• Title/Summary/Keyword: Three phase composite

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Phase Separated Structure and Electro-optical Properties of the (Polymer/Liquid Crystal) Composite Films ((고분자/액정) 복합막의 상분리구조와 전기광학 특성)

  • Park, K.S.;Noh, C.H.;SaKong, D.S.;Nam, K.D.;Kajiyama, T.
    • Journal of the Korean Applied Science and Technology
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    • v.12 no.2
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    • pp.29-39
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    • 1995
  • The phase separated structure and the electro-optical properties of the (polymer/liquid) crystal : LC) composite film strongly depended on the weight fraction of LC in it. The continuous LC phase was formed in a three-dimensional polymer network when the LC weight fraction was above 40wt%. The aggregation structure of the composite film could be controlled by controlling the solvent evaporation velocity during the film preparation process. The smaller LC domains or channels were formed in the case of the faster solvent evaporation velocity. The composite film exhibited reversible light scattering-light transmission switching upon electric field -OFF and -ON states, respectiverly. The light scattering properties of the composite film strongly depended on the spatial distortion of the nematic directors as well as the mismatch in refractive indices between matrix polymer and LC.

Evaluation of fiber-reinforced bipolar plate for PEM fuel cell (PEM 연료전지용 섬유강화 분리판의 특성 평가)

  • Lee, Hee-Sub;Kim, Sung-Geun;Ahn, Sung-Hoon;Jeon, Ui-Sik;Ahn, Sang-Yeoul;Ahn, Byung-Ki
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.11a
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    • pp.554-557
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    • 2005
  • The bipolar plate is a major component of the PEM fuel cell stack, which takes a large portion of stack cost. In this study, as alternative materials for bipolar plate of PEM fuel cells, graphite composites were fabricated by compression molding. Graphite particles mixed with epoxy resin were used as the main substance to provide electric conductivity. To achieve desired electric properties, specimens made with different mixing ratio, processing pressure and temperature were tested. To increase mechanical strength, one or two layer of woven carbon fabric were added to the original graphite and resin composite. Thus, the composite material is consisted of the three phases: graphite particles, epoxy resin, and carbon fabric. By increasing mixing ratio, fabricated pressure and process temperature, electric conductivity was improved. The results of tensile test showed that the tensile strength of two-phase graphite composite was about 5MPa, and that of three-phase composite was increased to 54MPa.

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Compact Dual-Band Three-Way Metamaterial Power-Divider with a Hybrid CRLH Phase-Shift Line

  • Jang, Kyeongnam;Kahng, Sungtek;Jeon, Jinsu;Wu, Qun
    • Journal of electromagnetic engineering and science
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    • v.14 no.1
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    • pp.15-24
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    • 2014
  • A compact dual-band three-way metamaterial power divider is proposed that has three in-phase outputs. Fully printed composite rightand left-handed (CRLH) unequal and equal power dividers are first implemented for 900-MHz and 2.4-GHz bands with the power-division ratios of 2:1 and 1:1, respectively. An initial 1:1:1 power divider is then achieved by incorporating the input of the two-way equal block into an output of the unequal block, and trimming the interconnection parameters. The condition of an identical phase at the three outputs of the power divider is then met by devising a hybrid CRLH phase-shift line to compensate for the different phase errors at the two frequencies. This scheme is confirmed by predicting the performance of the power divider with circuit analysis and full-wave simulation and measuring the fabricated prototype. They results show agreement; the in-phase outputs as well as the desirable power-division are accomplished and outdo the conventional techniques.

Evaluation of Mechanical and Electrical Properties of Bipolar Plate Made of Fiber-reinforced Composites for PEM Fuel Cell (섬유강화 복합재를 사용한 PEM 연료전지 분리판의 전기적.기계적 특성 평가)

  • Lee, Hee-Sub;Ahn, Sung-Hoon;Jeon, Ui-Sik;Ahn, Sang-Yeoul;Ahn, Byung-Ki
    • Transactions of the Korean Society of Automotive Engineers
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    • v.14 no.5
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    • pp.39-46
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    • 2006
  • The fuel cell is one of promising environment-friendly energy sources for the next generation. The bipolar plate is a major component of the PEM fuel cell stack, which takes a large portion of stack cost. In this study, as alternative materials for bipolar plate of PEM fuel cells, graphite composites were fabricated by compression molding. Graphite particles mixed with epoxy resin were used as the main substance to provide electric conductivity To achieve desired electrical properties, specimens made with different mixing ratio, processing pressure and temperature were tested. To increase mechanical strength, one or two layers of woven carbon fabric were added to the graphite and resin composite. Thus, the composite material was consisted of three phases: graphite particles, carbon fabric, and epoxy resin. By increasing mixing ratio of graphite, fabricated pressure and process temperature, the electric conductivity of the composite was improved. The results of tensile test showed that the tensile strength of the two-phase graphite composite was about 4MPa, and that of three-phase composite was increased to 57MPa. As surface properties, contact an91e and surface roughness were tested. Graphite composites showed contact angles higher than $90^{\circ}$, which mean low surface energy. The average surface roughness of the composite specimens was $0.96{\mu}m$.

A novel meso-mechanical model for concrete fracture

  • Ince, R.
    • Structural Engineering and Mechanics
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    • v.18 no.1
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    • pp.91-112
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    • 2004
  • Concrete is a composite material and at meso-level, may be assumed to be composed of three phases: aggregate, mortar-matrix and aggregate-matrix interface. It is postulated herein that although non-linear material parameters are generally used to model this composite structure by finite element method, linear elastic fracture mechanics principles can be used for modelling at the meso level, if the properties of all three phases are known. For this reason, a novel meso-mechanical approach for concrete fracture which uses the composite material model with distributed-phase for elastic properties of phases and considers the size effect according to linear elastic fracture mechanics for strength properties of phases is presented in this paper. Consequently, the developed model needs two parameters such as compressive strength and maximum grain size of concrete. The model is applied to three most popular fracture mechanics approaches for concrete namely the two-parameter model, the effective crack model and the size effect model. It is concluded that the developed model well agrees with considered approaches.

Mechanical Properties of Particle and Fiber Reinforced SMC Composites (입자와 섬유로 보강된 SMC 복합재의 기계적 특성에 관한 연구)

  • 정현조;윤성호
    • Transactions of the Korean Society of Automotive Engineers
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    • v.4 no.2
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    • pp.173-182
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    • 1996
  • An analytical model has been developed to predict the elastic properties of a filled resin reinforced by chopped fibers, a three-phase composite such as a filled sheet molding compound(SMC). In the model the matrix material and fillers form an effective matrix. The effective matrix is then considered to be reinforced with long fibers lying in the sheet plane but randomly oriented in the plane. Expressions for the resulting transversely isotropic composite properties are explicitly presented. Using this model, the Young's and shear moduli are calculated for the SMC sample with filler weight fraction of 35% and fiber content of 30%. The same properties are also determined experimentally. The agreement between the calculated and measured elastic moduli is found to be very good for the in-plane properties. However, the out-of-plane properties show a large difference because the effect of voids is not taken into account in the model.

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Effect of Poly(butyl acrylate)-Poly(methyl methacrylate) Rubber Particle Texture on the Toughening Behavior of Poly(methyl methacrylate)

  • Chung, Jae-Sik;Park, Kyung-Ran;Wu, Jong-Pyo;Han, Chang-Sun;Lee, Chan-Hong
    • Macromolecular Research
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    • v.9 no.2
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    • pp.122-128
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    • 2001
  • Monodisperse composite latex particles with size of ca. 300 nm, which consist ofn-butyl acrylate as a soft phase and methyl methacrylate as a hard phase with different morphology, were synthesized by seeded multi-stage emulsion polymerization. Three types of composite latex particles including random-, core/shell-, and gradient-type particles were obtained by using different monomer feeding methods during semi-batch emulsion polymerization. Effect of poly(butyl acrylate)-poly(methyl methacrylate) rubber particle morphology on the mechanical and rheological properties of rubber toughened poly(methyl methacrylate) was investigated. Among three different rubber particles, the gradient-type rubber particle showed better toughening effect than others. No significant variation of rheological property of poly(methyl methacrylate)/rubber blends was observed for the different rubber particle morphology.

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A Study on the Material Behavior of Glass Fiber Reinforced Thermoplastic Composite in Biaxial Stretch Forming (유리섬유 강화 열가소성 복합재료의 2축 인장성형시 재료거동에 관한 연구)

  • 이중희;류성기
    • Journal of the Korean Society for Precision Engineering
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    • v.17 no.2
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    • pp.169-175
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    • 2000
  • The object of this study was to investigate the feasibility of solid-phase forming of the composites and to characterize the material behavior in the biaxial stretch forming. The materials tested contained 20%, 30%, and 40% glass fibers by weight in a polypropylene matrix. Biaxial stretch forming tests were performed at three forming speeds of 10mm/sec, 1mm/sec, and 0.1mm/sec and at four forming temperatures of $75^{\circ}C, 100^{\circ}C, 125^{\circ}C, and 150^{\circ}C$ to investigate effects of forming speed and forming temperature. The microscopic observation of a formed part was conducted at various strain levels to characterize the material behavior. The strain distribution on a formed part was measured and displayed on the farmed geometry with a contour display The material behavior of the composite in the biaxial stretch forming was strongly influenced by the forming conditions.

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Deformation Properties of TiC-Mo Eutectic Composite at High Temperature (TiC-Mo 공정복합재료의 고온 변형특성)

  • Shin, Soon-Gi
    • Korean Journal of Materials Research
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    • v.23 no.10
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    • pp.568-573
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    • 2013
  • The deformation properties of a TiC-Mo eutectic composite were investigated in a compression test at temperatures ranging from room temperature to 2053 K and at strain rates ranging from $3.9{\times}10^{-5}s^{-1}$ to $4.9{\times}10^{-3}s^{-1}$. It was found that this material shows excellent high-temperature strength as well as appreciable room-temperature toughness, suggesting that the material is a good candidate for high-temperature application as a structure material. At a low-temperature, high strength is observed. The deformation behavior is different among the three temperature ranges tested here, i.e., low, intermediate and high. At an intermediate temperature, no yield drop occurs, and from the beginning the work hardening level is high. At a high temperature, a yield drop occurs again, after which deformation proceeds with nearly constant stress. The temperature- and yield-stress-dependence of the strain is the strongest in this case among the three temperature ranges. The observed high-temperature deformation behavior suggests that the excellent high-temperature strength is due to the constraining of the deformation in the Mo phase by the thin TiC components, which is considerably stronger than bulk TiC. It is also concluded that the appreciable room-temperature toughness is ascribed to the frequent branching of crack paths as well as to the plastic deformation of the Mo phase.

Mechanochemical Treatment of Quartz for Preparation of EMC Materials

  • Shin, Hee-Young;Chae, Young-Bae;Park, Jai-Koo
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.315-324
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    • 2001
  • Mechanochemical effects that occurred in the fine grinding process of quartz particles using planetary ball mill was investigated. Quartz particles have been frequently utilized for optical materials, semiconductor molding materials. We determined that grinding for a long time can be create amorphous structures from the crystalline quartz by Mechanochemical effects. But, to be produced nano-composite particles that the critical grinding time reached for composite materials in a short time. Henceforth, a qualitative estimation must be conducted on the filler for EMC(Epoxy molding compound) materials. It can be produced mechanochemically treated composite materials and also an integrated grinding efficiency considering of the nano-composite amorphous structured particles. The mechanochemical characteristics were evaluated based on particle morphology, size distribution, specific surface area, density and the amount of amorphous phase materials into the particle surface. The grinding operation in the planetary ball mill can be classified into three stages. During the first stage, initial particle size was reduced for the increase of specific surface area. In the second stage, the specific surface areas increased in spite of the increase in particle size. The final stage as a critical grinding stage, the ground quartz was considered mechanochemically treated particles as a nano- composite amorphous structured particles. The development of amorphous phase on the particle surface was evaluated by X-ray diffractometry, thermal gravity analysis and IR spectrometer. The amount of amorphous phase of particles ground for 2048 minutes was 85.3% and 88.2% by X-ray analysis and thermal gravity analysis, respectively.

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