• Title/Summary/Keyword: Three-dimensional electrode system

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Three-dimensional Electrochemical Oxidation process using Nanosized Zero-valent Iron/Activated carbon as Particle electrode and Persulfate (나노영가철/활성탄 입자전극과 과황산을 이용한 3차원 전기화학적 산화공정)

  • Min, Dongjun;Kim, Cheolyong;Ahn, Jun-Young;Cho, Soobin;Hwang, Inseong
    • Journal of Soil and Groundwater Environment
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    • v.23 no.6
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    • pp.104-113
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    • 2018
  • A three-dimensional electrochemical process using nanosized zero-valent iron (NZVI)/activated carbon (AC) particle electrode and persulfate (PS) was developed for oxidizing pollutants. X-ray diffraction (XRD), scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS), and Brunauer-Emmett-Teller (BET) surface area analysis were performed to characterize particle electrode. XRD and SEM-EDS analysis confirmed that NZVI was impregnated on the surface of AC. Compared with the conventional two-dimensional electrochemical process, the three-dimensional particle electrode process achieved three times higher efficiency in phenol removal. The system with current density of $5mA/cm^2$ exhibited the highest phenol removal efficiency among the systems employing 1, 5, and $10mA/cm^2$. The removal efficiency of phenol increased as the Fe contents in the particle electrode increased. The particle electrode achieved more than 70% of phenol removal until it was reused for three times. The sulfate radical played a predominant role in phenol removal according to the radical scavenging test.

Self-Supporting 3D-Graphene/MnO2 Composite Supercapacitors with High Stability

  • Zhaoyang Han;Sang-Hee Son
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.2
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    • pp.175-185
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    • 2023
  • A hybrid supercapacitor is a promising energy storage device in view of its excellent capacitive performance. Commercial three-dimensional foam nickel (Ni) can be used as an ideal framework due to an interconnected network structure. However, its application as an electrode material for supercapacitors is limited due to its low specific capacity. Herein, we report a successful growth of MnO2 on the surface of graphene by a one-step hydrothermal method; thus, forming a three-dimensional MnO2-graphene-Ni hybrid foam. Our results show that the mixed structure of MnO2 with nanoflowers and nanorods grown on the graphene/Ni foam as a hybrid electrode delivers the maximum specific capacitance of 193 F·g-1 at a current density 0.1 A·g-1. More importantly, the hybrid electrode retains 104% of its initial capacitance after 1,000 charge-discharge cycles at 1 A·g-1; thus, showing the potential application as a stable supercapacitor electrode.

Fabrication of Electrochemical Sensor with Tunable Electrode Distance

  • Yi, Yu-Heon;Park, Je-Kyun
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.5 no.1
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    • pp.30-37
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    • 2005
  • We present an air bridge type electrode system with tunable electrode distance for detecting electroactive biomolecules. It is known that the narrower gap between electrode fingers, the higher sensitivity in IDA (interdigitated array) electrode. In previous researches on IDA electrode, narrower patterning required much precise and expensive equipment as the gap goes down to nanometer scale. In this paper, an improved method is suggested to replace nano gap pattering with downsizing electrode distance and showed that the patterning can be replaced by thickness control using metal deposition methods, such as electroplating or metal sputtering. The air bridge type electrode was completed by the following procedures: gold patterning for lower electrode, copper electroplating, gold deposition for upper electrode, photoresist patterning for gold film support, and copper etching for space formation. The thickness of copper electroplating is the distance between upper and lower electrodes. Because the growth rate of electroplating is $0.5{\mu}m\;min^{-1}$, the distance is tunable up to hundreds of nanometers. Completed electrodes on the same wafer had $5{\mu}m$ electrode distance. The gaps between fingers are 10, 20, 30, and $40{\mu}m$ and the widths of fingers are 10, 20, 30, 40, and $50{\mu}m$. The air bridge type electrode system showed better sensitivity than planar electrode.

A Strady-State One-Dimensional Analysis of an Oxygen Electrode in Stationary and Flowing Liquid (정체 및 유동액체에서 산소전극의 안정상태 일차원적 해석)

  • 김태진
    • KSBB Journal
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    • v.4 no.2
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    • pp.150-156
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    • 1989
  • The chaacterisitics of a commercial membrance-coverd electrode in air-saturated saline solution were investigated in terms of a steadystate one-dimensional model. The electrode system miiersed in an aqueous medium consists of three layers: an external concentration boundary layer, a membrance, and an inner electrolyte layer. The membrance can be permeabld to the water and impermeable to the ionic species. In stationary midium, the water migrates from the external medium to the inner electrolyte layer until a thermodynamic equilibrium is reached. In a following midium, however, there is a reverse direction of water movement due to the hyrodynamic pressure differential until both thickness of the electrolyte layer and the membrance are equal.

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A brief review on graphene applications in rechargeable lithium ion battery electrode materials

  • Akbar, Sameen;Rehan, Muhammad;Liu, Haiyang;Rafique, Iqra;Akbar, Hurria
    • Carbon letters
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    • v.28
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    • pp.1-8
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    • 2018
  • Graphene is a single atomic layer of carbon atoms, and has exceptional electrical, mechanical, and optical characteristics. It has been broadly utilized in the fields of material science, physics, chemistry, device fabrication, information, and biology. In this review paper, we briefly investigate the ideas, structure, characteristics, and fabrication techniques for graphene applications in lithium ion batteries (LIBs). In LIBs, a constant three-dimensional (3D) conductive system can adequately enhance the transportation of electrons and ions of the electrode material. The use of 3D graphene and graphene-expansion electrode materials can significantly upgrade LIBs characteristics to give higher electric conductivity, greater capacity, and good stability. This review demonstrates several recent advances in graphene-containing LIB electrode materials, and addresses probable trends into the future.

Fabrication of Micro Tool Electrode for Machining Micro Structures using Wire Electrical Discharge Grinding(WEDG) (WEDG 방법을 이용한 마이크로 구조물 가공용 미세공구 제작)

  • Park Sung-Jun;Ahn Hyun-Min;Lee Kyo-Seung
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.14 no.5
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    • pp.13-20
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    • 2005
  • Micro EDM process is generally used for machining microholes, cavities, and three dimensional shapes. For machining micro structures, first of all, micro tool electrode is indispensable and WEDG system is proposed for tool fabrication method. When using WEDG, its machining characteristics are highly affected by many EDM parameters such as applied voltage, current, rotation speed, capacitance, and pulse duration. Therefore, the design of experiment is introduced to fully understand the effect of the EDM parameters on machining tool electrode. And an attempt has been made to develop the mathematical model for predicting the size of the tool electrode by calculating spark distance. The suggested model was verified with experiment and predicted working gap distance is in good accord with the measured value.

Design of silicon-graphite based composite electrode for lithium-ion batteries using single-walled carbon nanotubes (단일벽 탄소나노튜브를 이용한 리튬이온전지용 실리콘-흑연 기반 복합전극 설계)

  • Jin-young Choi;Jeong-min Choi;Seung-Hyo Lee;Jun Kang;Dae-Wook Kim;Hye-Min Kim
    • Journal of the Korean institute of surface engineering
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    • v.57 no.3
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    • pp.214-220
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    • 2024
  • In this study, three-dimensional (3D) networks structure using single-walled carbon nanotubes (SWCNTs) for Si-graphite composite electrode was developed and studied about effects on the electrochemical performances. To investigate the effect of SWCNTs on forming a conductive 3D network structure electrode, zero-dimensional (0D) carbon black and different SWCNTs composition electrode were compared. It was found that SWCNTs formed a conductive network between nano-Si and graphite particles over the entire area without aggregation. The formation of 3D network structure enabled to effective access for lithium ions leading to improve the c-rate performance, and provided cycle stability by alleviating the Si volume expansion from flexibility and buffer space. The results of this study are expected to be applicable to the electrode design for high-capacity lithium-ion batteries.

The Three-Dimensional Temporal Behavior Measurement of Light Emitted From Plasma Display Panel

  • Choi, Hoon-Young;Kwon, Hyung-Seok;Lee, Seok-Hyun;Lee, Seung-Gol
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.598-600
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    • 2002
  • To improve the luminance and efficiency of AC PDP, the effects of a square pulse applied to the address electrode during a sustain-period is investigated. Through this experiment, we confirmed the improvement of luminance and efficiency. We performed the temporal behavior measurement for the light emitted from AC PDP at floating state of the address electrode and at various auxiliary voltages (including ground state) applied to the address electrode using the scanned point detecting system. In the case of using an auxiliary voltage pulse, emission starts at the inner edges of the anode and cathode simultaneously. Also, we obtained the larger two discharge volumes compared with the normal sustain discharge where address electrode is floated.

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A Simulator for Potential Distribution Analysis

  • Kil, Gyung-Suk;Gil, Hyong-Jun;Park, Dae-Won
    • Journal of Electrical Engineering and Technology
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    • v.7 no.2
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    • pp.225-229
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    • 2012
  • This paper proposes a reduced-scale simulator that can replace numerical analytic methods for the estimation of potential distribution caused by ground faults in various grounding systems. The simulator consists of a hemispherical electrolytic tank, a three-dimensional potential probe, a grounding electrode, and a data acquisition module. The potential distribution is measured using a potentiometer with a position-tracing function when a test current flows to the grounding electrode. Using the simulator, we could clearly analyze the potential distribution for a reduced- scale model by one-eightieth of the buried depth and length of the grounding rod and grounding grid. Once both the shape of the grounding electrode and the fault current are known, the actual potential distribution can be estimated.

The Measurement of Three-Dimensional Temporal Behavior According to the Pressure in the Plasma Display Panel (플라즈마 디스플레이 패널에서 압력에 3차원 시간 분해 측정)

  • 최훈영;이석현;이승걸
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.10
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    • pp.476-480
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    • 2003
  • In this paper, we have performed 3-dimensional time-resolving measurement of the Ne light emitted from the cell of plasma display panel(PDP) as a function of the pressure using the scanned point detecting system. From the temporal behavior results, we could analyze the discharge behavior of panel with Ne-Xe(4%) mixing gas and 300 torr, 400 torr and 500 torr pressure. At the top view of panel, the discharge of 300 torr panel starts at the 634 ns and ends at the 722 ns. The emission duration time is about 90 ns. The discharge of 400 torr panel starts at the 682 ns and ends at the 786 ns. the emission duration time is about 100 ns. Also, the discharge of 500 torr panel starts at the 770 ns and ends at the 826 ns. the emission duration time is about 56 ns. The discharge moves from inner edge of cathode electrode to outer cathode electrode forming arc type. In the side view of 300 torr, 400 torr and 500 torr an emission shows that the light is detected up to 180${\mu}{\textrm}{m}$, 150${\mu}{\textrm}{m}$ and 70${\mu}{\textrm}{m}$ height of barrier rib and the emission distribution of the 300 torr is wider than 400 torr, 500 torr.