• Title/Summary/Keyword: Thin Shell

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Synthesis of Uniformly Doped Ge Nanowires with Carbon Sheath

  • Kim, Tae-Heon;;Choe, Sun-Hyeong;Seo, Yeong-Min;Lee, Jong-Cheol;Hwang, Dong-Hun;Kim, Dae-Won;Choe, Yun-Jeong;Hwang, Seong-U;Hwang, Dong-Mok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.289-289
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    • 2013
  • While there are plenty of studies on synthesizing semiconducting germanium nanowires (Ge NWs) by vapor-liquid-solid (VLS) process, it is difficult to inject dopants into them with uniform dopants distribution due to vapor-solid (VS) deposition. In particular, as precursors and dopants such as germane ($GeH_4$), phosphine ($PH_3$) or diborane ($B_2H_6$) incorporate through sidewall of nanowire, it is hard to obtain the structural and electrical uniformity of Ge NWs. Moreover, the drastic tapered structure of Ge NWs is observed when it is synthesized at high temperature over $400^{\circ}C$ because of excessive VS deposition. In 2006, Emanuel Tutuc et al. demonstrated Ge NW pn junction using p-type shell as depleted layer. However, it could not be prevented from undesirable VS deposition and it still kept the tapered structures of Ge NWs as a result. Herein, we adopt $C_2H_2$ gas in order to passivate Ge NWs with carbon sheath, which makes the entire Ge NWs uniform at even higher temperature over $450^{\circ}C$. We can also synthesize non-tapered and uniformly doped Ge NWs, restricting incorporation of excess germanium on the surface. The Ge NWs with carbon sheath are grown via VLS process on a $Si/SiO_2$ substrate coated 2 nm Au film. Thin Au film is thermally evaporated on a $Si/SiO_2$ substrate. The NW is grown flowing $GeH_4$, HCl, $C_2H_2$ and PH3 for n-type, $B_2H_6$ for p-type at a total pressure of 15 Torr and temperatures of $480{\sim}500^{\circ}C$. Scanning electron microscopy (SEM) reveals clear surface of the Ge NWs synthesized at $500^{\circ}C$. Raman spectroscopy peaked at about ~300 $cm^{-1}$ indicates it is comprised of single crystalline germanium in the core of Ge NWs and it is proved to be covered by thin amorphous carbon by two peaks of 1330 $cm^{-1}$ (D-band) and 1590 $cm^{-1}$ (G-band). Furthermore, the electrical performances of Ge NWs doped with boron and phosphorus are measured by field effect transistor (FET) and they shows typical curves of p-type and n-type FET. It is expected to have general potentials for development of logic devices and solar cells using p-type and n-type Ge NWs with carbon sheath.

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A novel higher-order shear deformation theory for bending and free vibration analysis of isotropic and multilayered plates and shells

  • Zine, Abdallah;Tounsi, Abdelouahed;Draiche, Kada;Sekkal, Mohamed;Mahmoud, S.R.
    • Steel and Composite Structures
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    • v.26 no.2
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    • pp.125-137
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    • 2018
  • In this work, the bending and free vibration analysis of multilayered plates and shells is presented by utilizing a new higher order shear deformation theory (HSDT). The proposed involves only four unknowns, which is even less than the first shear deformation theory (FSDT) and without requiring the shear correction coefficient. Unlike the conventional HSDTs, the present one presents a novel displacement field which incorporates undetermined integral variables. The equations of motion are derived by using the Hamilton's principle. These equations are then solved via Navier-type, closed form solutions. Bending and vibration results are found for cylindrical and spherical shells and plates for simply supported boundary conditions. Bending and vibration problems are treated as individual cases. Panels are subjected to sinusoidal, distributed and point loads. Results are presented for thick to thin as well as shallow and deep shells. The computed results are compared with the exact 3D elasticity theory and with several other conventional HSDTs. The proposed HSDT is found to be precise compared to other several existing ones for investigating the static and dynamic response of isotropic and multilayered composite shell and plate structures.

Analysis of Laminated Composite Stiffened Plates with arbitrary orientation stiffener (임의방향 보강재를 가지는 복합적층 보강판의 해석)

  • Yhim, Sung-Soon;Chang, Suk-Yoon;Park, Dae-Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.8 no.2
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    • pp.147-158
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    • 2004
  • For stiffened plates composed of composite materials, many researchers have used a finite element method which connected isoparametric plate elements and beam elements. However, the finite element method is difficult to reflect local behavior of stiffener because beam elements are transferred stiffness for nodal point of plate elements, especially the application is limited in case of laminated composite structures. In this paper, for analysis of laminated composite stiffened plates, 3D shell elements for stiffener and plate are employed. Reissner-Mindlin's first order shear deformation theory is considered in this study. But when thickness will be thin, isoparamatric plate bending element based on the theory of Reissner-Mindlin is generated by transverse shear locking. To eliminate the shear locking and virtual zero energy mode, the substitute shear strain field is used. A deflection distribution is investigated for simple supported rectangular and skew stiffened laminated composite plates with arbitrary orientation stiffener as not only variation of slenderness and aspect ratio of the plate but also variation of skew angle of skew stiffened plates.

Preparation and characterization of magnetic nanoparticles with two kinds of core/shell structures (핵/껍질 구조를 가진 두 종류의 자기 나노입자의 제조와 특성비교)

  • 고영재;손인호;김영국;동성용;이근진;박규섭
    • Journal of the Korean Vacuum Society
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    • v.10 no.1
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    • pp.87-92
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    • 2001
  • Magnetic Fe-Co(C) nanocapsules and Fe-Co nanoparticles were prepared by arc-discharge in two kinds of atmospheres, i.e. methane and a mixture of ($H_2$+Ar), respectively. Characterization and magnetic properties of this two kinds of ultrafine particles were investigated systematically by means of X-ray diffraction, Mssbauer spectroscopy, X-ray photoelectron spectroscopy, transmission electron microscopy, energy disperse spectroscopy analysis, chemical analysis, oxygen determination and magnetization measurement. Effects of carbon element, decomposed from a methane atmosphere in carbon arc process, on phase structures, magnetic states and surface characterization were studied in comparison to that of Ar element. Two ultrafine particles showed a little difference in the weight ratio of (Fe/co) and the size for Fe-Co nanoparticles was about two times bigger than Fe-Co(C) nanocapsules. The saturation magnetization of Fe-Co (C) nanocapsules was about 8% higher than that of Fe-Co nanoparticles while their phase constitutions were similar. Although no carbon could be detected by XRD measurement because of extremely thin shells on the surfaces of the cores, it is still believed that they are carbon and oxygen layers.

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Mapping the East African Ionosphere Using Ground-based GPS TEC Measurements

  • Mengist, Chalachew Kindie;Kim, Yong Ha;Yeshita, Baylie Damtie;Workayehu, Abyiot Bires
    • Journal of Astronomy and Space Sciences
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    • v.33 no.1
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    • pp.29-36
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    • 2016
  • The East African ionosphere (3°S-18°N, 32°E-50°E) was mapped using Total Electron Content (TEC) measurements from ground-based GPS receivers situated at Asmara, Mekelle, Bahir Dar, Robe, Arbaminch, and Nairobi. Assuming a thin shell ionosphere at 350 km altitude, we project the Ionospheric Pierce Point (IPP) of a slant TEC measurement with an elevation angle of >10° to its corresponding location on the map. We then infer the estimated values at any point of interest from the vertical TEC values at the projected locations by means of interpolation. The total number of projected IPPs is in the range of 24-66 at any one time. Since the distribution of the projected IPPs is irregularly spaced, we have used an inverse distance weighted interpolation method to obtain a spatial grid resolution of 1°×1° latitude and longitude, respectively. The TEC maps were generated for the year 2008, with a 2 hr temporal resolution. We note that TEC varies diurnally, with a peak in the late afternoon (at 1700 LT), due to the equatorial ionospheric anomaly. We have observed higher TEC values at low latitudes in both hemispheres compared to the magnetic equatorial region, capturing the ionospheric distribution of the equatorial anomaly. We have also confirmed the equatorial seasonal variation in the ionosphere, characterized by minimum TEC values during the solstices and maximum values during the equinoxes. We evaluate the reliability of the map, demonstrating a mean error (difference between the measured and interpolated values) range of 0.04-0.2 TECU (Total Electron Content Unit). As more measured TEC values become available in this region, the TEC map will be more reliable, thereby allowing us to study in detail the equatorial ionosphere of the African sector, where ionospheric measurements are currently very few.

Feature-Based Non-manifold Geometric Modeling System to Provide Integrated Environment for Design and Analysis of Injection Molding Products (사출 성형 제품의 설계 및 해석의 통합 환경을 제공하기 위한 특징 형상 기반 비다양체 모델링 시스템의 개발)

  • 이상헌;이건우
    • Korean Journal of Computational Design and Engineering
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    • v.1 no.2
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    • pp.133-149
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    • 1996
  • In order to reduce the trial-and-errors in design and production of injection molded plastic parts, there has been much research effort not only on CAE systems which simulate the injection molding process, but also on CAD systems which support initial design and re-design of plastic parts and their molds. The CAD systems and CAE systems have been developed independently with being built on different basis. That is, CAD systems manipulate the part shapes and the design features in a complete solid model, while CAE systems work on shell meshes generated on the abstract sheet model or medial surface of the part. Therefore, it is required to support the two types of geometric models and feature information in one environment to integrate CAD and CAE systems for accelerating the design speed. A feature-based non-manifold geometric modeling system has been developed to provide an integrated environment for design and analysis of injection molding products. In this system, the geometric models for CAD and CAE systems are represented by a non-manifold boundary representation and they are merged into a single geometric model. The suitable form of geometric model for any application can be extracted from this model. In addition, the feature deletion and interaction problem of the feature-based design system has been solved clearly by introducing the non-manifold Boolean operation based on 'merge and selection' algorithm. The sheet modeling capabilities were also developed for easy modeling of thin plastic parts.

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Flexural Strength of HSB Plate Girder with Compact or Noncompact Web Due to Inelastic Lateral-Torsional Buckling (조밀 또는 비조밀 복부판을 갖는 HSB 플레이트거더의 비탄성 횡비틀림좌굴에 의한 휨강도)

  • Shin, Dong Ku;Cho, Eun Young
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.6A
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    • pp.399-409
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    • 2012
  • The flexural behavior of HSB plate girder with a non-slender web, due to inelastic lateral-torsional buckling, under uniform bending was investigated by the nonlinear finite element analysis. Both homogeneous sections fabricated from SM570-TMC, HSB600 or HSB800 steel and hybrid sections with HSB800 flanges and SM570-TMC web were considered. The flanges and web of selected noncomposite I-girders were modeled as thin shell elements and the geometrical and material nonlinear finite element analysis was performed by the ABAQUS program. The steel was assumed as an elasto-plastic strain hardening material. Initial imperfections and residual stresses were taken into account and their effects on the inelastic lateral-torsional buckling behavior were analyzed. The flexural strengths of selected sections obtained by the finite element analysis were compared with the nominal flexural strengths from KHBDC LSD, AASHTO LRFD, and Eurocode and the applicability of these codes in predicting the inelastic lateral torsional buckling strength of HSB plate girders with a non-slender web was assessed.

A study on drainage system of the room-and-pillar underground structure considering groundwater conditions (지하수 유출수 조건을 고려한 주방식 지하구조의 배수시스템 연구)

  • Lee, Chulho;Hyun, Younghwan;Hwang, Jedon;Chang, Soo-Ho
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.17 no.6
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    • pp.675-683
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    • 2015
  • The room-and-pillar construction method for underground space is adopted from the room-and-pillar mining method which is one of the most popular underground mining method in the world. Drainage system in the room-and-pillar underground construction method can be similar with the concept of single shell in tunnel because additional reinforcement except the TSL (thin spray-on liner) is not applied in the room-and-pillar construction method. That is, to decrease groundwater level and maintain safety in tunnel, the drainage pin hole inside lining (shotcrete) can be used. However, if total amount of outflow in the underground structure is relatively small or groundwater is not detected, such drainage system will not be useful and cause additional construction cost. In this study, outflow of conventional tunnels in South Korea was investigated and the criteria to determine whether the drainage pin hole is effective was suggested. And the guided drainage system was suggested when drainage pin hole was not applied in the room-and-pillar construction method.

Flexural Behavior of Composite HSB I-Girders in Positive Moment (HSB 강합성거더 정모멘트부 휨거동)

  • Cho, Eun-Young;Shin, Dong-Ku
    • Journal of Korean Society of Steel Construction
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    • v.22 no.4
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    • pp.377-388
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    • 2010
  • The flexural behavior of composite HSB600 and HSB800 I-girders under a positive moment was investigated using the material non-linear moment-curvature analysis method. Three representative composite sections with different ductility properties were selected as the baseline sections in this study. Using these baseline sections, the moment-curvature program was verified by comparing the flexural strength and the moment-curvature curve obtained from the program with those obtained using the non-linear FE analysis of ABAQUS. In the FE analysis, the composite girders were modeled three-dimensionally with flanges, the web, and the concrete slab as thin shell elements, and initial imperfections and residual stresses were imposed on the FE model. In the moment-curvature and FE analyses, the 28-day compressive strength of the concrete slab was assumed to be 30-50 MPa, and the HSB600 and HSB800 steels were modeled as elasto-plastic strain-hardening materials, with the concrete as the CEB-FIP model. The effects of the ductility ratio of the composite girder, the type of steel, the compressive strength of the concrete deck, and the location of the plastic neutral axis on the flexural characteristics were analyzed.

Inverted CdSe/ZnS Quantum Dots Light-Emitting Diode Using Low-Work Function Organic Material Polythylenimine Ethoylated

  • Kim, HongHee;Son, DongIck;Jin, ChangKyu;Hwang, DoKyung;Yoo, Tae-Hee;Park, CheolMin;Choi, Won Kook
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.246.1-246.1
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    • 2014
  • Over the past several years, colloidal core/shell type quantum dots lighting-emitting diodes (QDLEDs) have been extensively studied and developed for the future of optoelectronic applications. In the work, we fabricate an inverted CdSe/ZnS quantum dot (QD) based light-emitting diodes (QDLED). In order to reduce work function of indium tin oxide (ITO) electrode for inverted structure, a very thin (<10 nm) polyethylenimine ethoxylated (PEIE) is used as surface modifier[1] instead of conventional metal oxide electron injection layer. The PEIE layer substantially reduces the work function of ITO electrodes which is estimated to be 3.08 eV by ultraviolet photoemission spectroscopy (UPS). From transmission electron microscopy (TEM) study, CdSe/ZnS QDs are uniformly distributed and formed by a monolayer on PEIE layer. In this inverted QDLEDs, blend of poly (9,9-di-n-octyl-fluorene-alt-benzothiadiazolo) and poly(N,N'-bis(4-butylphenyl)-N,N'-bis(phenyl)benzidine] are used as hole transporting layer (HTL) to improve hole transporting property. At the operating voltage of 8 V, the QDLED device emitted spectrally orange color lights with high luminance up to 2450 cd/m2, and showed current efficacy of 0.6 cd/A, respectively.

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