• Title/Summary/Keyword: Thermosetting

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Measurement of the Degree of Cure of Thermosetting Resin Matrix Composite Materials (열경화성수지 복합재료의 경화정도의 측정에 관한 연구)

  • 김진수;이대길
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.9
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    • pp.2154-2164
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    • 1995
  • In this study, a dielectric cure monitoring system which consists of an electric circuit, a sensor and a personal computer was developed to on-line monitor the dielectric properties of carbon fiber epoxy composite materials. Also, the kinetic model of carbon fiber epoxy composite materials was developed by curve fitting of differential scanning calorimetry data. The start and end points of cure and the relationship between the dissipation factor and the degree of cure were obtained by comparing the dissipation factor from the dielectric properties with the degree of cure from the DSC data. The relationship between the dissipation factor and the degree of cure was tested under various temperature profiles.

Development of Phenolic SMC for The Rail (철도차량 및 지하철 불연 내장재 페놀 SMC 개발)

  • Kim Young-keun;Shin Dong-hyok;Kim Young-min;Park Joung-wuk;Min Jae-Jun
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.04a
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    • pp.55-58
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    • 2004
  • Phenolin resin, prepared form phenol and formaldehyde, is one of the oldest thermosetting resins available. Phenolic resins are cured via condensation polymerization with evolution of water, which in molding process is a big problem. The use of phenolic resins in glass fiber composites is growing, primarily due to their low flame spread, low smoke generation and low smoke toxicity properties. SMC of phenolics has been rearched since the 1986. The technology challenge was to match resin viscosity, handling and cure with those for the polyester SMC to avoid any special processing for fabricators and end users. Phenolic SMC was chosen because of the ease of molding to the required shape with light- weight, thin wall structure and with excellent fire protection.

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The effect of MWCNTs on the mechanical properties of woven Kevlar/epoxy composites

  • Taraghi, Iman;Fereidoon, Abdolhossein;Mohyeddin, Ali
    • Steel and Composite Structures
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    • v.17 no.6
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    • pp.825-834
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    • 2014
  • This manuscript presents an experimental investigation on the effect of Multi-walled carbon nanotubes (MWCNTs) addition on the tensile, flexural and impact properties of woven Kevlar fabric reinforced epoxy composites. MWCNTs were dispersed in the epoxy resin by sonication technique and the samples were fabricated by hand layup laminating procedure. Scanning electron microscopy (SEM) was used to characterize the microstructure of produced samples. The effects of adding small amounts (${\leq}1%$) of MWCNT on the tensile, flexural and impact (Izod) behaviors of laminated composites were analyzed. Results revealed that MWCNTs enhanced the Young's modulus up to 20%, bending modulus up to 40%, and impact strength up to 45% in comparison with woven Kevlar fabric/epoxy composites. It was found that the maximum improvements in mechanical properties were happened for 0.5 wt.% MWCNT.

A Study on Electrical Properties of Insulating Materials for Eco-friendly Distribution Power Cables (I) (친환경 배전급 전력케이블용 절연재료의 전기적 특성에 관한 연구 (I))

  • Lee, June-Ho;Kim, Chul-Ho;Cho, Young-Chul;Lee, Moon-Seok
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.66 no.3
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    • pp.551-556
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    • 2017
  • The cross-linked polyethylene(XLPE) has been most widely used for the power cable insulating layer because of its outstanding properties such as electrical and mechanical properties. However, XLPE is unrecyclable when disposed after replacement and demolishing because it becomes thermosetting through cross-linked process. Recently, because of growing social awareness of recycling and eco-friendly, there is growing need for the development of recyclable insulating materials that can replace XLPE. Therefore, the purpose of this study is to compare the electrical properties of XLPE and recyclable thermoplastic insulating materials. To this end, we compared and analyzed the electrical properties of XLPE and group N2 through AC breakdown test, accelerated water treeing test and accelerated life test(ALT).

Analysis of Electric Field Distribution and Characteristics of Volume Resistivity in HDPE/EVA Film for Recycling (재활용을 고려한 HDPE/EVA필름의 전계분포 및 체적저항특성 해석)

  • Lee, Hung-Kyu;Lim, Kee-Joe;Kim, Yong-Joo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.9
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    • pp.801-807
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    • 2008
  • Recently, CV, CN-CV and CNCV-W cable are used for HVDC transmission and distribution cable. However, XLPE which is used as insulation layer of power cable has thermosetting properties. It is very difficult to recycling. In this paper, we prepared HDPE/EVA film, which the blending ratio are 80:20, 70:30, 60:40, 50;50 respectively for the purpose of recycling. Main factor such as electric field distribution and its resistivity in insulation system affected on insulation performance and reliability for HVDC applications. Therefore, electric field distribution formed by space charge and characteristics of volume resistivity was currently investigated. We suggest the possibility of utilization for HVDC insulation layer from the results.

Experimental and microstructural evaluation on mechanical properties of sisal fibre reinforced bio-composites

  • Kumar, B. Ravi;Hariharan, S.S.
    • Steel and Composite Structures
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    • v.33 no.2
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    • pp.299-306
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    • 2019
  • The natural fibre composites are termed as bio-composites. They have shown a promising replacement to the current carbon/glass fibre reinforced composites as environmental friendly materials in specific applications. Natural fibre reinforced composites are potential materials for various engineering applications in automobile, railways, building and Aerospace industry. The natural fibre selected to fabricate the composite material is plant-based fibre e.g., sisal fibre. Sisal fibre is a suitable reinforcement for use in composites on account of its low density, high specific strength, and high hardness. Epoxy is a thermosetting polymer which is used as a resin in natural fibre reinforced composites. Hand lay-up technique was used to fabricate the composites by reinforcing sisal fibres into the epoxy matrix. Composites were prepared with the unidirectional alignment of sisal fibres. Test specimens with different fibre orientations were prepared. The fabricated composites were tested for mechanical properties. Impact test, tensile test, flexural test, hardness test, compression test, and thermal test of composites had been conducted to assess its suitability in industrial applications. Scanning electron microscopy (SEM) test revealed the microstructural information of the fractured surface of composites.

Experimental investigation on thermal behavior, sound absorption, and flammability of natural fibre polymer composites

  • Ravi Kumar, B.;Hariharan, S.S.
    • Structural Engineering and Mechanics
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    • v.76 no.5
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    • pp.613-618
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    • 2020
  • Exhausting oil resources and increasing pollution around the world are forcing researchers to look for new, renewable, biodegradable materials to lead sustainable development. The use of fiber reinforced composites based on natural fibres has increasingly begun as prospective materials for various engineering applications in the automotive, rail, construction and aerospace industries. The natural fiber chosen to make the composite material is plant-based fibre, e.g. jute fibre, and hemp fibre. Thermosetting polymer based Epoxy (LY556) was utilized as matrix material and The composites were produced using hand lay-up technique. The fabricated composites were tested for acoustic testing, thermo-gravimetric analysis (TGA) and flammability testing to asses sound absorption, thermal decomposition and fire resistivity of the structures. Hemp fibre composites have shown improved thermal stability over Jute fibre composites. However, the fire resistance characteristics of jute fibre composites are better as compared to hemp fibre composites. The sound absorption coefficient of composites was found to enhance with the increase of frequency.

Effect of Fiber Orientation and Fiber Contents on the Tensile Strength in Fiber-reinforced Thermoplastic Composites (섬유배향과 섬유함유량이 섬유강화 열가소성수지 복합재료의 인장강도에 미치는 영향)

  • Kim, Jin-Woo;Lee, Dong-Gi
    • Composites Research
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    • v.20 no.5
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    • pp.13-19
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    • 2007
  • Fiber-reinforced thermoplastic composites not only approach almost near to the strength of thermosetting composite but also has excellent productivity, recycling property, and impact resistance, which are pointed as weaknesses of thermosetting composites. The study for strength calculation of one direction fiber-reinforced thermoplastic composites and the study measuring precisely fiber orientation distribution were presented. Need the systematic study for the data base that can predict mechanical properties of composite material and fiber orientation distribution by the fiber content ratio was not constructed. Therefore, this study was investigated what affect the fiber content ratio and fiber orientation distribution have on the strength of composites. Fiber-reinforced thermoplastic composites by changing fiber orientation distribution and the fiber content ratio were made. Tensile strength ratio of $0^{\circ}$ direction of fiber-reinforced composites increased being proportional the fiber content and fiber orientation function as change from isotropy(J=0) to anisotropy(J=1). But, tensile strength ratio of $90^{\circ}$ direction by separation of fiber filament decreased when tensile load is imposed fur width direction of reinforcement fiber length direction.

Viscoelastic Properties of MF/PVAc Hybrid Resins as Adhesive for Engineered Flooring by Dynamic Mechanical Thermal Analysis

  • Kim, Sumin;Kim, Hyun-Joong;Yang, Han-Seung
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.2
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    • pp.37-45
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    • 2006
  • The viscoelastic properties of blends of melamine-formaldehyde (MF) resin and poly(vinyl acetate) (PVAc) for engineered flooring used on the Korean traditional ONDOL house floor heating system were investigated by dynamic mechanical thermal analysis (DMTA). Because MF resin is a thermosetting adhesive, the effect of MF rein was shown across all thermal behaviors. The addition of PVAc reduced the curing temperature. The DMTA thermogram of MF resin showed that the storage modulus (E') increased as the temperature was further increased as a result of the cross-linking induced by the curing reaction of the resin. The storage modulus (E') of MF resin increased both as a function of increasing temperature and with increasing heating rate. From isothermal DMTA results, peak $T_{tan{\delta}}$ values, maximum value of loss modulus (E") and the rigidities (${\Delta}E$) of MF/PVAc blends at room temperature as a function of open time, peak $T_{tan{\delta}}$ and maximum loss modulus (E") values were found to increase with blend MF content. Moreover, the rigidities of the 70:30 and 50:50 MF/PVAc blends were higher than those of the other blends, especially of 100% PVAc or MF. We concluded that blends the MF/PVAc blend ratios correlate during the adhesion process.

Thermo-electrical properties of randomly oriented carbon/carbon composite

  • Raunija, Thakur Sudesh Kumar;Supriya, N.
    • Carbon letters
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    • v.22
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    • pp.25-35
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    • 2017
  • The aim of the work was to investigate the thermo-electrical properties of low cost and rapidly produced randomly oriented carbon/carbon (C/C) composite. The composite body was fabricated by combining the high-pressure hot-pressing (HP) method with the low-pressure impregnation thermosetting carbonization (ITC) method. After the ITC method step selected samples were graphitized at $3000^{\circ}C$. Detailed characterization of the samples' physical properties and thermal properties, including thermal diffusivity, thermal conductivity, specific heat and coefficient of thermal expansion, was carried out. Additionally, direct current (DC) electrical conductivity in both the in-plane and through-plane directions was evaluated. The results indicated that after graphitization the specimens had excellent carbon purity (99.9 %) as compared to that after carbonization (98.1). The results further showed an increasing trend in thermal conductivity with temperature for the carbonized samples and a decreasing trend in thermal conductivity with temperature for graphitized samples. The influence of the thickness of the test specimen on the thermal conductivity was found to be negligible. Further, all of the specimens after graphitization displayed an enormous increase in electrical conductivity (from 190 to 565 and 595 to 1180 S/cm in the through-plane and in-plane directions, respectively).