 15.9%, FeO - 5.9%, MgO - 7.5%, $TiO_2$ - 0.6%, $Na_2O$ - 0.6%의 화학적인 구성비를 가진다. 또한 화성표면은 $SiO_2$ - 43.9%, $Al_2O_3$ - 8.1%, CaO - 6.0%, FeO - 18.1%, MgO - 7.1%, $Na_2O$ - 1.4%의 토양의 화학적인 구성비를 가지고 있다. 본 연구에서는 이러한 구성비를 가지고 있는 달과 화성 표면에 대한 우주방사선의 영향을 분석하기 위해서 GEANT4를 사용하여 수행한 전산 모사의 결과를 발표할 것이다.

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Geochemical Dispersion and Enrichment of Fluvial Sediments Depending on the Particla Size Distribution (입도분포에 따른 하상퇴적물의 지구화학적 분산 및 부화)

  • 이현구
    • Economic and Environmental Geology
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    • v.32 no.3
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    • pp.247-260
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    • 1999
  • Geochermical characteristics of the fluvial sediments deprnding on particle size distribution size were investigated in the respect of majir, minor and rare eath element chemisitry. Ratios of $Al_{2}O_{3}/Na_{2}O$ and $K_{2}O/Na_{2}O$ of the sediments show the homogeneous valus, and partly positive correlation with $SiO_{2}/Al_{2}O_{3}$, respecively. Characteristics of minor element ratios (V/Ni, Cr/V, Ni/Co and Zr/Hf)are within the lower and narrow range. Thesesuggested that sediment sources may be acidic to intermediate granitic rock, and may be explained by simple weathering and sedimentation. With increasing SiO2 contents, concentrations of $Al_{2}O_{3}$, $Fe_{2}O_{3}$, CaO and MgO decreased, but those of $K_{2}O$ and $Na_{2}O$ increased, Concentrations of Ba, Be, Cs, Cu, Li, Ni, Sr, V and Zr show comparatively normal negative and some positive trends. Compared with the mean composition of granite, concentrations of $Al_{2}O_{3}$, $Fe_{2}O_{3}$, MnO, CaO and MgO in the sediments of the study area were highly enriced. Among some minor and rare earth elements, concentrations of As, Cd, Cu, and V were enriched, but those of Be, Ce, Rb, Sc, Sr and Zn were depleted when compared with average composition of granite. By decreasing of particle size fractions, SiO2, Rb and Sr conterts decreased, but concentrations of $Al_{2}O_{3}$, $Fe_{2}O_{3}$, CaO, MgO, $TiO_{2}$, MgO, $P_{2}O_{5}$, Be, Cu, Hf, Pb, V and Zr increased. From the correlations between particle size fractions and element concenreations, some elements of $Fe_{2}O_{3}$, CaO, MgO, $P_{2}O_{5}$, Cu, Ni, Zn and Zr showed typical trends in the secondary contramination sediments. These trends are typically shown under 100 mesh fractions. It indicates that the fraction of minus 100 mesh is the optimum size fraction for geochemical and environmental survey.

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Gahnite-Sillimanite-Garnet Mineral Assemblage from the Host Rocks of the Cannington Deposit, North Queensland, Australia: Relationship between Metamorphism and Zn-Mineralization (호주 퀸즈랜드 주 캔닝턴 광상 모암의 아연-첨정석-규선석-석류석에 관한 연구 :변성작용과 아연-광화작용에 대해서)

  • Kim Hyeong Soo
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.4
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    • pp.309-325
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    • 2004
  • The Cannington Ag-Pb-Zn deposit, northwest Queensland, Australia developed around the host rocks composing banded and migmatitic gneisses, sillimanite-garnet schist and amphibolite. Three crystal habits of sillimanite, gahnite (Zn-spinel) and garnet porphyroblasts occurred on the host rocks of the Cannington deposit could be used to delineate metamorphism that closely associated with Zn-mineralization in the deposit. Linkages the metamorphism to Zinc-mineralization is determined in four chemical systems, KFMASH (K$_2$O-FeO-MgO-Al$_2$O$_3$-SiO$_2$-$H_2O$), KFMASHTO (K$_2$O-FeO-MgO-Al$_2$O$_3$-SiO$_2$-$H_2O$-TiO$_2$-Fe$_2$O$_3$), NCKFMASH (Na$_2$O-CaO-K$_2$O-FeO-MgO-AlO$_3$-SiO$_2$-$H_2O$) and MnNCK-FMASH (MnO-Na$_2$O-CaO-K$_2$O-FeO-MgO-AlO$_3$-SiO$_2$-$H_2O$), using THERMOCALC program (version 3.1; Powell and Holland 1988). Partial melting in MnNCKFMASH and NCKFMASH systems occurs at lower temperature than in the KFMASH and KFMASHTO systems. The partial melting temperature decreases with increasing of Na/(Na+Ca+K) of the bulk rock compositions in the MnNCKFMASH system. The host rocks have melted ca 15 vol.% in the MnNCKFMASH system at peak metamorphic conditions (634$\pm$62$^{\circ}C$ and 4.8$\pm$1.3 kbar), but partial melting have not occurred in KFMASHTO system. Based on calculations of sillimanite isograd in different systems and sillimanite modal pro-portion, prismatic and rhombic sillimanite and gahnite porphyroblasts including prismatic sillimanite inclusion probably have resulted from pressure and temperature increasing through partial melting (from 550~$600^{\circ}C$, 2.0~3.0 kbar to 700~75$0^{\circ}C$, 5.0~7.0 kbar), furthermore have experienced N-S then W-E crustal shortening during D$_1$ and D$_2$ deformation. Consequently, Zinc mineralization related to gahnite growth occurred during D$_2$ and was redistributed and upgraded by partial melting and retrograde metamorphism into structural and rheological sites during shearing in D$_3$.